Crystal Engineering with Soft and Topologically Adaptable Molecular Host Frameworks

Stimulating Concepts in Chemistry

Volumn , Issue , 2005, Pages 221-234

  Holman, K Travis ^a   Ward, Michael D ^a  

^a University of Minnesota   (United States)

Author keywords

Architectural isomerism; Clathrates; Crystal engineering; Host guest chemistry; Hydrogen bonding; Inclusion compounds; Supramolecular chemistry; Template synthesis

Indexed keywords

CRYSTAL ENGINEERING; HYDROGEN BONDS; ISOMERS; MOLECULES; PLANTS (BOTANY); PORE SIZE; STEREOCHEMISTRY; SUPRAMOLECULAR CHEMISTRY; SYNTHESIS (CHEMICAL);

ARCHITECTURAL ISOMERISM; CLATHRATES; HOSTGUEST CHEMISTRY; INCLUSION COMPOUNDS; TEMPLATE SYNTHESIS;

CONFORMATIONS;

EID: 84906259650     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/3527605746.ch15     Document Type: Chapter

References (29)

1. G. Alberti, R. Vivani, F. Marmottini, P. Zappelli, P, "Microporous solids based on pillared metal(IV) phosphates and phosphonates", J. Porous Mater. 1998, 5, 205-220.
2. A. Clearfield, "Organically pillared micro- and mesoporous materials", Chem. Mater. 1998, 10, 2801-2810.
3. "Molecular inclusion and molecular recognition. Clathrates I & II", Topics in Current Chemistry, Vol. 140 and 149 (Ed. E. Weber), Springer-Verlag, New York, 1987 and 1988.
4. O. Ermer, L. Lindenberg, Lorenz, "Double-diamond inclusion compounds of 2,6-dimethylideneadamantane-1,3,5,7-tetracarboxylic acid", Helv. Chim. Acta 1991, 74, 825-8277.
5. P. Brunet, M. Simard, J. D. Wuest, "Molecular tectonics. Porous hydrogen-bonded networks with unprecedented structural integrity", J. Am. Chem. Soc. 1997, 119, 2737-2738.
6. K. Endo, T. Koike, T. Sawaki, O. Hayashida, H. Masuda, Y. Aoyama, "Catalysis by organic solids. Stereoselective Diels-Alder reactions promoted by microporous molecular crystals having an extensive hydrogen-bonded network", J. Am. Chem. Soc. 1997, 119, 4117-4122.
7. n 5 xDMF, a single framework octahedral coordination polymer with large square channels", Angew. Chem., Int. Ed. Engl. 1995, 34, 2127-2129.
8. H. Li, M. Eddaoudi, M. O'Keeffe, O. M. Yaghi, "Design and synthesis of an exceptionally stable and highly porous metal-organic framework", Nature 1999, 402, 276-279.
9. 3]n." Science, 1999, 283, 1148-1150.
10. P. J. Hagrman, D. Hagrman, J. Zubieta, "Organicinorganic hybrid materials: from "simple" coordination polymers to organodiamine-templated molybdenum oxides" Angew. Chem., Int. Ed. 1999, 1999, 38.
11. "Structural aspects of inclusion compounds formed by organic host lattices", Inclusion Compounds, Vol. 2, (Eds. J. L. Atwood, J. E. D. Davies, D. D. MacNicol), Academic, London, 1984.
12. "Solid-State Supramolecular Chemistry: Crystal Engineering", Comprehensive Supramolecular Chemistry, Vol. 6 (Eds.: J. L. Atwood, J. E. D. Davies, D. D. MacNicol, F. Vögtle, K. S. Suslick), Pergamon, Oxford, 1996.
13. G. M. J. Schmidt, "Photodimerization in the solid state", Pure Appl. Chem. 1971, 27, 647-678.
14. G. R. Desiraju, Crystal engineering: The design of organic solids, Elsevier, New York, 1989.
15. V. A. Russell, M. C. Etter, M. D.Ward, "Layered materials by molecular design: structural enforcement by hydrogen bonding in guanidinium alkane- and arenesulfonates", J. Am. Chem. Soc. 1994, 116, 1941-1952.
16. V. A. Russell, M. C. Etter, M. D.Ward, "Guanidinium parasubstituted benzenesulfonates: competitive hydrogen bonding in layered structures and the design of nonlinear optical materials", Chem. Mater. 1994, 6, 1206-1217.
17. V. A. Russell, M. D. Ward, "Two-dimensional hydrogenbonded assemblies: the influence of sterics and competitive hydrogen bonding on the structures of guanidinium arenesulfonate networks", J. Mater. Chem. 1997, 7, 1123-1133.
18. C. Cao, H.-G. Hong, T. E. Mallouk, "Layered metal phosphates and phosphonates: from crystals to monolayers", Acc. Chem. Res. 1992, 26, 420-427.
19. S. Batten, R. Robson, "Interpenetrating nets: ordered, periodic entanglement", Angew. Chem., Int. Ed. 1998, 37, 1461-1494.
20. V. A. Russell, C. C., Evans, W. Li, M. D. Ward, "Nanoporous molecular sandwiches: pillared two-dimensional hydrogen bonded networks with adjustable porosity", Science 1997, 276, 575-579.
21. J. A. Swift, A. M. Reynolds, M. D. Ward, "Cooperative host-guest recognition in crystalline clathrates: steric guest ordering by molecular gears", Chem. Mater. 1998, 10, 4159-4168.
22. M. D. Hollingsworth, U.Werber-Zwanziger, M. E. Brown, J. D. Chaney, J. C. Huffman, K. D. M. Harris, S. P. Smart, "Spring-loaded at the molecular level: relaxation of guest-induced strain in channel inclusion compounds", J. Am. Chem. Soc. 1999, 1999, 121.
23. A. M. Pivovar, M. D. Ward, unpublished results.
24. J. A. Swift, A. M. Pivovar, A. M. Reynolds, M. D. Ward, "Template-directed architectural isomerism of open molecular frameworks: engineering of crystalline clathrates", J. Am. Chem. Soc. 1998, 120, 5887-5894.
25. M. E. Davis, A. Katz, W. R. Ahmad, "Rational catalyst design via imprinted nanostructured materials", Chem. Mater. 1996, 8, 1820-1839.
26. Q. Huo, D. I. Margolese, G. D. Stucky, "Surfactant control of phases in the synthesis of mesoporous silica-based materials", Chem. Mater. 1996, 8, 1147-1160.
27. J. A. Swift, M. D. Ward, "Cooperative Polar Ordering of Acentric Guest Molecules in Topologically Controlled Host Frameworks", Chem. Mater. 2000, 12, 1501-1504.
28. C. C. Evans, L. Sukarto, M. D. Ward, "Sterically controlled architectural reversion in H-bonded crystalline clathrates", J. Am. Chem. Soc. 1998, 121, 320-325.
29. K. T. Holman, M. D.Ward, "Metric Engineering of Crystalline Inclusion Compounds by Structural Mimicry", Angew. Chem. Int. Ed. 2000, 39, 1653-1656.