Thermodynamic features of the complexation of neodymium(III) and Americium(III) by lactate in trifluoromethanesulfonate media

Journal of Solution Chemistry

Volumn 39, Issue 8, 2010, Pages 1213-1229

  Zalupski, P R ^a   Nash, K L ^b   Martin, L R ^a  

^a IDAHO NATIONAL LABORATORY   (United States)

^b WASHINGTON STATE UNIVERSITY   (United States)

Author keywords

Actinides; Calorimetry; Lanthanides; TALSPEAK process; Thermochemistry

Indexed keywords

EID: 77958600090     PISSN: 00959782     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10953-010-9573-2     Document Type: Article

References (51)

1. P.A. Baisden G.R. Choppin 2007 Nuclear waste management and the nuclear fuel cycle S. Nagy (eds) Encyclopedia of Life Support Systems (EOLSS). Developed under the Auspices of the UNESCO Eolss Publishers Oxford http://www.eolss.net
2. Baisden, P.A., Choppin, G.R.: Nuclear waste management and the nuclear fuel cycle. In: Nagy, S. (ed.) Encyclopedia of Life Support Systems (EOLSS). Developed under the Auspices of the UNESCO. Eolss Publishers, Oxford (2007). http://www.eolss.net
3. Nash, K.L., Lumetta, G.J., Clark, S.B., Friese, J.: Significance of the nuclear fuel cycle in the 21st century. In: Nash, K.L., Lumetta, G.J., Clark, S.B., Friese, J. (eds.) Separations for the Nuclear Fuel Cycle in the 21st Century. ACS Symposium Series, vol. 933, p. 10. Oxford University Press, Oxford (2006)
4. Schulz, W.W., Navratil, J.D.: Science and Technology of Tributyl Phosphate, vol. 1. CRC Press, Boca Raton (1984)
5. Nash, K.L.: Twenty-first century approaches to actinide partitioning. In: Nash, K.L., Lumetta, G.J., Clark, S.B., Friese, J. (eds.) Separations for the Nuclear Fuel Cycle in the 21st Century. ACS Symposium Series, vol. 933, p. 23. Oxford University Press, Oxford (2006)
6. Nash, K.L., Madic, C., Mathur, J.N., Lacquemont, J.: Actinide separation science and technology. In: Morss, L.R., Edelstein, N.M., Fuger, J. (eds.) The Chemistry of the Actinide and Transactinide Elements, vol. 3, p. 2622-2798. Springer, Dordrecht (2006)
7. Rizkalla, E.N., Choppin, G.R.: Lanthanides and actinides hydration and hydrolysis. In: Gschneidner, K.A., Eyring, L. Jr., Choppin, G.R., Lander, G.H. (eds.) Handbook on the Physics and Chemistry of Rare Earths, vol. 18, pp. 529-557. Elsevier/North-Holland, Amsterdam (1994)
8. G.R. Choppin 1995 Comparative solution chemistry of the 4f and 5f elements J. Alloys Compd. 223 174 179 1:CAS:528:DyaK2MXmvVShtro%3D 10.1016/0925-8388(94)09002-5
9. R.D. Shannon 1976 Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Acta Crystallogr. A32 751 767 1:CAS:528:DyaE2sXjs1Gluw%3D%3D
10. K.L. Nash 1993 A review of the basic chemistry and recent developments in trivalent f-elements separations Solv. Extr. Ion Exch. 11 729 768 1:CAS:528:DyaK3sXmtlGrtLw%3D 10.1080/07366299308918184
11. K.L. Nash 1999 Aqueous complexes in separations of f-elements: options and strategies for future development Sep. Sci. Technol. 34 911 929 1:CAS:528:DyaK1MXjslGiurc%3D
12. G.R. Choppin 2002 Covalency in f-element bonds J. Alloys Compd. 344 55 59 1:CAS:528:DC%2BD38Xns1ams70%3D 10.1016/S0925-8388(02)00305-5 (Pubitemid 35152053)
13. R.M. Diamond K. Street Jr. G.T. Seaborg 1954 An ion-exchange study of possible hybridized 5f bonding in the actinides J. Am. Chem. Soc. 76 1461 1469 1:CAS:528:DyaG2cXktFWqtA%3D%3D 10.1021/ja01635a001
14. Y. Zhu J. Chen R. Jiao 1996 Extraction of Am(III) and Eu(III) from nitrate solution with purified cyanex 301 Solv. Extr. Ion Exch. 14 61 68 10.1080/07366299608918326 (Pubitemid 126624882)
15. Z. Kolarik U. Mullich F. Gassner 1999 Extraction of Am(III) and Eu(III) nitrates by 2-6-di-(5,6-dipropyl-1,2,4-triazin-3-yl)pyridines Solv. Extr. Ion Exch. 17 1155 1170 1:CAS:528:DyaK1MXls1yqtbs%3D 10.1080/07366299908934641
16. Z. Kolarik 2008 Complexation and separation of lanthanides(III) and actinides(III) by heterocyclic N-donors in solutions Chem. Rev. 108 4208 4252 1:CAS:528:DC%2BD1cXhtFGjs7fJ 10.1021/cr078003i
17. T. Sekine 1965 Studies of the liquid-liquid partition systems. III. The solvent extraction of americium(III) and europium(III) thiocyanate complexes with tributylphosphate Bull. Chem. Soc. Jpn. 38 1972 1978 1:CAS:528: DyaF28XitlCmsA%3D%3D 10.1246/bcsj.38.1972
18. R.D. Baybarz H.B. Kinser B.S. Weaver 1963 Isolation of transplutonium elements by tertiary amine extraction Nucl. Sci. Eng. 17 457 462 1:CAS:528:DyaF2cXktFKjtr4%3D
19. B. Weaver F.A. Kappelmann 1968 Preferential extraction of lanthanides over trivalent actinides by monoacidic organophosphates from carboxylic acids and from mixtures of carboxylic and aminopolyacetic acids J. Inorg. Nucl. Chem. 30 263 272 1:CAS:528:DyaF1cXnt1ymsg%3D%3D 10.1016/0022-1902(68)80089-2
20. Weaver, B., Kappelmann, F.A.: A new method for separating americium and curium from the lanthanides by extraction from an aqueous solution of an aminopolyacetic acid complex with a monoacidic organophosphate or phosphonate. ORNL-3559 (1964)
21. M. Nilsson K.L. Nash 2007 A review of the development and operational characteristics of the TALSPEAK process Solv. Extr. Ion Exch. 25 665 701 1:CAS:528:DC%2BD2sXhtFChu7vI 10.1080/07366290701634636 (Pubitemid 47559917)
22. M. Nilsson K.L. Nash 2009 Trans-lanthanide extraction studies in the TALSPEAK system: investigating the effect of acidity and temperature Solv. Extr. Ion Exch. 27 354 377 1:CAS:528:DC%2BD1MXktlGqu70%3D 10.1080/07366290902821164
23. D.F. Peppard G.W. Mason J.L. Maier W.J. Driscoll 1957 Fractional extraction of the lanthanides as their di-alkyl orthophosphates J. Inorg. Nucl. Chem. 4 334 343 1:CAS:528:DyaG2sXovFKgtQ%3D%3D 10.1016/0022-1902(57)80016-5
24. Z. Kolarik H. Pankova 1966 Acidic organophosphorus extractants. I. Extraction of lanthanides by means of dialkyl phosphoric acids-effect of structure and size of alkyl group J. Inorg. Nucl. Chem. 28 2325 2333 1:CAS:528:DyaF2sXmtFSq 10.1016/0022-1902(66)80123-9
25. V.N. Kosyakov E.A. Yerin 1980 On the mechanism of trivalent actinide extraction in the system HDEHP-lactic acid with DTPA J. Radioanal. Chem. 56 93 104 1:CAS:528:DyaL3cXitVChtbc%3D 10.1007/BF02516941
26. P.R. Danesi C. Cianetti E.P. Horwitz 1982 Distribution equilibria of Eu(III) in the system: bis(2-ethylhexyl)phosphoric acid, organic diluent-NaCl, lactic acid, polyaminocarboxylic acid, water Sep. Sci. Technol. 17 507 519 1:CAS:528:DyaL38XnsFensg%3D%3D 10.1080/01496398208068555
27. P.R. Danesi C. Cianetti 1982 Kinetics and mechanism of the interfacial mass transfer of Eu(III) in the system: bis(2-ethylhexyl)phosphoric acid, n-dodecane-NaCl, lactic acid, polyaminocarboxylic acid, water Sep. Sci. Technol. 17 969 984 1:CAS:528:DyaL38XhvVyjurY%3D 10.1080/01496398208082107
28. Moattar, F.: Über die in Komplexbildnermischungen auftretenden Verbindungen dreivertiger Transurane. KFK-1416 (1971)
29. Martell, A.E., Smith, R.M.: NIST critically selected stability constants of metal complexes database; Version 8.0, 2004
30. Robinson, R.A., Stokes, R.H.: Electrolyte Solutions, 2nd edn., pp. 483-484. Dover, Mineola (2002)
31. P.R. Zalupski K.L. Nash 2008 Two-phase calorimetry I. Studies on the thermodynamics of lanthanide extraction by bis(2-ethyl(hexyl))phosphoric acid Solv. Extr. Ion Exch. 26 514 533 1:CAS:528:DC%2BD1cXhtFKls7%2FI 10.1080/07366290802301374
32. Zékány, L., Nagypál, I.: PSEQUAD. A comprehensive program for the evaluation of potentiometric and/or spectrophotometric equilibrium data using analytical derivatives. In: Leggett, D.J. (ed.) Computational Methods for the Determination of Formation Constants, pp. 291-299. Plenum Press, New York (1985)
33. H.B. Silber V. Maraschin R. Campbell 2003 Europium(III)-triflate interactions in water and aqueous methanol studied by UV-Vis and luminescence J. Solid State Chem. 171 225 229 1:CAS:528:DC%2BD3sXjs1CjtrY%3D 10.1016/S0022-4596(02)00156-1
34. Robinson, R.A., Stokes, R.H.: Electrolyte Solutions, 2nd edn., pp. 122-123. Dover, Mineola (2002)
35. P.H. Barry J.W. Lynch 1991 Liquid junction potentials and small cell effects in patch-clamp analysis J. Membr. Biol. 121 101 117 1:STN:280: DyaK3MzltVWlsQ%3D%3D 10.1007/BF01870526
36. J.A. Rard D.A. Palmer J.G. Albright 2003 Isopiestic determination of the osmotic and activity coefficients of aqueous sodium trifluoromethanesulfonate at 298.15 K and 323.15 K, and representation with an extended ion-interaction (Pitzer) model J. Chem. Eng. Data 48 158 166 1:CAS:528:DC%2BD38XovFCnsb4%3D 10.1021/je020134n
37. O.D. Bonner 1981 Study of methanesulfonates and trifluoromethanesulfonates: evidence for hydrogen bonding to the trifluoro group J. Am. Chem. Soc. 103 3262 3265 1:CAS:528:DyaL3MXkt1CjtLs%3D 10.1021/ja00402a004
38. Robinson, R.A., Stokes, R.H.: Electrolyte Solutions, 2nd edn, pp. 438-439. Dover, Mineola (2002)
39. R.A. Robinson 1980 The temperature variation of the Harned coefficient in the system HCl-NaCl J. Solution Chem. 9 449 454 1:CAS:528:DyaL3cXmtFWju7s%3D
40. K.S. Pitzer G. Mayorga 1973 Thermodynamics of electrolytes. II. Activity and osmotic coefficients for strong electrolytes with one or both ions univalent J. Phys. Chem. 77 2300 2308 1:CAS:528:DyaE3sXlt12rtr0%3D 10.1021/j100638a009
41. B. Das 2004 Pitzer ion interaction parameters of single aqueous electrolytes at 25 °C J. Solution Chem. 33 33 45 1:CAS:528: DC%2BD2cXjs1Oisbw%3D 10.1023/B:JOSL.0000026644.59715.0f (Pubitemid 39023531)
42. G.R. Choppin H.G. Friedman Jr. 1966 Complexes of trivalent lanthanide ions. III. Bidentate chelates Inorg. Chem. 5 1599 1603 1:CAS:528: DyaF28XkslSqt78%3D 10.1021/ic50043a029
43. G.R. Choppin A.J. Graffeo 1965 Complexes of trivalent lanthanide and actinide ions. II. Inner-sphere complexes Inorg. Chem. 4 1254 1257 1:CAS:528:DyaF2MXksFWqsLg%3D 10.1021/ic50031a004
44. G.R. Choppin J.A. Chopoorian 1961 Complexes of the lanthanide elements with α-hydroxy carboxylate ligands J. Inorg. Nucl. Chem. 22 97 113 1:CAS:528:DyaF38XntFGmug%3D%3D 10.1016/0022-1902(61)80234-0
45. K. Bukietynska A. Mondry E. Osmȩda 1981 Application of the oscillator strength of "hypersensitive" transitions to the investigation of complex equilibria of lanthanide ions. II. Spectroscopy, stability and thermodynamics of lanthanide complexes with monocarboxylic and α-hydroxy acids J. Inorg. Nucl. Chem. 43 1321 1330 1:CAS:528: DyaL3MXltVCjtLg%3D 10.1016/0022-1902(81)80037-1
46. H. Deelstra F. Verbeek 1964 The determination of the stability constants of the lanthanide α-hydroxyisobutyrate and lactate complexes by potentiometric titration Anal. Chim. Acta 31 251 257 1:CAS:528: DyaF2MXhvFaktg%3D%3D 10.1016/S0003-2670(00)88816-9
47. D. Jalon-Dalmais M. Petit-Ramel G. Thomas-David 1981 Etude protometrique et polarimetrique des complexes de l'acide L(+) lactique avec le neodyme, le praseodyme et le samarium C. R. Acad. Sc. Paris 292 II 833 836 1:CAS:528:DyaL3MXlsFOlsLk%3D
48. A. Aziz S.J. Lyle J.E. Newbery 1971 Europium(III) complexes with propionate, lactate, pyruvate and α-alaninate in aqueous solution J. Inorg. Nucl. Chem. 33 1757 1764 1:CAS:528:DyaE3MXkvVWjs78%3D 10.1016/0022-1902(71)80613-9
49. 4+ and $\mathrm[UO]-[2][2+]$ Acta Chem. Scand. A 38 501 512 10.3891/acta.chem.scand.38a-0501
50. G.R. Choppin P. Thakur J.N. Mathur 2006 Complexation thermodynamics and structural aspects of actinide-aminopolycarboxylates Coord. Chem. Rev. 250 936 947 1:CAS:528:DC%2BD28Xjsl2ru78%3D 10.1016/j.ccr.2006.02.003
51. Grimes, T., Nilsson, M., Nash, K.L.: Lactic acid partitioning in TALSPEAK. Sep. Sci. Technol. 45 (2010, in press)