Formic acid dehydrogenation with bioinspired iridium complexes: A kinetic isotope effect study and mechanistic insight

ChemSusChem

Volumn 7, Issue 7, 2014, Pages 1976-1983

  Wang, Wan Hui ^a,b,d   Xu, Shaoan ^a   Manaka, Yuichi ^a   Suna, Yuki ^a   Kambayashi, Hide ^a   Muckerman, James T ^c   Fujita, Etsuko ^c   Himeda, Yuichiro ^a,b  

^a NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

^c BROOKHAVEN NATIONAL LABORATORY   (United States)

^d DALIAN UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

dehydrogenation; formic acid; hydrogen; iridium; isotope effects

Indexed keywords

CARBON DIOXIDE; CARBON MONOXIDE; CARRIER MOBILITY; DEHYDROGENATION; DEUTERIUM; ENERGY BARRIERS; FORMIC ACID; HYDROGEN; HYDROGEN PRODUCTION; IRIDIUM; KINETICS; LIGANDS; PROTONS;

DEUTERIUM KINETIC ISOTOPE EFFECT; DIFFERENT MECHANISMS; HYDROGEN ELIMINATION; HYDROGEN GENERATIONS; ISOTOPE EFFECT; KINETIC ISOTOPE EFFECTS; PENTAMETHYLCYCLOPENTADIENYL; RATE DETERMINING STEP;

IRIDIUM COMPOUNDS;

BIOMIMETIC MATERIAL; DEUTERIUM; FORMIC ACID; FORMIC ACID DERIVATIVE; HYDROGEN; IRIDIUM; ORGANOMETALLIC COMPOUND;

CHEMISTRY; KINETICS; PH;

BIOMIMETIC MATERIALS; DEUTERIUM; FORMATES; HYDROGEN; HYDROGEN-ION CONCENTRATION; IRIDIUM; KINETICS; ORGANOMETALLIC COMPOUNDS;

EID: 84905241149     PISSN: 18645631     EISSN: 1864564X     Source Type: Journal    
DOI: 10.1002/cssc.201301414     Document Type: Article

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