Understanding chlorite, chlorate and perchlorate formation when generating hypochlorite using boron doped diamond film electrodes

ECS Transactions

Volumn 58, Issue 35, 2013, Pages 21-32

  Hubler, D K ^a   Baygents, J C ^a   Chaplin, B P ^b   Farrell, J ^a  

^a University of Arizona   (United States)

^b University of Illinois at Chicago   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; CARBON; CHEMISORPTION; CHLORINE; DIAMOND FILMS; ELECTRODES; FREE RADICAL REACTIONS; INORGANIC COMPOUNDS; REACTION INTERMEDIATES;

BORON-DOPED DIAMOND FILMS; BY-PRODUCT FORMATION; DIAMOND ELECTRODE; DIRECT ELECTRON TRANSFER; HYDROGEN-TERMINATED SURFACES; HYDROXYL RADICALS; OXIDATION STATE; TERTIARY CARBON ATOM;

SURFACE REACTIONS;

EID: 84904959181     PISSN: 19385862     EISSN: 19386737     Source Type: Conference Proceeding    
DOI: 10.1149/05835.0021ecst     Document Type: Conference Paper

References (38)

1. H. B. Martin, A. Argotia, U. Landau, A. B. Anderson and J. C. Angus, J. Electrochem. Soc., 143, L133 (1996).
2. K. E. Carter and J. Farrell, Environ. Sci. Technol., 42, 6111 (2008).
3. J. F. Zhi, H. B. Wang, T. Nakashima, T. N. Rao and A. Fujishima, J. Phys. Chem. B, 107, 13389 (2003).
4. B. P. Chaplin, G. Schrader and J. Farrell, Environ. Sci. Technol., 43, 8302 (2009).
5. B. P. Chaplin, G. Schrader and J. Farrell, Environ. Sci. Technol., 44, 4264 (2010).
6. M. J. Pacheco, V. Santos, L. Ciriaco, and A. Lopes, J. Hazard. Mater., 186, 1033 (2011).
7. M. Mascia, A. Vacca, A. M. Polcaro, S. Palmas, J. R. Ruiz and A. Da Pozzo, J. Hazard. Mater., 174, 314 (2010).
8. M. E. H Bergmann, Electrochemistry for the Environment, C. Comninellis and G. Chen, Editors, p. 163, Springer, New York (2009).
9. M. E. H. Bergmann, J. Rollin and T. Iourtchouk, Electrochimica Acta, 54, 2102 (2009).
10. M. E. H. Bergmann and J. Rollin, Catal. Today, 124, 198 (2007).
11. A. M. Polcaro, A. Vacca, M. Mascia, and F. Ferrara, J. Appl. Electrochem. 38, 979 (2008).
12. A. M. Polcaro, A. Vacca, M. Mascia, S. Palmas and J. R. Ruiz, J. Appl. Electrochem. 39, 2083 (2009).
13. E. T. Urbansky and M. R. Schock, J. Environ. Man., 56, 79 (1999).
14. E.T. Urbansky, Environ. Sci. Pollut. Res., 9, 187 (2002).
15. G. Lang and G. Horanyi, J. Electroanal. Chem., 552, 197 (2003).
16. Interim Drinking Water Health Advisory for Perchlorate, EPA 822-R-08-025, U.S. Environmental Protection Agency, Washington, DC (2008).
17. Perchlorate in Drinking Water, R-16-04, California Department of Health Services, Sacramento, California (2007).
18. Perchlorate Information, Massachusetts Department of Environmental Protection, Boston, Massachusetts (2008).
19. J. S. Xu, M. C. Granger, Q. Y. Chen, J. W. Strojek, T. E. Lister and G. M. Swain, Anal. Chem., 69 (19), A591 (1997).
20. H. A. Girard, N. Simon, D. Ballutaud, E. de La Rochefoucauld and A. Etcheberry, Diamond and Related Materials, 16 (4-7), 888 (2007).
21. K. B. Holt, A. J. Bard, Y. Show and G. M. Swain, J. Phys. Chem. B, 108 (39), 15117 (2004).
22. H. B. Martin, A. Argoitia, U. Landau, A. B. Anderson and J. C. Angus, J. Electrochem. Soc., 143 (6), L133 (1996).
23. D. Mishra, Z. H. Liao and J. Farrell, Environ. Sci. Technol., 42, 9344 (2008).
24. B. P. Chaplin, D. K. Hubler and J. Farrell, Electrochimica Acta, 89, 122 (2012).
25. Materials Studio, version 4.2, Accelrys Corporation, San Diego, CA (2007).
26. B. Delley, J. Chem. Phys., 92, 508 (1990).
27. B. Delley, J. Chem. Phys., 113, 7756 (2000).
28. B. Delley, J. Phys. Chem., 100 6107 (1996).
29. A. D. Becke, Phys. Rev. A, 38, 3098 (1988).
30. C. T. Lee, W. T. Yang and R. G. Parr, Phys. Rev. B, 37, 785 (1988).
31. B. Delley, Phys. Rev. B, 66, 155125, 1 (2002).
32. B. Delley, Mol. Simulat., 32, 117 (2006).
33. S. P. de Visser, J. Biocatal. Biotransformation, 1, 1 (2012).
34. A. B. Anderson and D. B. Kang, J. Phys. Chem. A, 102, 5993 (1998).
35. Y. Cai, A. B. Anderson, J. C. Angus, and L. N. Kostadinov, J. Electrochem. Soc., 154 F36 (2007).
36. C. P. Kelly, C. J. Cramer and D. G. Truhlar, J. Phys. Chem. A, 110, 2493 (2006).
37. A. Orchideh, D. K. Hubler, G. Schrader, J. Farrell and B. P. Chaplin, Environ. Sci. Technol., 45 10582 (2011).
38. A. Kraft, Platinum Metals Review, 52 (3), 177 (2008).