Characterization of polar organic components in fine aerosols in the southeastern United States: Identity, origin, and evolution

Journal of Geophysical Research Atmospheres

Volumn 111, Issue 14, 2006, Pages

  Gao, Song ^a   Surratt, Jason D ^b   Knipping, Eladio M ^c   Edgerton, Eric S ^d   Shahgholi, Mona ^b   Seinfeld, John H ^a  

^a California Institute of Technology   (United States)

^b CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^c ELECTRIC POWER RESEARCH INSTITUTE   (United States)

^d Atmospheric Research and Analysis Inc ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC AEROSOLS; ATMOSPHERIC CHEMISTRY; LIQUID CHROMATOGRAPHY; MASS SPECTROMETRY; OXIDATION; PARTICULATE EMISSIONS;

AEROSOL; ANALYTICAL METHOD; CHEMICAL ANALYSIS; DEGRADATION; IDENTIFICATION METHOD; LIQUID CHROMATOGRAPHY; MASS SPECTROMETRY; MOLECULAR ANALYSIS; ORGANIC COMPOUND; OXIDATION; QUANTITATIVE ANALYSIS;

NORTH AMERICA; UNITED STATES;

EID: 33846084788     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/2005JD006601     Document Type: Article

References (39)

1. Aschmann, S. M., E. C. Tuazon, J. Arey, and R. Atkinson (2003), Products of the gas-phase reaction of O3 with cyclohexene, J. Phys. Chem. A, 107, 2247-2255.
2. Baltensperger, U., et al. (2005), Secondary organic aerosols from anthropogenic and biogenic precursors, Faraday Disc., 130, 265-278.
3. Barsanti, K., and J. Pankow (2004), Thermodynamics of the formation of atmospheric organic particulate matter by accretion reactions: Part 1. Aldehydes and ketones, Atmos. Environ., 38, 4371-4382.
4. Buxton, G. V., G. A. Salmon, and J. E. Williams (2000), The reactivity of biogenic monoterpenes towards OH center dot and SO4-center dot radicals in de-oxygenated acidic solution, J. Atmos. Chem., 36, 111-134.
5. Cappiello, A., E. De Simoni, C. Fiorucci, F. Mangani, P. Palma, H. Trufelli, S. Decesari, M. C. Facchini and S. Fuzzi (2003), Molecular characterization of the water-soluble organic compounds in fogwater by ESIMS/MS, Environ. Sci. Technol., 37, 1229-1240.
6. Choi M., and C. Chan (2002), The effects of organic species on the hygroscopic behaviors of inorganic aerosols, Environ. Sci. Technol., 36, 2422-2428.
7. Cruz, C., and S. Pandis (1998), The effect of organic coatings on the cloud condensation nuclei activation of inorganic atmospheric aerosol, J. Geophys. Res., 103, 13,111-13,123.
8. Cruz, C., and S. Pandis (2000), Deliquescence and hygroscopic growth of mixed inorganic-organic atmospheric aerosol, Environ. Sci. Technol., 34, 4313-4319.
9. El-Zanan, H. S., D. H. Lowenthal, B. Zielinska, J. C. Chow, and N. Kumar (2005), Determination of the organic aerosol mass to organic carbon ratio in IMPROVE samples, Chemosphere, 60, 485-496.
10. Gao, S., M. Keywood, N. L. Ng, J. Surratt, V. Varutbangkul, R. Bahreini, R. C. Flagan, and J. H. Seinfeld (2004a), Low-molecular-weight and oligomeric components in secondary organic aerosol from the ozonolysis of cycloalkenes and alpha-pinene, J. Phys. Chem. A, 108, 10,147-10,164.
11. Gao, S., et al. (2004b), Particle phase acidity and oligomer formation in secondary organic aerosol, Environ. Sci. Technol., 38, 6582-6589.
12. Gelencser, A., T. Meszaros, M. Blazso, G. Kiss, Z. Krivacsy, A. Molnar, and E. Meszaros (2000), Structural characterisation of organic matter in fine tropospheric aerosol by pyrolysis-gas chromatography-mass spectrometry, J. Atmos. Chem., 37, 173-183.
13. Gelencser, A., A. Hoffer, Z. Krivacsy, G. Kiss, A. Molnar, and E. Meszaros (2002), On the possible origin of humic matter in fine continental aerosol, J. Geophys. Res., 107(D12), 4137, doi:10.1029/ 2001JD001299.
14. Glasius, M., M. Lahaniati, A. Calogirou, D. Di Bella, N. R. Jensen, J. Hjorth, D. Kotzias, and B. R. Larsen (2000), Carboxylic acids in secondary aerosols from oxidation of cyclic monoterpenes by ozone, Environ. Sci. Technol., 34, 1001-1010.
15. Hansen, D., E. S. Edgerton, B. E. Hartsell, J. J. Jansen, N. Kandasamy, G. M. Hidy, and C. L. Blanchard (2003), The southeastern aerosol research and characterization study: Part 1, Overview, J. Air Waste Manage., 53, 1460-1471.
16. Havers, N., P. Burba, J. Lambert, and D. Klockow (1998), Spectroscopic characterization of humic-like substances in airborne particulate matter, J. Atmos. Chem., 29, 45-54.
17. Kalberer, M., et al. (2004), Identification of polymers as major components of atmospheric organic aerosols, Science, 303, 1659-1662.
18. Kavouras, I. G., N. Mihalopoulos, and E. G. Stephanou (1999), Formation and gas/particle partitioning of monoterpenes photooxidation products over forests, Geophys. Res. Lett., 26, 55-58.
19. Kiss, G., B. Varga, A. Gelencser, Z. Krivacsy, A. Molnar, T. Alsberg, L. Persson, H. C. Hansson, and M. C. Facchini (2001), Characterisation of polar organic compounds in fog water, Atmos. Environ., 35, 2193-2200.
20. Kiss, G., E. Tombacz, B. Varga, T. Alsberg, and L. Persson (2003), Estimation of the average molecular weight of humic-like substances isolated from fine atmospheric aerosol, Atmos. Environ., 37, 3783-3794.
21. Klaus, U., T. Pfeifer, and M. Spiteller (2000), APCI-MS/MS: A powerful tool for the analysis of bound residues resulting from the interaction of pesticides with DOM and humic substances, Environ. Sci. Technol., 34, 3514-3520.
22. Krivacsy, Z., et al. (2001), Study on the chemical character of water soluble organic compounds in fine atmospheric aerosol at the Jungfraujoch, J. Atmos. Chem., 39, 235-259.
23. Leenheer, J. A., C. E. Rostad, P. M. Gates, E. T. Furlong, and I. Ferrer (2001), Molecular resolution and fragmentation of fulvic acid by electrospray ionization/multistage tandem mass spectrometry, Anal. Chem., 73, 1461-1471.
24. Lim, H. J., and B. J. Turpin (2002), Origins of primary and secondary organic aerosol in Atlanta: Results of time-resolved measurements during the Atlanta supersite experiment, Environ. Sci. Technol., 36, 4489-4496.
25. Martin, F., F. J. Gonzalezvila, J. C. Delrio, and T. Verdejo (1994), Pyrolysis derivatization of humic substances: 1. Pyrolysis of fulvic-acids in the presence of tetramethylammonium hydroxide, J. Anal. Appl. Pyrol., 28, 71-80.
26. Martin, F., J. C. Delrio, F. J. Gonzalezvila, and T. Verdejo (1995), Pyrolysis derivatization of humic substances: 2. Pyrolysis of soil humic acid in the presence of tetramethylammonium hydroxide, J. Anal. Appl. Pyrol., 31, 75-83.
27. Pio, C. A., C. A. Alves, and A. C. Duarte (2001), Organic components of aerosols in a forested area of central Greece, Atmos. Environ., 35, 389-401.
28. Plancque, G., B. Amekraz, V. Moulin, P. Toulhoat, and C. Moulin (2001), Molecular structure of fulvic acids by electrospray with quadrupole time-of-flight mass spectrometry, Rapid Commun. Mass. Spectrom., 15, 827-835.
29. Samburova, V., M. Kalberer, and R. Zenobi (2005), Characterization of high molecular weight compounds in urban atmospheric particles, Atmos. Chem. Phys. Disc., 5, 437-454.
30. Sarvari, Z., Z. Krivacsy, U. Baltensperger, S. Nyeki, E. Weingartner, S. Wessel, and S. G. Jennings (1999), Low-molecular weight carboxylic acids in atmospheric aerosol at different European sites, J. Aerosol Sci., 30, S261-S262.
31. Stephanou, E. G., and N. Stratigakis (1993), Oxocarboxylic and alpha, omega-dicarboxylic acids - Photooxidation products of biogenic unsaturated fatty-acids present in urban aerosols, Environ. Sci. Technol., 27, 1403-1407.
32. Szidat, S., et al. (2004), Source apportionment of aerosols by C-14 measurements in different carbonaceous particle fractions, Radiocarbon, 46, 475-484.
33. Tolocka, M. P., M. Jang, J. M. Ginter, F. J. Cox, R. M. Kamens, and M. V. Johnston (2004), Formation of oligomers in secondary organic aerosol, Environ. Sci. Technol., 38, 1428-1434.
34. Turpin, B. J., and H. J. Lim (2001), Species contributions to PM2.5 mass concentrations: Revisiting common assumptions for estimating organic mass, Aerosol Sci. Technol., 35, 602-610.
35. Turpin, B. J., J. J. Huntzicker, and S. V. Hering (1994), Investigation of organic aerosol sampling artifacts in the Los-Angeles basin, Atmos. Environ., 28, 3061-3071.
36. Whiterhalter, R., R. Van Dingenen, B. R. Larsen, N. R. Jensen, and J. Hjorth (2003), LC-MS analysis of aerosol particles from the oxidation of a-pinene by ozone and OH-radicals, Atmos. Chem. Phys. Disc., 3, 1-39.
37. Yu, J. Z., D. R. Cocker, R. J. Griffin, R. C. Flagan, and J. H. Seinfeld (1999), Gas-phase ozone oxidation of monoterpenes: Gaseous and particulate products, J. Atmos. Chem., 34, 207-258.
38. Yu, L. E., M. L. Shulman R. Kopperud, and L. M. Hildemann (2005), Characterization of organic compounds collected during Southeastern Aerosol and Visibility Study: Water-soluble organic species, Environ. Sci. Technol., 39, 707-715.
39. Zheng, M., G. R. Cass, J. J. Schauer, and E. S. Edgerton (2002), Source apportionment of PM2.5 in the southeastern United States using solvent-extractable organic compounds as tracers, Environ. Sci. Technol., 36, 2361-2371.