Mechanistic interpretation of the effects of acid strength on alkane isomerization turnover rates and selectivity

Journal of Catalysis

Volumn 319, Issue , 2014, Pages 283-296

  Knaeble, William ^a   Carr, Robert T ^a   Iglesia, Enrique ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Acid strength; Bifunctional catalysis; Deprotonation energy; Heteropolyacids; Ion pair transition state theory; Keggin polyoxometalates; Skeletal isomerization

Indexed keywords

EID: 84908657311     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2014.09.005     Document Type: Article

References (31)

1. A. Corma Chem. Rev. 95 1995 559
2. M.J. Janik, J. Macht, E. Iglesia, and M. Neurock J. Phys. Chem. C 113 2009 1872
3. J. Macht, M.J. Janik, M. Neurock, and E. Iglesia J. Am. Chem. Soc. 130 2008 10369
4. M. Brändle, and J. Sauer J. Am. Chem. Soc. 120 1998 1556
5. A.J. Jones, R.T. Carr, S.I. Zones, and E. Iglesia J. Catal. 312 2014 58
6. J. Macht, M.J. Janik, M. Neurock, and E. Iglesia Angew. Chem., Int. Ed. 46 2007 7864
7. R. Carr, M. Neurock, and E. Iglesia J. Catal. 278 2011 78
8. J. Macht, R.T. Carr, and E. Iglesia J. Am. Chem. Soc. 131 2009 6554
9. P. Deshlahra, R.T. Carr, E. Iglesia, Ionic and covalent stabilization of intermediates and transition states in catalysis by solid acids, J. Am. Chem. Soc., submitted for publication.
10. P.B. Weisz, and E.W. Swegler Science 126 1957 31
11. M. Guisnet, F. Alvarez, G. Giannetto, and G. Perot Catal. Today 1 1987 415
12. G.D. Pirngruber, K. Seshan, and J. Lercher J. Catal. 186 1999 188
13. J.J. Cowan, C.L. Hill, R.S. Reiner, and I.A. Weinstock Inorg. Synth. 33 2002 18
14. L.C. Baker, and T.P. McCutcheon J. Am. Chem. Soc. 78 1956 4503
15. L.C. Baker, and T.P. McCutcheon J. Am. Chem. Soc. 72 1950 2374
16. D.W. Scott Chemical Thermodynamic Properties of Hydrocarbons and Related Substances: Properties of the Alkane Hydrocarbons, C1 through C10, in the Ideal Gas State from 0 to 1500 K 1974 U.S. Bureau of Mines Washington
17. C.D. Baertsch, K.T. Komala, Y.-H. Chua, and E. Iglesia J. Catal. 205 2002 44
18. N. Mizuno, and M. Misono Chem. Rev. 98 1998 199
19. B.B. Bardin, and R.J. Davis Appl. Catal., A 200 2000 219
20. M. Janik, B. Bardin, R. Davis, and M. Neurock J. Phys. Chem. B 110 2006 4170
21. X. Rozanska, P. Sautet, F. Delbecq, F. Lefebvre, S. Borshch, H. Chermette, J.-M. Basset, and E. Grinenval Phys. Chem. Chem. Phys. 13 2011 15955
22. T. Okuhara, N. Mizuno, and M. Misono Adv. Catal. 41 1996 113
23. G. Djéga-Mariadassou, and M. Boudart J. Catal. 216 2003 89
24. R. Madon, and M. Boudart Ind. Eng. Chem. Fundam. 21 1982 438
25. J. Macht, R.T. Carr, and E. Iglesia J. Catal. 264 2009 54
26. V.B. Kazansky Acc. Chem. Res. 24 1991 379
27. M.A. Natal-Santiago, R. Alcalá, and J.A. Dumesic J. Catal. 181 1999 124
28. M. Boronat, P. Viruela, and A. Corma J. Phys. Chem. 100 1996 16514
29. T. Demuth, X. Rozanska, L. Benco, J. Hafner, R.A. van Santen, and H. Toulhoat J. Catal. 214 2003 68
30. A L.L. East, T. Bucko, and J. Hafner J. Phys. Chem. A 111 2007 5945
31. R.A. Alberty, and C.A. Gehrig J. Phys. Chem. Ref. Data 14 1985 803