Transition state analysis of enantioselective brønsted base catalysis by chiral cyclopropenimines

Journal of the American Chemical Society

Volumn 136, Issue 30, 2014, Pages 10700-10707

  Bandar, Jeffrey S ^a   Sauer, Gregory S ^c   Wulff, William D ^b   Lambert, Tristan H ^a   Vetticatt, Mathew J ^c  

^a Och Spine at New York Presbyterian Hospitals   (United States)

^b MICHIGAN STATE UNIVERSITY   (United States)

^c BINGHAMTON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; CATALYSIS; CATALYSTS; CHEMICAL BONDS; ISOTOPES;

BENZYL ACRYLATE; CARBON-CARBON BOND FORMATION; CATALYST DESIGNS; ENANTIOSELECTIVE; KINETIC ISOTOPE EFFECTS; MICHAEL ADDITIONS; RATE-LIMITING STEPS; TRANSITION STATE;

ENANTIOSELECTIVITY;

2,3 BIS(DICYCLOHEXYLAMINO) CYCLOPROPENIMINE; ACRYLIC ACID; BRONSTED BASE; CARBON 13; IMINE; UNCLASSIFIED DRUG; ACRYLIC ACID DERIVATIVE; CARBON; CYCLOPROPANE DERIVATIVE; CYCLOPROPENE; GLYCINE;

ARTICLE; ATOM; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYSIS; CATALYST; CHIRALITY; DENSITY FUNCTIONAL THEORY; ENANTIOSELECTIVITY; MICHAEL ADDITION; ANALOGS AND DERIVATIVES; CHEMICAL STRUCTURE; CHEMISTRY; KINETICS; QUANTUM THEORY; STEREOISOMERISM;

ACRYLATES; CARBON ISOTOPES; CATALYSIS; CYCLOPROPANES; GLYCINE; IMINES; KINETICS; MODELS, MOLECULAR; QUANTUM THEORY; STEREOISOMERISM;

EID: 84905215856     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja504532d     Document Type: Article

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