Organosulfates from pinene and isoprene over the pearl river delta, South China: Seasonal variation and implication in formation mechanisms

Environmental Science and Technology

Volumn 48, Issue 16, 2014, Pages 9236-9245

  He, Quan Fu ^a   Ding, Xiang ^a   Wang, Xin Ming ^a   Yu, Jian Zhen ^b   Fu, Xiao Xin ^a   Liu, Teng Yu ^a   Zhang, Zhou ^a   Xue, Jian ^b   Chen, Duo Hong ^c   Zhong, Liu Ju ^c   Donahue, Neil M ^d  

^a GUANGZHOU INSTITUTE OF GEOCHEMISTRY   (China)

^b HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Hong Kong)

^c Environmental Monitoring Center of Guangdong Province   (China)

^d CARNEGIE MELLON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANTIGEN-ANTIBODY REACTIONS; CHEMICAL REACTIONS; ELECTROSPRAY IONIZATION; ISOMERS; MONOTERPENES; NITROGEN OXIDES;

ANTHROPOGENIC POLLUTANTS; BIOGENIC PRECURSORS; FORMATION MECHANISM; LOW CONCENTRATIONS; MASTER CHEMICAL MECHANISM; NEGATIVE ELECTROSPRAY IONIZATIONS; SEASONAL VARIATION; SECONDARY ORGANIC AEROSOLS;

ISOPRENE;

2 METHYLTETROL SULFATE ESTER; ISOPRENE; ISOPRENE DERIVED ORGANOSULFATE DERIVATIVE; ORGANOSULFUR DERIVATIVE; PINENE; PINENE DERIVED NITROOXYORGANOSULFATE DERIVATIVE; SULFATE; UNCLASSIFIED DRUG; 1,3 BUTADIENE DERIVATIVE; HEMITERPENE; PENTANE; TERPENE;

AIR MASS; ATMOSPHERIC POLLUTION; CONCENTRATION (COMPOSITION); ISOPRENE; PHOTOCHEMISTRY; POLLUTION MONITORING; SEASONAL VARIATION;

AIR POLLUTION; ARTICLE; ATMOSPHERE; AUTUMN; BIOMASS BURNING; CHINA; CITY; CONTROLLED STUDY; DAY LENGTH; FIRE ECOLOGY; GEOCHEMISTRY; LIMIT OF DETECTION; LIMIT OF QUANTITATION; LIQUID CHROMATOGRAPHY; NEGATIVE ION ELECTROSPRAY; NIGHT; PARTICULATE MATTER; PHOTOCHEMISTRY; RIVER; SEASONAL VARIATION; SECONDARY ORGANIC AEROSOL; SUMMER; TANDEM MASS SPECTROMETRY; CHEMISTRY; SEASON;

CHINA; GUANGDONG; ZHUJIANG DELTA;

BUTADIENES; CHINA; HEMITERPENES; MONOTERPENES; PENTANES; RIVERS; SEASONS; SULFATES; TANDEM MASS SPECTROMETRY;

EID: 84906251840     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es501299v     Document Type: Article

References (70)

1. Guenther, A.; Hewitt, C. N.; Erickson, D.; Fall, R.; Geron, C.; Graedel, T.; Harley, P.; Klinger, L.; Lerdau, M.; Mckay, W. A.; Pierce, T.; Scholes, B.; Steinbrecher, R.; Tallamraju, R.; Taylor, J.; Zimmerman, P. A global-model of natural volatile organic-compound emissions J. Geophys. Res. 1995, 100 (D5) 8873-8892
2. Kanakidou, M.; Seinfeld, J. H.; Pandis, S. N.; Barnes, I.; Dentener, F. J.; Facchini, M. C.; Van Dingenen, R.; Ervens, B.; Nenes, A.; Nielsen, C. J.; Swietlicki, E.; Putaud, J. P.; Balkanski, Y.; Fuzzi, S.; Horth, J.; Moortgat, G. K.; Winterhalter, R.; Myhre, C. E. L.; Tsigaridis, K.; Vignati, E.; Stephanou, E. G.; Wilson, J. Organic aerosol and global climate modelling: a review Atmos. Chem. Phys. 2005, 5, 1053-1123
3. Hoyle, C. R.; Boy, M.; Donahue, N. M.; Fry, J. L.; Glasius, M.; Guenther, A.; Hallar, A. G.; Hartz, K. H.; Petters, M. D.; Petaja, T.; Rosenoern, T.; Sullivan, A. P. A review of the anthropogenic influence on biogenic secondary organic aerosol Atmos. Chem. Phys. 2011, 11 (1) 321-343
4. Nieminen, T.; Manninen, H. E.; Sihto, S. L.; Yli-Juuti, T.; Mauldin, R. L.; Petaja, T.; Riipinen, I.; Kerminen, V. M.; Kulmala, M. Connection of sulfuric acid to atmospheric nucleation in boreal forest Environ. Sci. Technol. 2009, 43 (13) 4715-4721
5. Weber, R. J.; Sullivan, A. P.; Peltier, R. E.; Russell, A.; Yan, B.; Zheng, M.; de Gouw, J.; Warneke, C.; Brock, C.; Holloway, J. S.; Atlas, E. L.; Edgerton, E. A study of secondary organic aerosol formation in the anthropogenic-influenced southeastern United States J. Geophys. Res. 2007, 112 (D13) D13302
6. Carlton, A. G.; Pinder, R. W.; Bhave, P. V.; Pouliot, G. A. To what Extent can biogenic SOA be controlled? Environ. Sci. Technol. 2010, 44 (9) 3376-3380
7. Iinuma, Y.; Boege, O.; Kahnt, A.; Herrmann, H. Laboratory chamber studies on the formation of organosulfates from reactive uptake of monoterpene oxides Phys. Chem. Chem. Phys. 2009, 11 (36) 7985-7997
8. Nozière, B.; Ekström, S.; Alsberg, T.; Holmström, S. Radical-initiated formation of organosulfates and surfactants in atmospheric aerosols Geophys. Res. Lett. 2010, 37 (5) L05806
9. Surratt, J. D.; Gómez-González, Y.; Chan, A. W. H.; Vermeylen, R.; Shahgholi, M.; Kleindienst, T. E.; Edney, E. O.; Offenberg, J. H.; Lewandowski, M.; Jaoui, M.; Maenhaut, W.; Claeys, M.; Flagan, R. C.; Seinfeld, J. H. Organosulfate formation in biogenic secondary organic aerosol J. Phys. Chem. A 2008, 112 (36) 8345-8378
10. Surratt, J. D.; Kroll, J. H.; Kleindienst, T. E.; Edney, E. O.; Claeys, M.; Sorooshian, A.; Ng, N. L.; Offenberg, J. H.; Lewandowski, M.; Jaoui, M.; Flagan, R. C.; Seinfeld, J. H. Evidence for organosulfates in secondary organic aerosol Environ. Sci. Technol. 2007, 41 (2) 517-527
11. Claeys, M.; Wang, W.; Vermeylen, R.; Kourtchev, I.; Chi, X. G.; Farhat, Y.; Surratt, J. D.; Gomez-Gonzalez, Y.; Sciare, J.; Maenhaut, W. Chemical characterisation of marine aerosol at Amsterdam Island during the austral summer of 2006-2007 J. Aerosol Sci. 2010, 41 (1) 13-22
12. Gómez-González, Y.; Wang, W.; Vermeylen, R.; Chi, X.; Neirynck, J.; Janssens, I. A.; Maenhaut, W.; Claeys, M. Chemical characterisation of atmospheric aerosols during a 2007 summer field campaign at Brasschaat, Belgium: sources and source processes of biogenic secondary organic aerosol Atmos. Chem. Phys. 2012, 12 (1) 125 - 138
13. Hatch, L. E.; Creamean, J. M.; Ault, A. P.; Surratt, J. D.; Chan, M. N.; Seinfeld, J. H.; Edgerton, E. S.; Su, Y.; Prather, K. A. Measurements of isoprene-derived organosulfates in ambient aerosols by aerosol time-of-flight mass spectrometry part 2: temporal variability and formation mechanisms Environ. Sci. Technol. 2011, 45 (20) 8648-8655
14. Hatch, L. E.; Creamean, J. M.; Ault, A. P.; Surratt, J. D.; Chan, M. N.; Seinfeld, J. H.; Edgerton, E. S.; Su, Y. X.; Prather, K. A. Measurements of isoprene-derived organosulfates in ambient aerosols by aerosol time-of-flight mass spectrometry-part 1: single particle atmospheric observations in Atlanta Environ. Sci. Technol. 2011, 45 (12) 5105-5111
15. Iinuma, Y.; Müller, C.; Berndt, T.; Böge, O.; Claeys, M.; Herrmann, H. Evidence for the existence of organosulfates from β-pinene ozonolysis in ambient secondary organic aerosol Environ. Sci. Technol. 2007, 41 (19) 6678-6683
16. 3 levels on isoprene-derived secondary organic aerosol formation using conditional sampling approaches Atmos. Chem. Phys. 2013, 13 (16) 8457-8470
17. Lin, Y.-H.; Zhang, H.; Pye, H. O. T.; Zhang, Z.; Marth, W. J.; Park, S.; Arashiro, M.; Cui, T.; Budisulistiorini, S. H.; Sexton, K. G.; Vizuete, W.; Xie, Y.; Luecken, D. J.; Piletic, I. R.; Edney, E. O.; Bartolotti, L. J.; Gold, A.; Surratt, J. D. Epoxide as a precursor to secondary organic aerosol formation from isoprene photooxidation in the presence of nitrogen oxides Proc. Natl. Acad. Sci. U.S.A. 2013, 110 (17) 6718-6723
18. Pye, H. O. T.; Pinder, R. W.; Piletic, I. R.; Xie, Y.; Capps, S. L.; Lin, Y.-H.; Surratt, J. D.; Zhang, Z.; Gold, A.; Luecken, D. J.; Hutzell, W. T.; Jaoui, M.; Offenberg, J. H.; Kleindienst, T. E.; Lewandowski, M.; Edney, E. O. Epoxide pathways improve model predictions of isoprene markers and reveal key role of acidity in aerosol formation Environ. Sci. Technol. 2013, 47 (19) 11056-11064
19. Frossard, A. A.; Shaw, P. M.; Russell, L. M.; Kroll, J. H.; Canagaratna, M. R.; Worsnop, D. R.; Quinn, P. K.; Bates, T. S. Springtime Arctic haze contributions of submicron organic particles from European and Asian combustion sources J. Geophys. Res. 2011, 116, D05205
20. Hawkins, L. N.; Russell, L. M.; Covert, D. S.; Quinn, P. K.; Bates, T. S. Carboxylic acids, sulfates, and organosulfates in processed continental organic aerosol over the southeast Pacific Ocean during VOCALS-REx 2008 J. Geophys. Res. 2010, 115 (D13) D13201
21. Kristensen, K.; Glasius, M. Organosulfates and oxidation products from biogenic hydrocarbons in fine aerosols from a forest in North West Europe during spring Atmos. Environ. 2011, 45 (27) 4546-4556
22. Russell, L. M.; Takahama, S.; Liu, S.; Hawkins, L. N.; Covert, D. S.; Quinn, P. K.; Bates, T. S. Oxygenated fraction and mass of organic aerosol from direct emission and atmospheric processing measured on the R/VRonald Brownduring TEXAQS/GoMACCS 2006 J. Geophys. Res. 2009, 114, D00F05
23. Tolocka, M. P.; Turpin, B. Contribution of organosulfur compounds to organic aerosol mass Environ. Sci. Technol. 2012, 46 (15) 7978-7983
24. Lukács, H.; Gelencsér, A.; Hoffer, A.; Kiss, G.; Horváth, K.; Hartyáni, Z. Quantitative assessment of organosulfates in size-segregated rural fine aerosol Atmos. Chem. Phys. 2009, 9 (1) 231-238
25. Stone, E. A.; Yang, L.; Yu, L. E.; Rupakheti, M. Characterization of organosulfates in atmospheric aerosols at Four Asian locations Atmos. Environ. 2012, 47 (0) 323-329
26. Worton, D. R.; Goldstein, A. H.; Farmer, D. K.; Docherty, K. S.; Jimenez, J. L.; Gilman, J. B.; Kuster, W. C.; de Gouw, J.; Williams, B. J.; Kreisberg, N. M.; Hering, S. V.; Bench, G.; McKay, M.; Kristensen, K.; Glasius, M.; Surratt, J. D.; Seinfeld, J. H. Origins and composition of fine atmospheric carbonaceous aerosol in the Sierra Nevada Mountains, California Atmos. Chem. Phys. 2011, 11 (19) 10219-10241
27. Froyd, K. D.; Murphy, S. M.; Murphy, D. M.; de Gouw, J. A.; Eddingsaas, N. C.; Wennberg, P. O. Contribution of isoprene-derived organosulfates to free tropospheric aerosol mass Proc. Natl. Acad. Sci. U.S.A. 2010, 107 (50) 21360-21365
28. Surratt, J. D.; Chan, A. W. H.; Eddingsaas, N. C.; Chan, M.; Loza, C. L.; Kwan, A. J.; Hersey, S. P.; Flagan, R. C.; Wennberg, P. O.; Seinfeld, J. H. Reactive intermediates revealed in secondary organic aerosol formation from isoprene Proc. Natl. Acad. Sci. U.S.A. 2010, 107 (15) 6640-6645
29. Worton, D. R.; Surratt, J. D.; LaFranchi, B. W.; Chan, A. W. H.; Zhao, Y.; Weber, R. J.; Park, J.-H.; Gilman, J. B.; de Gouw, J.; Park, C.; Schade, G.; Beaver, M.; Clair, J. M. S.; Crounse, J.; Wennberg, P.; Wolfe, G. M.; Harrold, S.; Thornton, J. A.; Farmer, D. K.; Docherty, K. S.; Cubison, M. J.; Jimenez, J.-L.; Frossard, A. A.; Russell, L. M.; Kristensen, K.; Glasius, M.; Mao, J.; Ren, X.; Brune, W.; Browne, E. C.; Pusede, S. E.; Cohen, R. C.; Seinfeld, J. H.; Goldstein, A. H. Observational insights into aerosol formation from isoprene Environ. Sci. Technol. 2013, 47 (20) 11403-11413
30. Paulot, F.; Crounse, J. D.; Kjaergaard, H. G.; Kürten, A.; St. Clair, J. M.; Seinfeld, J. H.; Wennberg, P. O. Unexpected epoxide formation in the gas-phase photooxidation of isoprene Science 2009, 325 (5941) 730-733
31. Pathak, R. K.; Louie, P. K. K.; Chan, C. K. Characteristics of aerosol acidity in Hong kong Atmos. Environ. 2004, 38 (19) 2965-2974
32. Ding, X.; Wang, X.-M.; Zheng, M. The influence of temperature and aerosol acidity on biogenic secondary organic aerosol tracers: Observations at a rural site in the central Pearl River Delta region, South China Atmos. Environ. 2011, 45 (6) 1303-1311
33. Offenberg, J. H.; Lewandowski, M.; Edney, E. O.; Kleindienst, T. E.; Jaoui, M. Influence of aerosol acidity on the formation of secondary organic aerosol from biogenic precursor hydrocarbons Environ. Sci. Technol. 2009, 43 (20) 7742-7747
34. Surratt, J. D.; Lewandowski, M.; Offenberg, J. H.; Jaoui, M.; Kleindienst, T. E.; Edney, E. O.; Seinfeld, J. H. Effect of acidity on secondary organic aerosol formation from isoprene Environ. Sci. Technol. 2007, 41 (15) 5363-5369
35. Lin, P.; Yu, J. Z.; Engling, G.; Kalberer, M. Organosulfates in humic-like substance fraction isolated from aerosols at seven locations in East Asia: A study by ultra-high-resolution mass spectrometry Environ. Sci. Technol. 2012, 46 (24) 13118-13127
36. Van Pinxteren, D.; Brüggemann, E.; Gnauk, T.; Iinuma, Y.; Müller, K.; Nowak, A.; Achtert, P.; Wiedensohler, A.; Herrmann, H. Size- and time-resolved chemical particle characterization during CAREBeijing-2006: Different pollution regimes and diurnal profiles J. Geophys. Res. 2009, 114 (D2) D00G09
37. Ma, Y.; Xu, X.; Song, W.; Geng, F.; Wang, L. Seasonal and diurnal variations of particulate organosulfates in urban Shanghai, China Atmos. Environ. 2014, 85 (0) 152-160
38. Chan, C. K.; Yao, X. Air pollution in mega cities in China Atmos. Environ. 2008, 42 (1) 1-42
39. Wang, X. M.; Situ, S. P.; Guenther, A.; Chen, F.; Wu, Z. Y.; Xia, B. C.; Wang, T. J. Spatiotemporal variability of biogenic terpenoid emissions in Pearl River Delta, China, with high-resolution land-cover and meteorological data Tellus Ser. B-Chem. Phys. Meteorol. 2011, 63 (2) 241-254
40. Wang, T.; Wei, X. L.; Ding, A. J.; Poon, C. N.; Lam, K. S.; Li, Y. S.; Chan, L. Y.; Anson, M. Increasing surface ozone concentrations in the background atmosphere of Southern China, 1994-2007 Atmos. Chem. Phys. 2009, 9 (16) 6217-6227
41. Ding, X.; Wang, X.-M.; Gao, B.; Fu, X.-X.; He, Q.-F.; Zhao, X.-Y.; Yu, J.-Z.; Zheng, M. Tracer-based estimation of secondary organic carbon in the Pearl River Delta, South China J. Geophys. Res. 2012, 117 (D5) D05313
42. Guo, H.; Jiang, F.; Cheng, H. R.; Simpson, I. J.; Wang, X. M.; Ding, A. J.; Wang, T. J.; Saunders, S. M.; Wang, T.; Lam, S. H. M.; Blake, D. R.; Zhang, Y. L.; Xie, M. Concurrent observations of air pollutants at two sites in the Pearl River Delta and the implication of regional transport Atmos. Chem. Phys. 2009, 9 (19) 7343-7360
43. Wang, X.; Ding, X.; Fu, X.; He, Q.; Wang, S.; Bernard, F.; Zhao, X.; Wu, D. Aerosol scattering coefficients and major chemical compositions of fine particles observed at a rural site hit the central Pearl River Delta, South China J. Environ. Sci.-China 2012, 24 (1) 72-77
44. Zhang, Y. L.; Wang, X. M.; Blake, D. R.; Li, L. F.; Zhang, Z.; Wang, S. Y.; Guo, H.; Lee, F. S. C.; Gao, B.; Chan, L. Y.; Wu, D.; Rowland, F. S. Aromatic hydrocarbons as ozone precursors before and after outbreak of the 2008 financial crisis in the Pearl River Delta region, South China J. Geophys. Res. 2012, 117, D15306
45. Zheng, J.; Zheng, Z.; Yu, Y.; Zhong, L. Temporal, spatial characteristics and uncertainty of biogenic VOC emissions in the Pearl River Delta region, China Atmos. Environ. 2010, 44 (16) 1960-1969
46. Safi Shalamzari, M.; Ryabtsova, O.; Kahnt, A.; Vermeylen, R.; Hérent, M.-F.; Quetin-Leclercq, J.; Van der Veken, P.; Maenhaut, W.; Claeys, M. Mass spectrometric characterization of organosulfates related to secondary organic aerosol from isoprene Rapid Commun. Mass Spectrom. 2013, 27 (7) 784-794
47. Method 5040 Issue 3 (Interim): Elemental carbon (diesel exhaust). In NIOSH manual of analytical methods; National Institute of Occupational Safety and Health: Cincinnati, OH, 1999.
48. Gao, S.; Surratt, J. D.; Knipping, E. M.; Edgerton, E. S.; Shahgholi, M.; Seinfeld, J. H. Characterization of polar organic components in fine aerosols in the southeastern United States: Identity, origin, and evolution J. Geophys. Res. 2006, 111 (D14) D14314
49. Zhao, B.; Wang, S. X.; Liu, H.; Xu, J. Y.; Fu, K.; Klimont, Z.; Hao, J. M.; He, K. B.; Cofala, J.; Amann, M. NOx emissions in China: historical trends and future perspectives Atmos. Chem. Phys. 2013, 13 (19) 9869-9897
50. Aschmann, S. M.; Reisseil, A.; Atkinson, R.; Arey, J. Products of the gas phase reactions of the OH radical with α- and β-pinene in the presence of NO J. Geophys. Res. 1998, 103 (D19) 25553-25561
51. Sheehan, P. E.; Bowman, F. M. Estimated effects of temperature on secondary organic aerosol concentrations Environ. Sci. Technol. 2001, 35 (11) 2129-2135
52. Andreae, M. O.; Merlet, P. Emission of trace gases and aerosols from biomass burning Global Biogeochem. Cy. 2001, 15 (4) 955-966
53. 10 aerosol from a rural site in Belgium Atmos. Environ. 2013, 81 (0) 561-568
54. Claeys, M.; Szmigielski, R.; Kourtchev, I.; Van der Veken, P.; Vermeylen, R.; Maenhaut, W.; Jaoui, M.; Kleindienst, T. E.; Lewandowski, M.; Offenberg, J. H.; Edney, E. O. Hydroxydicarboxylic acids: markers for secondary organic aerosol from the photooxidation of alpha-pinene Environ. Sci. Technol. 2007, 41 (5) 1628-1634
55. Jaoui, M.; Kleindienst, T. E.; Lewandowski, M.; Offenberg, J. H.; Edney, E. O. Identification and quantification of aerosol polar oxygenated compounds bearing carboxylic or hydroxyl groups. 2. Organic tracer compounds from monoterpenes Environ. Sci. Technol. 2005, 39 (15) 5661-5673
56. Muller, L.; Reinnig, M. C.; Naumann, K. H.; Saathoff, H.; Mentel, T. F.; Donahue, N. M.; Hoffmann, T. Formation of 3-methyl-1,2,3-butanetricarboxylic acid via gas phase oxidation of pinonic acid-a mass spectrometric study of SOA aging Atmos. Chem. Phys. 2012, 12 (3) 1483-1496
57. Iinuma, Y.; Kahnt, A.; Mutzel, A.; Boge, O.; Herrmann, H. Ozone-driven secondary organic aerosol production chain Environ. Sci. Technol. 2013, 47 (8) 3639-3647
58. Guenther, A. B.; Zimmerman, P. R.; Harley, P. C.; Monson, R. K.; Fall, R. Isoprene and monoterpene emission rate variability-model evaluations and sensitivity analyses J. Geophys. Res. 1993, 98 (D7) 12609-12617
59. Rinne, H. J. I.; Guenther, A. B.; Greenberg, J. P.; Harley, P. C. Isoprene and monoterpene fluxes measured above Amazonian rainforest and their dependence on light and temperature Atmos. Environ. 2002, 36 (14) 2421-2426
60. Gómez-González, Y.; Surratt, J. D.; Cuyckens, F.; Szmigielski, R.; Vermeylen, R.; Jaoui, M.; Lewandowski, M.; Offenberg, J. H.; Kleindienst, T. E.; Edney, E. O.; Blockhuys, F.; Van Alsenoy, C.; Maenhaut, W.; Claeys, M. Characterization of organosulfates from the photooxidation of isoprene and unsaturated fatty acids in ambient aerosol using liquid chromatography/(-) electrospray ionization mass spectrometry J. Mass Spectrom. 2008, 43 (3) 371-382
61. Hofzumahaus, A.; Rohrer, F.; Lu, K. D.; Bohn, B.; Brauers, T.; Chang, C. C.; Fuchs, H.; Holland, F.; Kita, K.; Kondo, Y.; Li, X.; Lou, S. R.; Shao, M.; Zeng, L. M.; Wahner, A.; Zhang, Y. H. Amplified trace gas removal in the troposphere Science 2009, 324 (5935) 1702-1704
62. Li, S. W.; Liu, W. Q.; Xie, P. H.; Qin, M.; Yang, Y. J. Observation of nitrate radical in the nocturnal boundary layer during a summer field campaign in Pearl River Delta, China Terr. Atmos. Ocean Sci. 2012, 23 (1) 39-48
63. Atkinson, R.; Arey, J. Atmospheric degradation of volatile organic compounds Chem. Rev. 2003, 103 (12) 4605-4638
64. Liu, Z.; Wang, Y.; Gu, D.; Zhao, C.; Huey, L. G.; Stickel, R.; Liao, J.; Shao, M.; Zhu, T.; Zeng, L.; Amoroso, A.; Costabile, F.; Chang, C. C.; Liu, S. C. Summertime photochemistry during CAREBeijing-2007: ROx budgets and O3 formation Atmos. Chem. Phys. 2012, 12 (16) 7737-7752
65. Xue, J.; Yuan, Z.; Yu, J. Z.; Lau, A. K. H. An observation-based model for secondary inorganic aerosols Aerosol Air Qual. Res. 2014, 10.4209/aaqr.2013.06.0188
66. Minerath, E. C.; Casale, M. T.; Elrod, M. J. Kinetics feasibility study of alcohol sulfate esterification reactions in tropospheric aerosols Environ. Sci. & Technol. 2008, 42 (12) 4410-4415
67. 2.5 in Hong Kong using online ionic chemical composition measurements Atmos. Environ. 2011, 45 (39) 7081-7088
68. Wang, X.; Zhang, Y.; Hu, Y.; Zhou, W.; Lu, K.; Zhong, L.; Zeng, L.; Shao, M.; Hu, M.; Russell, A. G. Process analysis and sensitivity study of regional ozone formation over the Pearl River Delta, China, during the PRIDE-PRD2004 campaign using the Community Multiscale Air Quality modeling system Atmos. Chem. Phys. 2010, 10 (9) 4423-4437
69. McNeill, V. F.; Woo, J. L.; Kim, D. D.; Schwier, A. N.; Wannell, N. J.; Sumner, A. J.; Barakat, J. M. Aqueous-phase secondary organic aerosol and organosulfate formation in atmospheric aerosols: A modeling study Environ. Sci. Technol. 2012, 46 (15) 8075-8081
70. Lin, Y.-H.; Zhang, Z.; Docherty, K. S.; Zhang, H.; Budisulistiorini, S. H.; Rubitschun, C. L.; Shaw, S. L.; Knipping, E. M.; Edgerton, E. S.; Kleindienst, T. E.; Gold, A.; Surratt, J. D. Isoprene epoxydiols as precursors to secondary organic aerosol formation: Acid-catalyzed reactive uptake studies with authentic compounds Environ. Sci. Technol. 2012, 46 (1) 250-258