Inappropriate use of the quasi-reversible electrode kinetic model in simulation-experiment comparisons of voltammetric processes that approach the reversible limit

Analytical Chemistry

Volumn 86, Issue 16, 2014, Pages 8408-8417

  Simonov, Alexandr N ^a   Morris, Graham P ^b   Mashkina, Elena A ^a   Bethwaite, Blair ^a   Gillow, Kathryn ^b   Baker, Ruth E ^b   Gavaghan, David J ^b   Bond, Alan M ^a  

^a MONASH UNIVERSITY   (Australia)

^b UNIVERSITY OF OXFORD   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRODES; EXPERIMENTS; ORGANOMETALLICS; RATE CONSTANTS;

AQUEOUS ELECTROLYTE; CHARGE TRANSFER COEFFICIENT; DOUBLE-LAYER CAPACITANCE; GLASSY CARBON ELECTRODES; HETEROGENEOUS ELECTRON TRANSFER RATE CONSTANT; OVERPARAMETERIZATION; STANDARD FORMAL POTENTIAL; VOLTAMMETRIC EXPERIMENTS;

COMPUTER SIMULATION;

EID: 84906256588     PISSN: 00032700     EISSN: 15206882     Source Type: Journal    
DOI: 10.1021/ac5019952     Document Type: Article

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