Mechanistic consequences of composition in acid catalysis by polyoxometalate keggin clusters

Journal of the American Chemical Society

Volumn 130, Issue 31, 2008, Pages 10369-10379

  Macht, Josef ^a   Janik, Michael J ^b   Neurock, Matthew ^c   Iglesia, Enrique ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b The Pennsylvania State University   (United States)

^c UNIVERSITY OF VIRGINIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACIDS; ALCOHOLS; ATOMIC PHYSICS; ATOMS; BROMINE COMPOUNDS; CATALYSIS; CHARGE DENSITY; CHARGE DISTRIBUTION; CHLORINE COMPOUNDS; COBALT; DEHYDRATION; DEUTERIUM; DEWATERING; DIFFERENCE EQUATIONS; DIMERS; DYES; DYNAMICS; ENTHALPY; EQUILIBRIUM CONSTANTS; ETHERS; FORMING; GARNETS; IONS; ISOMERS; ISOTOPES; OLEFINS; OLIGOMERS; ORGANIC COMPOUNDS; PHASE EQUILIBRIA; PROTONS; SENSITIVITY ANALYSIS; SILICA; SILICATE MINERALS; SILICON; STABILIZATION; THERMODYNAMICS;

2-BUTANOL; 2-PROPANOL; ACID CATALYSIS; ACID CATALYSTS; ACID STRENGTHS; ALKANOL; ALKANOLS; ANIONIC CLUSTERS; CATALYTIC RATES; CATIONIC FRAGMENTS; CLEAVAGE REACTIONS; COMPENSATION EFFECTS; CONJUGATE BASES; DEHYDRATION RATES; DOUBLE-BOND ISOMERIZATION; ELEMENTARY STEPS; ELIMINATION RATES; ETHER CLEAVAGE; IN TRANSITIONS; ION TRANSITIONS; ION-PAIRS; KINETIC ISOTOPE EFFECTS; KINETICS AND MECHANISMS; MINERAL ACIDS; ORGANIC MOIETIES; POLYOXOMETALATE; PROTON AFFINITIES; RATE EQUATIONS; STABILIZATION ENERGIES; STEREOSELECTIVITIES; TERT-BUTANOL; THEORETICAL CALCULATIONS; TRANSITION STATE; TRANSITION STATES;

RATE CONSTANTS;

ALKANOL; ALKENE; BRONSTED ACID; ETHER;

ARTICLE; CATALYSIS; CHEMICAL BOND; CHEMICAL COMPOSITION; CHEMICAL REACTION; CHEMICAL STRUCTURE; DEHYDRATION; ENTHALPY; ISOMERIZATION; KINETICS; PROTON TRANSPORT;

EID: 48749130109     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja803114r     Document Type: Article

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