Magnetic EDTA-modified chitosan/SiO2/Fe3O4 adsorbent: Preparation, characterization, and application in heavy metal adsorption

Chemical Engineering Journal

Volumn 226, Issue , 2013, Pages 300-311

  Ren, Yong ^a   Abbood, Hayder A ^a,b   He, Fengbo ^a   Peng, Hong ^a   Huang, Kaixun ^a  

^a HUAZHONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

^b UNIVERSITY OF BASRAH   (Iraq)

Author keywords

Adsorption; Chitosan; EDTA; Heavy metal; Magnetic separation; Modification

Indexed keywords

ADSORPTION PROPERTIES; EDTA; EXPERIMENTAL CONDITIONS; HEAVY METAL ADSORPTION; MODIFICATION; PSEUDO-SECOND-ORDER KINETIC MODELS; REMOVAL OF HEAVY METAL IONS; WATER SOLUBLE CARBODIIMIDE;

ADSORPTION; CHITOSAN; HEAVY METALS; LEAD; MAGNETIC SEPARATION; METAL IONS;

CADMIUM COMPOUNDS;

EID: 84877895216     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2013.04.059     Document Type: Article

References (46)

1. Fu F., Wang Q. Removal of heavy metal ions from wastewaters: a review. J. Environ. Manage. 2011, 92:407-418.
2. Gode F., Pehlivan E. Removal of chromium(III) from aqueous solutions using Lewatit S 100: the effect of pH, time, metal concentration and temperature. J. Hazard. Mater. 2006, 136:330-337.
3. Landaburu-Aguirre J., Pongracz E., Peramaki P., Keiski R.L. Micellar-enhanced ultrafiltration for the removal of cadmium and zinc: use of response surface methodology to improve understanding of process performance and optimisation. J. Hazard. Mater. 2010, 180:524-534.
4. Nanseu-Njiki C.P., Tchamango S.R., Ngom P.C., Darchen A., Ngameni E. Mercury(II) removal from water by electrocoagulation using aluminium and iron electrodes. J. Hazard. Mater. 2009, 168:1430-1436.
5. 2+ from wastewater with a chelating agent and reverse osmosis processes. Desalination 2007, 217:276-281.
6. Lertlapwasin R., Bhawawet N., Imyim A., Fuangswasdi S. Ionic liquid extraction of heavy metal ions by 2-aminothiophenol in 1-butyl-3-methylimidazolium hexafluorophosphate and their association constants. Sep. Purif. Technol. 2010, 72:70-76.
7. Wu G., Kang H., Zhang X., Shao H., Chu L., Ruan C. A critical review on the bio-removal of hazardous heavy metals from contaminated soils: issues, progress, eco-environmental concerns and opportunities. J. Hazard. Mater. 2010, 174:1-8.
8. Ali I. New generation adsorbents for water treatment. Chem. Rev. 2012, 112:5073-5091.
9. Baccar R., Bouzid J., Feki M., Montiel A. Preparation of activated carbon from Tunisian olive-waste cakes and its application for adsorption of heavy metal ions. J. Hazard. Mater. 2009, 162:1522-1529.
10. Guibal E. Interactions of metal ions with chitosan-based sorbents: a review. Sep. Purif. Technol. 2004, 38:43-74.
11. Wu F.C., Tseng R.L., Juang R.S. A review and experimental verification of using chitosan and its derivatives as adsorbents for selected heavy metals. J. Environ. Manage. 2010, 91:798-806.
12. 4 porous magnetic microspheres for aqueous Pb(II) removal. J. Mater. Chem. 2011, 21:16550-16557.
13. Philippova O., Barabanova A., Molchanov V., Khokhlov A. Magnetic polymer beads: recent trends and developments in synthetic design and applications. Eur. Polym. J. 2011, 47:542-559.
14. Donia A.M., Atia A.A., Elwakeel K.Z. Selective separation of mercury(II) using magnetic chitosan resin modified with Schiff's base derived from thiourea and glutaraldehyde. J. Hazard. Mater. 2008, 151:372-379.
15. 4-chitosan nanoparticles under UV irradiation in aqueous system. Curr. Appl. Phys. 2010, 10:828-833.
16. Chen Y., Wang J. Preparation and characterization of magnetic chitosan nanoparticles and its application for Cu(II) removal. Chem. Eng. J. 2011, 168:286-292.
17. Wang J., Zheng S., Shao Y., Liu J., Xu Z., Zhu D. Amino-functionalized Fe(3)O(4)@SiO(2) core-shell magnetic nanomaterial as a novel adsorbent for aqueous heavy metals removal. J. Colloid Interface Sci. 2010, 349:293-299.
18. Hu X.J., Wang J.S., Liu Y.G., Li X., Zeng G.M., Bao Z.L., Zeng X.X., Chen A.W., Long F. Adsorption of chromium (VI) by ethylenediamine-modified cross-linked magnetic chitosan resin: isotherms, kinetics and thermodynamics. J. Hazard. Mater. 2011, 185:306-314.
19. Monier M., Ayad D.M., Wei Y., Sarhan A.A. Adsorption of Cu(II), Co(II), and Ni(II) ions by modified magnetic chitosan chelating resin. J. Hazard. Mater. 2010, 177:962-970.
20. 2+ from aqueous solutions. Colloid. Surface. B 2011, 88:574-581.
21. 2+ from aqueous solution by chitosan-coated magnetic nanoparticles modified with α-ketoglutaric acid. J. Colloid Interf. Sci. 2009, 330:29-37.
22. Zhu Y., Hu J., Wang J. Competitive adsorption of Pb(II), Cu(II) and Zn(II) onto xanthate-modified magnetic chitosan. J. Hazard. Mater. 2012, 221-222:155-161.
23. 2+ by imine-functionalized magnetic nanoparticles with tunable selectivity. Langmuir 2012, 28:468-473.
24. 4 nanoparticles via zero-length emulsion crosslinking method. Appl. Surf. Sci. 2009, 256:27-32.
25. Wang H., Chen Q.W., Chen J., Yu B.X., Hu X.Y. Carboxyl and negative charge-functionalized superparamagnetic nanochains with amorphous carbon shell and magnetic core: synthesis and their application in removal of heavy metal ions. Nanoscale 2011, 3:4600-4603.
26. Deng H., Li X., Peng Q., Wang X., Chen J., Li Y. Monodisperse magnetic single-crystal ferrite microspheres. Angew. Chem. Int. Ed. 2005, 44:2782-2785.
27. 2@PMMA core-shell-shell magnetic microspheres for highly efficient enrichment of peptides and proteins for MALDI-ToF MS analysis. Angew. Chem. Int. Ed. 2010, 49:607-611.
28. Sayin S., Yilmaz M. Synthesis of a new calixarene derivative and its immobilization onto magnetic nanoparticle surfaces for excellent extractants toward Cr(VI), As(V), and U(VI). J. Chem. Eng. Data 2011, 56:2020-2029.
29. Li Z.C., Fan H.T., Zhang Y., Chen M.X., Yu Z.Y., Cao X.Q., Sun T. Cd(II)-imprinted polymer sorbents prepared by combination of surface imprinting technique with hydrothermal assisted sol-gel process for selective removal of cadmium(II) from aqueous solution. Chem. Eng. J. 2011, 171:703-710.
30. Monier M., Ayad D.M., Wei Y., Sarhan A.A. Preparation and characterization of magnetic chelating resin based on chitosan for adsorption of Cu(II), Co(II), and Ni(II) ions. React. Funct. Polym. 2010, 70:257-266.
31. 2 microspheres. J. Mater. Process. Technol. 2009, 209:3218-3225.
32. Najafi M., Yousefi Y., Rafati A.A. Synthesis, characterization and adsorption studies of several heavy metal ions on amino-functionalized silica nano hollow sphere and silica gel. Sep. Purif. Technol. 2012, 85:193-205.
33. Repo E., Warchol J.K., Kurniawan T.A., Sillanpää M.E.T. Adsorption of Co(II) and Ni(II) by EDTA- and/or DTPA-modified chitosan: kinetic and equilibrium modeling. Chem. Eng. J. 2010, 161:73-82.
34. 2+ from aqueous solution by polymer-modified magnetic nanoparticles. J. Hazard. Mater. 2012, 211-212:366-372.
35. +. J. Hazard. Mater. 2011, 194:193-201.
36. Repo E., Warchol J.K., Bhatnagar A., Sillanpaa M. Heavy metals adsorption by novel EDTA-modified chitosan-silica hybrid materials. J. Colloid Interf. Sci. 2011, 358:261-267.
37. Zhou L., Wang Y., Liu Z., Huang Q. Characteristics of equilibrium, kinetics studies for adsorption of Hg(II), Cu(II), and Ni(II) ions by thiourea-modified magnetic chitosan microspheres. J. Hazard. Mater. 2009, 161:995-1002.
38. Hao Y.M., Man C., Hu Z.B. Effective removal of Cu (II) ions from aqueous solution by amino-functionalized magnetic nanoparticles. J. Hazard. Mater. 2010, 184:392-399.
39. Chen Y., Hu J., Wang J. Kinetics and thermodynamics of Cu(II) biosorption on to a novel magnetic chitosan composite bead. Environ. Technol. 2012, 33:2345-2351.
40. 4 nanoadsorbent for the removal of mercury from aqueous solutions. J. Colloid Interf. Sci. 2012, 365:204-212.
41. Peng Q., Liu Y., Zeng G., Xu W., Yang C., Zhang J. Biosorption of copper(II) by immobilizing Saccharomyces cerevisiae on the surface of chitosan-coated magnetic nanoparticles from aqueous solution. J. Hazard. Mater. 2010, 177:676-682.
42. Schmid R.W., Reilley C.N. A rapid electrochemical method for the determination of metal chelate stability constants. J. Am. Chem. Soc. 1956, 78:5513-5518.
43. Vitali L., Laranjeira M.C., Goncalves N.S., Favere V.T. Spray-dried chitosan microspheres containing 8-hydroxyquinoline-5 sulphonic acid as a new adsorbent for Cd(II) and Zn(II) ions. Int. J. Biol. Macromol. 2008, 42:152-157.
44. Tran H.V., Tran L.D., Nguyen T.N. Preparation of chitosan/magnetite composite beads and their application for removal of Pb(II) and Ni(II) from aqueous solution. Mater. Sci. Eng. C - Mater. Biol. Appl. 2010, 30:304-310.
45. Zhang G., Qu R., Sun C., Ji C., Chen H., Wang C., Niu Y. Adsorption for metal ions of chitosan coated cotton fiber. J. Appl. Polym. Sci. 2008, 110:2321-2327.
46. Huang G., Zhang H., Shi J.X., Langrish T.A.G. Adsorption of chromium(VI) from aqueous solutions using cross-linked magnetic chitosan beads. Ind. Eng. Chem. Res. 2009, 48:2646-2651.