Spectroscopic and Computational Investigation of Iron(III) Cysteine Dioxygenase: Implications for the Nature of the Putative Superoxo-Fe(III) Intermediate

Biochemistry

Volumn 53, Issue 36, 2014, Pages 5759-5770

  Blaesi, Elizabeth J ^a   Fox, Brian G ^a   Brunold, Thomas C ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMINO ACIDS; COMPUTATION THEORY; DENSITY FUNCTIONAL THEORY; DICHROISM; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONIC STRUCTURE; IRON; MAGNETIC RESONANCE; MOLECULAR OXYGEN; OXYGEN; PARAMAGNETIC RESONANCE; PH; REACTION INTERMEDIATES; SULFUR;

CATALYTIC MECHANISMS; COMPUTATIONAL INVESTIGATION; COORDINATION SITES; CYSTEINE DIOXYGENASE; ELECTRONIC ABSORPTION; MAGNETIC CIRCULAR DICHROISMS; OPTIMIZED STRUCTURES; PHYSIOLOGICAL PH;

IRON COMPOUNDS;

AZIDE; CYSTEINE; CYSTEINE DIOXYGENASE; FERRIC ION; FERRIC ION CYSTEINE DIOXYGENASE; HYDROXIDE; NITROGEN; SODIUM AZIDE; SODIUM DITHIONITE; SULFUR DERIVATIVE; SUPEROXIDE; SUPEROXO FERRIC ION; UNCLASSIFIED DRUG;

ARTICLE; BINDING SITE; CIRCULAR DICHROISM; COMPLEX FORMATION; CRYSTAL STRUCTURE; DENSITY FUNCTIONAL THEORY; ELECTRON SPIN RESONANCE; ENZYME ACTIVE SITE; ENZYME ACTIVITY; HYDROGEN BOND; PH; PRIORITY JOURNAL; PROTEIN EXPRESSION; CHEMISTRY; QUANTUM THEORY;

CIRCULAR DICHROISM; CYSTEINE DIOXYGENASE; ELECTRON SPIN RESONANCE SPECTROSCOPY; FERRIC COMPOUNDS; QUANTUM THEORY; SUPEROXIDES;

EID: 84908331647     PISSN: 00062960     EISSN: 15204995     Source Type: Journal    
DOI: 10.1021/bi500767x     Document Type: Article

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