Explorations Of Talspeak Chemistry In Extraction Chromatography: Comparisons of TTHA with DTPA and HDEHP with HEH[EHP]

Solvent Extraction and Ion Exchange

Volumn 31, Issue 2, 2013, Pages 107-121

  Braley, Jenifer C ^a,b   McAlister, Daniel R ^c   Philip Horwitz, E ^c   Nash, Kenneth L ^a  

^a WASHINGTON STATE UNIVERSITY   (United States)

^b PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^c PG Research Foundation Inc   (United States)

Author keywords

actinide separation; DTPA; extraction chromatography; HDEHP; HEH EHP ; Lanthanide separation; TTHA

Indexed keywords

ACTINIDE SEPARATION; DTPA; EXTRACTION CHROMATOGRAPHY; HDEHP; HEH[EHP]; TTHA;

ACTINIDES; CARBOXYLATION; FISSION PRODUCTS; LACTIC ACID; NUCLEAR FUEL REPROCESSING; ORGANIC ACIDS; PH; PHOSPHORIC ACID; RARE EARTH ELEMENTS; RESINS; SEPARATION; SOLVENT EXTRACTION;

CHROMATOGRAPHY;

EID: 84874164328     PISSN: 07366299     EISSN: 15322262     Source Type: Journal    
DOI: 10.1080/07366299.2012.735503     Document Type: Article

References (36)

1. Nash, K. L., Madic, C., Mathur, J. N. and Lacquement, J. 2006. "Actinide Separation Science and Technology". In The Chemistry of Actinides and Transactinide Elements, Edited by: Morss, L. R., Katz, J. J., Edelstein, N. and Fuger, J. 2622-2798. Springer: Dordrecht, the Netherlands.
2. Aspinall, H. 2001. Chemistry of the f-Block Elements; Gordon & Breach: Amsterdam, the Netherlands, 5th 61-104.
3. Jensen, M. P. and Bond, A. H. 2002. Influence of aggregation on the extraction of trivalent lanthanide and actinide cations by purified Cyanex 272, Cyanex 301, and Cyanex 302. Radiochim. Acta., 90(4): 205-209.
4. Jensen, M. P. and Bond, A. H. 2002. Comparison of covalency in the complexes of trivalent actinide and lanthanide cations. J. Am. Chem. Soc., 124(33): 9870-9877.
5. Choppin, G. R. and Nash, K. L. 1995. Actinide separation science. Radiochim. Acta., 70/7(1): 225-236.
6. Kozimor, S.A., Yang, P., Batista, E.R., Boland, K.S., Burns, C.J., Clark, D.L., Conradson, S.D., Martin Wilkerson, M.P. and Wolfsberg, L.E. 2009. Trends in covalency for d- and f-Element metallocene dichlorides identified using chlorine K-edge X-ray absorption spectroscopy and time-dependent density functional theory. J. Am. Chem. Soc., 131(34): 12125-12136.
7. Peterman, D.R., Martin, L.R., Klaehn, J.R., Harrup, M.K., Greenhalgh, M.R. and Luther, T.A. 2009. Selective separation of minor actinides and lanthanides using aromatic dithiophosphinic and phosphinic acid derivatives. J. Rad. Nucl. Chem, 282(2): 527-531.
8. Hill, C., Guillaneux, D., Berthon, L. and Madic, D. 2002. Sanex-BTP process development studies. J. Nucl. Sci. Technol.,: 453-461. Suppl. 3
9. Ekberg, C., Fermvik, A., Retegan, T., Skarnemark, G., Foreman, M. R. S., Hudson, M.J., Englund, S and Nilsson, M. 2008, 96. An overview and historical look back at the solvent extraction using nitrogen door ligands to extract and separate An(III) from Ln(III). Radiochim. Acta,: 225-233.
10. Weaver, B. and Kappelmann, F.A. 1968. "Talspeak, A new method of separating americium and curium from the lanthanides by extraction from an aqueous solution of an aminopolyacetic acid complex with a monoacetic organophosphate or phosphonate. August 1964, ORNL-3559". In Preferential extraction of lanthanides over trivalent actinides by monoacidic organophosphates from carboxylic acids and from mixtures of carboxylic and aminopolyacetic acids. J. Inorg. Nucl. Chem Edited by: Weaver, B. and Kappelmann, F.A. Vol. 30, 263-272.
11. Kosyakov, V. N. and Yerin, E. A. 1980. On the mechanism of trivalent actinide extraction in the system HDEHP-lactic acid with DTPA. J. Radioanal. Chem., 56: 93-104.
12. Grimes, T. S., Nilsson, M. and Nash, K. L. 2010. Lactic acid partitioning in TALSPEAK extraction systems. Sep. Sci. Technol., 45: 1725-1732.
13. Braley, J.C., Grimes, T.S. and Nash, K.L. 2012. Alternatives to HDEHP and DTPA for simplified TALSPEAK separations. Ind. Eng. Chem. Res., 51(2), 629-638)
14. Pierce, T.B. and Hobbs, R.S. 1963. The separation of the rare earths by partition chromatography with reversed phases. Part I. Behavior of column material. J. Chrom., 12: 74-80.
15. Pierce, T.B., Peck, P.F. and Hobbs, R.S. 1963. The separation of the rare earths by partition chromatography with reversed phases Part II. Behaviour of individual elements on HDEHP-corvic columns. J. Chrom., 12: 81-88.
16. Akaza, I., Kiba, T. and Kiba, T. 1970. The separation of gold, platinum, and palladium by reversed-phase partition chromatography. Bull. Chem. Soc. Jpn., 43: 2063-2067.
17. Sebesta, F. 1970. Extraction chromatography using chelating agents I. System zinc-dithizone-carbon tetrachloride. J. Radioanal. Chem., 6: 41-46.
18. Sebesta, F. 1971. Extraction chromatography using chelating agents II. Separation of some radioisotopes by dithizone. J. Radioanal. Chem., 7: 41-47.
19. Cortina, J.L., Miralles, N., Aguilar, M. and Sastre, A.M. 1994. Solvent impregnated resins containing di(2-ethylhexyl)phosphoric acid II. Study of the distribution equilibria of Zn(II), Cu(II), and Cd(II). Solv. Extr. Ion Exch., 12: 371-391.
20. Kosyakov, V.N. and Yerin, E.A. 1978. Separation of transplutonium and rare-earth elements by extraction with HDEHP from DTPA solution. J. Rad. Nucl. Chem., 43(1): 37-51.
21. Bond, W.D. and Leuze, R.E. January 1975. Feasibility studies of the partitioning of commercial high-level wastes generated in spent nuclear fuel reprocessing: Annual Progress Report for FY-1974, ORNL-5012 January,
22. Hu, Z., Pan, Y., Ma, W. and Fu, X. 1995. Purification of organophosphorus acid extractants. Solvent Extr. Ion Exch., 13(5): 965-976.
23. Horwitz, E.P., McAlister, D.R. and Dietz, M.L. 2006. Extraction chromatography versus solvent extraction: How similar are they?. Sep. Sci. Tech., 41(10): 2163-2182.
24. Nilsson, M. and Nash, K.L. 2009. Trans-lanthanide extraction studies in the TALSPEAK system: Investigating the effect of acidity and temperature. Solvent Extr. Ion Exch., 27(3): 354-377.
25. Nilsson, M. and Nash, K.L. 2007. Review article: A review of the development and operational characteristics of the TALSPEAK process. Solvent Extr. Ion Exch., 25(6): 665-710.
26. Svantesson, I., Hagström, I., Persson, G. and Liljenzin, J.O. 1979. Separation of americium and neodymium by selective stripping and subsequent extraction with HDEHP using DTPA-lactic acid solution in a closed loop. Radiochem. Radioanal. Letters, 37(4-5): 251-222.
27. 31P NMR and ESI-MS. Dalton Transactions., 41(3), 1054-1064) 1477-9226
28. Grimes, T. S., Tian, G., Rao, L. and Nash, K. L. 2012. Optical spectroscopy study of lanthanide organic phase complexes in the TALSPEAK separations process. Inorg. Chem., 51(11): 6299-6307.
29. Kolarik, Z., Koch, G. and Kuhn, W. 1974. Acidic organophosphorus extractants. XVIII. Rate of lanthanide (III) extraction by bis(2-ethylhexyl) phosphoric acid from complexing media. Jour. Inorg. Nucl. Chem., 36(4): 905-909.
30. Nilsson, M. and Nash, K. L. 2008. "TALSPEAK Chemistry in Advanced Nuclear Fuel Cycles Proceedings Atalante 2008". In Nuclear Fuel Cycles for a Sustainable Future, May 19-23 Montpelier, France paper number 01_12
31. Frullano, L., Rohovec, J., Peters, J.A. and Geraldes, C.F.G.C. 2002. "Structures of MRI Contrast Agents in Solution". In Contrast Agents. 1: Magnetic Resonance Imaging: Topics in Current Chemistry; Kraus, V, Vol. 221, 25-60. Berlin, Germany: Springer.
32. Leggett, C. J., Liu, G. and Jensen, M. P. 2010. Do Aqueous ternary complexes influence the TALSPEAK process?. Solvent Extr Ion Exch., 28: 313-334.
33. Choppin, G. R. and Rydberg, J. 1980. Nuclear Chemistry Theory and Applications, 593-599. Oxford, England: Pergammon Press. Appendix 2
34. Martell, A.E. and Smith, R.M. 2004. NIST Critically Selected Stability Constants of Metal Complexes Database Version 8.0
35. Tachimori, S. and Nakamura, H. 1979. Radiation effects of the separation of lanthanides and transplutonides by the TALSPEAK-type extraction. J. Radioanal. Chem., 52(2): 343-354.
36. Harris, D.C. 1991. Quantitative Chemical Analysis, 3rd, New York, NY: W. H. Freeman and Company.