Understanding persulfate production at boron doped diamond film anodes

Electrochimica Acta

Volumn 150, Issue , 2014, Pages 68-74

  Davis, Jake ^a   Baygents, James C ^a   Farrell, James ^a  

^a University of Arizona   (United States)

Author keywords

Anode; BDD; Boron doped diamond; Electrosynthesis; Persulfate

Indexed keywords

ANODES; CHEMISORPTION; DENSITY FUNCTIONAL THEORY; DIAMOND FILMS; DIAMONDS; EXPERIMENTS; OXIDATION; REACTION INTERMEDIATES; ROTATING DISKS; SULFUR COMPOUNDS;

BDD; BORON DOPED DIAMOND; BORON-DOPED DIAMOND FILMS; DIRECT ELECTRON TRANSFER; ELECTROSYNTHESIS; PERSULFATE; ROTATING DISK ELECTRODES; SULFURIC ACID SOLUTION;

FREE RADICAL REACTIONS;

EID: 84909584443     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2014.10.104     Document Type: Article

References (34)

1. F. Ullmann, Y.S., Yamamoto, F.T., Campbell, R., Pfefferkorn, J.F., Rounsaville, Ullmann's encyclopedia of industrial chemistry, Volume 1, Issue 7, VCH, 1991. http://books.google.com/books?id=AMRTAAAAMAAJ&pgis=1 (accessed September 29, 2014).
2. CRC Handbook of Chemistry and Physics, 93rd Edition, CRC Press, 2012. http://books.google.com/books?id=-BzP7Rkl7WkC&pgis=1 (accessed September 12, 2014).
3. R. Kirk, Kirk-Othmer encyclopedia of chemical technology, (2000)
4. K.J. Radimer, M.J., McCarthy, Electrolytic production of sodium persulfate, US4144144 A, 1979. http://www.google.com/patents/US4144144 (accessed September 29, 2014).
5. W. Smit, J. Hoogland, The mechanism of the anodic formation of the peroxodisulphate ion on platinum-III. elaboration of experimental results, Electrochim. Acta. 16 (1971) 961-979. . (accessed September 29, 2014) http://www.sciencedirect.com/science/article/pii/0013468671850600.
6. W. Smit, J.G. Hoogland, The mechanism of the anodic formation of the peroxodisulphate ion on platinum-IV. influence of alkali-metal cations, Electrochim. Acta. (1971) 1-13.
7. W. Smit, J. Hoogland, The mechanism of the anodic formation of peroxodisulphate ion on platinum-II. Time dependence of the anode potential, Electrochim. Acta. 16 (1971) 821-831.
8. W. Smit, J. Hoogland, The mechanism of the anodic formation of the peroxodisulphate ion on platinum-I. establishment of the participating anion, Electrochim. Acta. 16 (1971) . . (accessed September 29, 2014) http://www.sciencedirect.com/science/article/pii/001346867185123X.
9. J. SCHULTZE, WATER ADSORPTION ON PLATINUM ELECTRODES IN AQUEOUS ELECTROLYTES, BER BUNSENGES. 73 (1969) 483 http://scholar.google.com/scholar-lookup?issue=5&journal=BERICHTEDERBUNSEN-GESELLSCHAFTFURPHYSIKALISCHECHEMIE&hl=en&pages=483-%26&title=ADSORPTIONOFWATERONPLATINUMELECTRODESINAQUEOUSELECTROLYTES&author=JSCHULTZE&publication-year=1969&volume=73#0 (accessed September 29, 2014)
10. F. Foerster, Elektrochemie wasseriger lösungen, (1922) xx, 900 p. http://catalog.hathitrust.org/Record/006496910.
11. P. Michaud, E. Mahé,W. Haenni, A. Perret, C. Comninellis, Preparation of Peroxodisulfuric Acid Using Boron-Doped Diamond Thin Film Electrodes, 3 (2007) 77-79
12. K. Serrano, P. Michaud, C. Comninellis, A. Savall, Electrochemical preparation of peroxodisulfuric acid using boron doped diamond thin film electrodes, Electrochim. Acta. 48 (2002) 431-436.
13. J. Davis, J. Baygents, J. Farrell, Effect of current density and sulfuric acid concentration on persulfuric acid generation by boron-doped diamond film anodes, J. Appl. Electrochem. (2014).
14. H.B. Martin, A. Argoitia, U. Landau, Hydrogen oxygen evolution on boron-doped diamond electrodes, J. (1996)
15. B. Chaplin, I. Wyle, H. Zeng, J. Carlisle, J. Farrell, Characterization of the performance and failure mechanisms of boron-doped ultrananocrystalline diamond electrodes, J. Appl. Electrochem. 41 (2011) 1329-1340.
16. B. Chaplin, D. Hubler, J. Farrell, Understanding anodic wear at boron doped diamond film electrodes, Electrochim. Acta. 89 (2013) 122-131.
17. M.C. Granger, M. Witek, J. Xu, J. Wang, M. Hupert, A. Hanks, et al., Standard Electrochemical Behavior of High-Quality, Boron-Doped Polycrystalline Diamond Thin-Film Electrodes, Anal, Chem. 72 (2000)3793-3804, doi: http://dx.doi.org/10.1021/ac0000675.
18. J.-S. Filhol, M. Neurock, Elucidation of the electrochemical activation of water over Pd by first principles, Angew. Chem. Int. Ed. Engl. 45 (2006)402-406, doi: http://dx.doi.org/10.1002/anie.200502540.
19. L.N. Kostadinov, A.B. Anderson, Constrained Variation Calculations of Electron- Transfer Transition States Using the Lagrange Method, Electrochem. Solid-State Lett. 6 (2003)E30, doi: http://dx.doi.org/10.1149/1.1607571.
20. J. Vatamanu, O. Borodin, G.D. Smith, Molecular dynamics simulations of atomically flat and nanoporous electrodes with a molten salt electrolyte, Phys. Chem. Chem. Phys. 12 (2010)170-182, doi:http://dx.doi.org/10.1039/b917592j.
21. C. Taylor, S. Wasileski, J.-S. Filhol, M. Neurock, First principles reaction modeling of the electrochemical interface: Consideration and calculation of a tunable surface potential from atomic and electronic structure, Phys. Rev. B. 73 (2006)165402, doi: http://dx.doi.org/10.1103/PhysRevB.73.165402.
22. B. Delley, From molecules to solids with the DMol[sup 3] approach, J. Chem. Phys. 113 (2000)7756, doi: http://dx.doi.org/10.1063/1.1316015.
23. B. Delley, An all-electron numerical method for solving the local density functional for polyatomic molecules, J. Chem. Physics 92 (1990)508, doi: http://dx.doi.org/10.1063/1.458452.
24. Materials Studio, (n.d.). http://accelrys.com/products/materials-studio/.
25. B. Delley, Fast Calculation of Electrostatics in Crystals and Large Molecules, J. Phys. Chem. 100 (1996)6107-6110, doi:http://dx.doi.org/10.1021/jp952713n.
26. B. Delley, The conductor-like screening model for polymers and surfaces, Mol. Simul. 32 (2006)117-123, doi:http://dx.doi.org/10.1080/08927020600589684.
27. C.P. Kelly, C.J. Cramer, D.G. Truhlar, Adding explicit solvent molecules to continuum solvent calculations for the calculation of aqueous acid dissociation constants, J. Phys. Chem. A. 110 (2006)2493-2499, doi:http://dx.doi.org/10.1021/jp055336f.
28. D. Mishra, Z. Liao, J. Farrell, Understanding Reductive Dechlorination of Trichloroethene on Boron-Doped Diamond Film Electrodes, Environ. Sci. Technol. 42 (2008)9344-9349, doi:http://dx.doi.org/10.1021/es801815z.
29. A.B. Anderson, D.B. Kang, Quantum Chemical Approach to Redox Reactions Including Potential Dependence: Application to a Model for Hydrogen Evolution from Diamond, J. Phys. Chem. A. 102 (1998)5993-5996, doi: http://dx.doi.org/10.1021/jp9810926.
30. Y. Cai, A.B. Anderson, J.C. Angus, L.N. Kostadinov, Hydrogen Evolution on Diamond Electrodes by the Volmer-Heyrovsky Mechanism, J. Electrochem. Soc. 154 (2007)F36, doi:http://dx.doi.org/10.1149/1.2403044.
31. H. Sun, COMPASS: An ab Initio Force-Field Optimized for Condensed-Phase Applications Overview with Details on Alkane and Benzene Compounds, J. Phys. Chem. B. 102 (1998)7338-7364, doi: http://dx.doi.org/10.1021/jp980939v.
32. H.C. Andersen, Molecular dynamics simulations at constant pressure and/or temperature, J. Chem. Phys. 72 (1980)2384, doi:http://dx.doi.org/10.1063/1.439486.
33. U. Höfker, G. Fels, SN2 - Second-order Nucleophilic Substitution, Wiley Inf. Serv. GmbH. (2014) 7 http://www.chemgapedia.de/vsengine/vlu/vsc/en/ch/12/oc/vlu-organik/substitution/sn-2/sn-2.vlu/Page/vsc/en/ch/12/oc/substitution/sn-2/aktivierungsenergie-sn2/aktivierungsenergie-sn2.vscml.html.
34. M.N. Latto, D.J. Riley, P.W. May, Impedance studies of boron-doped CVD diamond electrodes, Diam. Relat. Mater. 9 (2000)1181-1183, doi:http://dx.doi.org/10.1016/S0925-9635(99)00244-7.