Effect of acidity on secondary organic aerosol formation from isoprene

Environmental Science and Technology

Volumn 41, Issue 15, 2007, Pages 5363-5369

  Surratt, Jason D ^a   Lewandowski, Michael ^b   Offenberg, John H ^b   Jaoui, Mohammed ^c   Kleindienst, Tadeusz E ^b   Edney, Edward O ^b   Seinfeld, John H ^a  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^b U S ENVIRONMENTAL PROTECTION AGENCY   (United States)

^c ALION SCIENCE AND TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACIDITY; CATALYSTS; CONCENTRATION (PROCESS); ESTERS; PHASE CONTROL; CHEMICAL ANALYSIS;

CHEMICAL ANALYSES; INORGANIC SEED; PARTICLE-PHASE ACIDITY; PARTICLE-PHASE REACTIONS;

AEROSOLS; ATMOSPHERIC AEROSOLS;

ISOPRENE;

ACIDITY; AEROSOLS; CATALYSTS; CONCENTRATION (PROCESS); ESTERS; PHASE CONTROL;

ACIDITY; AEROSOL FORMATION; CHEMICAL ANALYSIS; ISOPRENE; LABORATORY METHOD; TRACER;

ACIDITY; AEROSOL; AIR POLLUTANT; ARTICLE; CHEMICAL ANALYSIS; TROPOSPHERE; UNITED STATES;

AEROSOLS; BUTADIENES; CARBON; GASES; HEMITERPENES; HYDROGEN-ION CONCENTRATION; NITRIC OXIDE; ORGANIC CHEMICALS; OXIDATION-REDUCTION; PENTANES; SPECTROMETRY, MASS, MATRIX-ASSISTED LASER DESORPTION-IONIZATION;

AEROSOL MASS CONCENTRATION; AMBIENT AEROSOLS; CHEMICAL EVIDENCES; MASS CONCENTRATION; PARTICLE-PHASE REACTIONS; SECONDARY ORGANIC AEROSOLS; SULFATE ESTERS; TROPOSPHERIC AEROSOLS;

EID: 34547685897     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es0704176     Document Type: Article

References (38)

1. Jang, M.; Czoschke, N. M.; Lee, S.; Kamens, R. M. Heterogeneous atmospheric aerosol production by acid-catalyzed particle-phase reactions. Science 2002, 298, 814-817.
2. 3 reaction: Influence of particle acidity on aerosol yields and products. Atmos. Environ. 2004, 38, 761-773.
3. Tolocka, M. P.; Jang, M.; Ginter, J. M.; Cox, F. J.; Kamens, R. M.; Johnston, M. V. Formation of oligomers in secondary organic aerosol. Environ. Sci. Technol. 2004, 38, 1428-1434.
4. Gao, S.; Keywood, M.; Ng, N. L.; Surratt, J. D.; Varutbangkul, V.; Bahreini, R.; Flagan, R. C.; Seinfeld, J. H. Low molecular weight and oligomeric components in secondary organic aerosol from the ozonolysis of cycloalkenes and α-pinene. J. Phys. Chem. 2004, 108, 10147-10164.
5. Gao, S.; Ng, N. L.; Keywood, M.; Varutbangkul, V.; Bahreini, R.; Nenes, A.; He, J.; Yoo, K. Y.; Beauchamp, J. L.; Hodyss, R. P.; Flagan, R. C.; Seinfeld, J. H. Particle-phase acidity and oligomer formation in secondary organic aerosol. Environ. Sci. Technol. 2004, 38, 6582-6589.
6. 2.5 samples collected in the eastern United States. Atmos. Environ. 2005, 39, 5281-5289.
7. 2. Environ. Sci. Technol. 2006, 40, 3807-3812.
8. 3 in the presence of alcohols and carboxylic acids. Environ. Sci. Technol. 2000, 34, 2105-2115.
9. 3. Environ. Sci. Technol. 2005, 39, 4049-4059.
10. Kalberer, M.; Paulsen, D.; Sax, M.; Steinbacher, M.; Dommen, J.; Prevot, A. S. H.; Fisseha, R.; Weingartner, E.; Frankevich, V.; Zenobi, R.; Baltensperger, U. Identification of polymers as major components of atmospheric organic aerosols. Science 2004, 303, 1659-1662.
11. Surratt, J. D.; Murphy, S. M.; Kroll, J. H.; Ng, N. L.; Hildebrandt, L.; Sorooshian, A.; Szmigielski, R.; Vermeylen, R.; Maenhaut, W.; Claeys, M.; Flagan, R. C.; Seinfeld, J. H. Chemical composition of secondary organic aerosol formed from the photooxidation of isoprene. J. Phys. Chem. A 2006, 110, 9665-9690.
12. Barsanti, K. C.; Pankow, J. F. Thermodynamics of the formation of atmospheric organic particulate matter by accretion reactions. Part 1: Aldehydes and ketones. Atmos. Environ. 2004, 38, 4371-4282.
13. Barsanti, K. C.; Pankow, J. F. Thermodynamics of the formation of atmospheric organic particulate matter by accretion reactions. Part 2: Dialdehydes, methylglyoxal, and diketones. Atmos. Environ. 2005, 39, 6597-6607.
14. Surratt, J. D.; Kroll, J. H.; Kleindienst, T. E.; Edney, E. O.; Claeys, M.; Sorooshian, A.; Ng, N. L.; Offenberg, J. H.; Lewandowski, M.; Jaoui, M.; Flagan, R. C.; Seinfeld, J. H. Evidence for organosulfates in secondary organic aerosol. Environ. Sci. Technol. 2007, 41, 517-527.
15. Liggio, J.; Li, S. M.; McLaren, R. Heterogeneous reactions of glyoxal on particulate matter: Identification of acetals and sulfate esters. Environ. Sci. Technol. 2005, 39, 1532-1541.
16. Liggio, J.; Li, S. M. Organosulfate formation during the uptake of pinonaldehyde on acidic sulfate aerosols. Geophys. Res. Lett. 2006, 33, L13808, doi:10.1029/2006GL026079.
17. Iinuma, Y.; Müller, C.; Böge, O.; Gnauk, T.; Herrmann, H. The formation of organic sulfate esters in the limonene ozonolysis secondary organic aerosol (SOA) under acidic conditions. Atmos. Environ. 2007, doi:10.1016/j.atmosenv.2007.03.007.
18. Limbeck, A.; Kulmala, M.; Puxbaum, H. Secondary organic aerosol formation in the atmosphere via heterogeneous reaction of gaseous isoprene on acidic particles. Geophys. Res. Lett. 2003, 30, 1996-1999.
19. Claeys, M.; Graham, B.; Vas, G.; Wang, W.; Vermeylen, R.; Pashynska, V.; Cafmeyer, J.; Guyon, P.; Andreae, M. O.; Artaxo, P.; Maenhaut, W. Formation of secondary organic aerosols through photooxidation of isoprene. Science 2004, 303, 1173-1176.
20. x conditions. Geophys. Res. Lett. 2005, 32, L18808, doi:10.1029/2005GL023637.
21. Kroll, J. H.; Ng, N. L.; Murphy, S. M.; Flagan, R. C.; Seinfeld, J. H. Secondary organic aerosol formation from isoprene photooxidation. Environ. Sci. Technol. 2006, 40, 1869-1877.
22. Henze, D. K.; Seinfeld, J. H. Global secondary organic aerosol from isoprene oxidation. Geophys. Res. Lett. 2006, 33, L09812, doi:10.1029/2006GL025976.
23. x photooxidation. Geophys. Res. Lett. 2006, 33, L13805, doi:10.1029/2006GL026523.
24. Birch, M. E.; Cary, R. A. Elemental carbon-based method for monitoring occupational exposures to particulate diesel exhaust. Aerosol Sci. Technol. 1996, 24, 221-241.
25. Jaoui, M.; Kleindienst, T. E.; Lewandowski, M.; Edney, E. O. Identification and quantification of aerosol polar oxygenated compounds bearing carboxylic and/or hydroxyl groups. 1. Method development. Anal. Chem. 2004, 76, 4765-4778.
26. 2.5. Environ. Sci. Technol. 2006, 40, 3819-3828.
27. Lioy, P. J.; Samson, P. J.; Tanner, R. L.; Leaderer, B. P.; Minnich, T.; Lyons, W. The distribution and transport of sulfate species in the New York metropolitan area during the 1977 summer aerosol study. Atmos. Environ. 1980, 14, 1391-1407.
28. Koutrakis, P.; Wolfson, J. M.; Spengler, J. D. An improved method for measuring aerosol strong acidity: Results from a 9 month study in St. Louis, MO and Kingston, TN. Atmos. Environ. 1988, 22, 157-162.
29. Liu, L.-J. S.; Burton, R.; Wilson, W. E.; Koutrakis, P. Comparison of aerosol acidity in urban and semirural environments. Atmos. Environ. 1996, 30, 1237-1245.
30. Miyoshi, A.; Hatakeyama, S.; Washida, N. OH radical-initiated photooxidation of isoprene: An estimate of global CO production. J. Geophys. Res. 1994, 99, 18779-18787.
31. 5-unsaturated diols. Atmos. Environ. 2000, 34, 1529-1542.
32. Szmigielski, R.; Surratt, J. D.; Vermeylen, R.; Szmigielska, K.; Kroll, J. H.; Ng, N. L.; Murphy, S. M.; Sorooshian, A.; Seinfeld, J. H.; Claeys, M. Characterization of 2-methylglyceric acid oligomers in secondary organic aerosol formed from the photooxidation of isoprene using trimethylsilylation and gas chromatography/ion trap mass spectrometry. J. Mass. Spectrom. 2007, 42, 101-116.
33. Kalberer, M.; Sax, M.; Samburova, V. Molecular size evolution of oligomers in organic aerosols collected in urban atmospheres and generated in a smog chamber. Environ. Sci. Technol. 2006, 40, 5917-5922.
34. Boge, O.; Miao, Y.; Plewka, A.; Herrmann, H. Formation of secondary organic particle-phase compounds from isoprene gas-phase oxidation products: An aerosol chamber and field study. Atmos. Environ. 2006, 40, 2501-2509.
35. Claeys, M.; Wang, W.; Ion, A. C.; Kourtchev, I.; Gelencsér, A.; Maenhaut, W. Formation of secondary organic aerosols from isoprene and its gas-phase oxidation products through reaction with hydrogen peroxide. Atmos. Environ. 2004, 38, 4093-4098.
36. Wang, W.; Kourtchev, I.; Graham, B.; Cafmeyer, J.; Maenhaut, W.; Claeys, M. Characterization of oxygenated derivatives of isoprene related to 2-methyltetrols in Amazonian aerosols using trimethylsilylation and gas chromatography/ion trap mass spectrometry. Rapid Commun. Mass Spectrom. 2005, 19, 1343-1351.
37. 2.5 during the summer of 2003 in Research Triangle Park, NC. Atmos. Environ. 2007, 41, 4073-4083.
38. Kourtchev, I.; Ruuskanen, T. M.; Keronen, P.; Sogacheva, L.; Maso, M. D.; Reissell, A.; Chi, X.; Vermeylen, R.; Kulmala, M.; Maenhaut, W.; Claeys, M. Determination of isoprene and α-/β-pinene oxidation products in boreal forest aerosols from Hyytiälä, Finland: Diurnal variations and possible link with particle formation events. Plant Biol. 2007, doi:10.1055/s-2007-964945.