Acid-stable magnetic core-shell nanoparticles for the separation of rare earths

Industrial and Engineering Chemistry Research

Volumn 53, Issue 39, 2014, Pages 15222-15229

  Dupont, David ^a   Luyten, Jakob ^a   Bloemen, Maarten ^a   Verbiest, Thierry ^a   Binnemans, Koen ^a  

^a UNIVERSITY OF LEUVEN   (Belgium)

Author keywords

[No Author keywords available]

Indexed keywords

CORE SHELL NANOPARTICLES; FUNCTIONAL ELECTRIC STIMULATION; IRON OXIDES; MAGNETITE; METAL IONS; NANOMAGNETICS; NANOPARTICLES; RARE EARTHS; SHELLS (STRUCTURES); SILICA; SILICA NANOPARTICLES; SILICON; SYNTHESIS (CHEMICAL);

ACIDIC ENVIRONMENT; CORE SHELL; ETHYLENE DIAMINE; FUNCTIONALIZED; GRAFTING DENSITIES; MAGNETIC RETRIEVALS; RARE EARTH IONS; SUPERPARAMAGNETICS;

SIO2 NANOPARTICLES;

EID: 84907546039     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie502546c     Document Type: Article

References (48)

1. Hao, R.; Xing, R.; Xu, Z.; Hou, Y.; Gao, S.; Sun, S. Synthesis, Functionalization, and Biomedical Applications of Multifunctional Magnetic Nanoparticles Adv. Mater. 2010, 22, 2729
2. Lu, A.-H.; Salabas, E. L.; Schüth, F. Magnetic Nanoparticles: Synthesis, Protection, Functionalization, and Application Angew. Chem., Int. Ed. 2007, 46, 1222
3. Grass, R. N.; Athanassiou, E. K.; Stark, W. J. Covalently Functionalized Cobalt Nanoparticles as a Platform for Magnetic Separations in Organic Synthesis Angew. Chem., Int. Ed. 2007, 46, 4909
4. Liu, Z.; Li, B.; Wang, B.; Yang, Z.; Wang, Q.; Li, T.; Qin, D.; Li, Y.; Wang, M.; Yan, M. Magnetic Nanoparticles Modified with DTPA-AMC-Rare Earth for Fluorescent and Magnetic Resonance Dual Mode Imaging Dalton Trans. 2012, 41, 8723
5. 4 Nanoparticles for Imaging Applications Angew. Chem., Int. Ed. 2011, 50, 3063
6. 4 Nanoparticles Coupled with a Fluorescent Eu Complex for Dual Imaging Applications Chem. Commun. 2012, 48, 2952
7. 2+ Langmuir 2010, 26, 12247
8. 4 Magnetic Nano-Particles Chem. Eng. J. 2013, 218, 46
9. 4 Adsorbent: Preparation, Characterization, and Application in Heavy Metal Adsorption Chem. Eng. J. 2013, 226, 300
10. 2+ in Aqueous Solution New J. Chem. 2011, 35, 2697
11. Warner, C. L.; Addleman, R. S.; Cinson, A. D.; Droubay, T. C.; Engelhard, M. H.; Nash, M. A.; Yantasee, W.; Warner, M. G. High-Performance, Superparamagnetic, Nanoparticle-Based Heavy Metal Sorbents for Removal of Contaminants from Natural Waters ChemSusChem 2010, 3, 749
12. Rossier, M.; Koehler, F. M.; Athanassiou, E. K.; Grass, R. N.; Aeschlimann, B.; Gunther, D.; Stark, W. J. Gold Adsorption on the Carbon Surface of C/Co Nanoparticles Allows Magnetic Extraction from Extremely Diluted Aqueous Solutions J. Mater. Chem. 2009, 19, 8239
13. Rossier, M.; Koehler, F. M.; Athanassiou, E. K.; Grass, R. N.; Waelle, M.; Birbaum, K.; Günther, D.; Stark, W. J. Energy-Efficient Noble Metal Recovery by the Use of Acid-stable Nanomagnets Ind. Eng. Chem. Res. 2010, 49, 9355
14. Yantasee, W.; Warner, C. L.; Sangvanich, T.; Addleman, R. S.; Carter, T. G.; Wiacek, R. J.; Fryxell, G. E.; Timchalk, C.; Warner, M. G. Removal of Heavy Metals from Aqueous Systems with Thiol Functionalized Superparamagnetic Nanoparticles Environ. Sci. Technol. 2007, 41, 5114
15. Hao, Y.-M.; Man, C.; Hu, Z.-B. Effective Removal of Cu (II) Ions from Aqueous Solution by Amino-functionalized Magnetic Nanoparticles J. Hazard. Mater. 2010, 184, 392
16. Wu, D.; Sun, Y.; Wang, Q. Adsorption of Lanthanum (III) from Aqueous Solution Using 2-ethylhexyl Phosphonic Acid Mono-2-ethylhexyl Ester-Grafted Magnetic Silica Nanocomposites J. Hazard. Mater. 2013, 260, 409
17. 5+ Removal: Adsorbent Regeneration and Reuse Ind. Eng. Chem. Res. 2014, 10.1021/ie500912k
18. Zargoosh, K.; Abedini, H.; Abdolmaleki, A.; Molavian, M. R. Effective Removal of Heavy Metal Ions from Industrial Wastes Using Thiosalicylhydrazide-Modified Magnetic Nanoparticles Ind. Eng. Chem. Res. 2013, 52, 14944
19. 3+ Ion Adsorption Properties J. Mater. Sci. 2014, 49, 3478
20. Koehler, F. M.; Rossier, M.; Waelle, M.; Athanassiou, E. K.; Limbach, L. K.; Grass, R. N.; Gunther, D.; Stark, W. J. Magnetic EDTA: coupling heavy metal chelators to metal nanomagnets for rapid removal of cadmium, lead and copper from contaminated water Chem. Commun. 2009, 4862
21. 4@Humic Acid Magnetic Nanoparticles ACS Appl. Mater. Interfaces 2012, 4, 6891
22. 2+ J. Nanopart. Res. 2013, 15, 1
23. 2 Core-Shell Microspheres and their Application to the Highly Specific Capture of Phosphopeptides for MALDI-TOF MS Analysis Chem. Commun. 2008, 5, 564
24. Huang, C.; Hu, B. Silica-coated Magnetic Nanoparticles Modified with γ-Mercaptopropyltrimethoxysilane for Fast and Selective Solid Phase Extraction of Trace Amounts of Cd, Cu, Hg, and Pb in Environmental and Biological Samples Prior to their Determination by Inductively Coupled Plasma Mass Spectrometry Spectrochim. Acta, Part B 2008, 63, 437
25. Saman, N.; Johari, K.; Mat, H. Adsorption Characteristics of Sulfur-Functionalized Silica Microspheres with Respect to the Removal of Hg(II) from Aqueous Solutions Ind. Eng. Chem. Res. 2014, 53, 1225
26. Dupont, D.; Brullot, W.; Bloemen, M.; Verbiest, T.; Binnemans, K. Selective Uptake of Rare Earths from Aqueous Solutions by EDTA-functionalized Magnetic and Non-magnetic Nanoparticles ACS Appl. Mater. Interfaces 2014, 6, 4980
27. Wei, S.; Wang, Q.; Zhu, J.; Sun, L.; Lin, H.; Guo, Z. Multifunctional Composite Core-Shell Nanoparticles Nanoscale 2011, 3, 4474
28. Schartl, W. Current Directions in Core-shell Nanoparticle Design Nanoscale 2010, 2, 829
29. Ghosh Chaudhuri, R.; Paria, S. Core/Shell Nanoparticles: Classes, Properties, Synthesis Mechanisms, Characterization, and Applications Chem. Rev. 2011, 112, 2373
30. 2 Core-Shell Nanoparticles with Tunable Properties ACS Nano 2008, 2, 847
31. 4 Seeds Nanoscale 2011, 3, 701
32. 2 Core/Shell Nanoparticles: The Silica Coating Regulations with a Single Core for Different Core Sizes and Shell Thicknesses Chem. Mater. 2012, 24, 4572
33. Witucki, G. L. A Silane Primer-Chemistry and Applications of Alkoxy Silanes J. Coat. Technol. 1993, 65, 57
34. Hermanson, G. T. In Bioconjugate Techniques, 2 nd ed.; Hermanson, G. T., Ed.; Academic Press: New York, 2008; pp 562-581.
35. De Palma, R.; Peeters, S.; Van Bael, M. J.; Van den Rul, H.; Bonroy, K.; Laureyn, W.; Mullens, J.; Borghs, G.; Maes, G. Silane Ligand Exchange to Make Hydrophobic Superparamagnetic Nanoparticles Water-Dispersible Chem. Mater. 2007, 19, 1821
36. Fadeev, A. Y.; McCarthy, T. J. Self-Assembly Is Not the Only Reaction Possible Between Alkyltrichlorosilanes and Surfaces: Monomolecular and Oligomeric Covalently Attached Layers of Dichloro- and Trichloroalkylsilanes on Silicon Langmuir 2000, 16, 7268
37. Onclin, S.; Ravoo, B. J.; Reinhoudt, D. N. Engineering Silicon Oxide Surfaces Using Self-Assembled Monolayers Angew. Chem., Int. Ed. 2005, 44, 6282
38. Tucker-Schwartz, A. K.; Farrell, R. A.; Garrell, R. L. Thiol-ene Click Reaction as a General Route to Functional Trialkoxysilanes for Surface Coating Applications J. Am. Chem. Soc. 2011, 133, 11026
39. Larsen, B. A.; Hurst, K. M.; Ashurst, W. R.; Serkova, N. J.; Stoldt, C. R. Mono and Dialkoxysilane Surface Modification of Superparamagnetic Iron Oxide Nanoparticles for Application as Magnetic Resonance Imaging Contrast Agents J. Mater. Res. 2012, 27, 1846
40. Bloemen, M.; Brullot, W.; Luong, T. T.; Geukens, N.; Gils, A.; Verbiest, T. Improved Functionalization of Oleic Acid-Coated Iron Oxide Nanoparticles for Biomedical Applications J. Nanopart. Res. 2012, 14, 1100
41. Wu, W.; He, Q. G.; Jiang, C. Z. Magnetic Iron Oxide Nanoparticles: Synthesis and Surface Functionalization Strategies Nanoscale Res. Lett. 2008, 3, 397
42. Xie, F.; Zhang, T. A.; Dreisinger, D.; Doyle, F. A Critical Review on Solvent Extraction of Rare Earths from Aqueous Solutions Miner. Eng. 2014, 56, 10
43. Choppin, G. R.; Goedken, M. P.; Gritmon, T. F. The Complexation of Lanthanides by Aminocarboxylate Ligands-II J. Inorg. Nucl. Chem. 1977, 39, 2025
44. Cotton, S. In Lanthanide and Actinide Chemistry; Wiley: Chichester, U.K., 2006; Chapter 4, pp 35-60.
45. Brullot, W.; Reddy, N. K.; Wouters, J.; Valev, V. K.; Goderis, B.; Vermant, J.; Verbiest, T. Versatile Ferrofluids Based on Polyethylene Glycol Coated Iron Oxide Nanoparticles J. Magn. Magn. Mater. 2012, 324, 1919
46. Huang, S.-H.; Chen, D.-H. Rapid Removal of Heavy Metal Cations and Anions from Aqueous Solutions by an Amino-functionalized Magnetic Nano-Adsorbent J. Hazard. Mater. 2009, 163, 174
47. 4 Magnetic Nanoparticles for Removal of Cu(II) Ions J. Colloid Interface Sci. 2005, 283, 446
48. Vander Hoogerstraete, T.; Wellens, S.; Verachtert, K.; Binnemans, K. Removal of Transition Metals from Rare earths by Solvent Extraction with an Undiluted Phosphonium Ionic Liquid: Separations Relevant to Rare-earth Magnet Recycling Green Chem. 2013, 15, 919