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Volumn 16, Issue 32, 2014, Pages 16919-16930

Structural and spectroscopic characterization of E- and Z-isomers of azobenzene

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EID: 84904757610     PISSN: 14639076     EISSN: None     Source Type: Journal    
DOI: 10.1039/c4cp00240g     Document Type: Article
Times cited : (53)

References (108)
  • 1
    • 0012766378 scopus 로고    scopus 로고
    • Royal Society of Chemistry, Cambridge
    • P. Bamfield, Chromic Phenomena, Royal Society of Chemistry, Cambridge, 2nd edn, 2001
    • (2001) Chromic Phenomena
    • Bamfield, P.1
  • 2
    • 0141659045 scopus 로고    scopus 로고
    • K. Hunger, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, FRG
    • Industrial Dyes, ed. K. Hunger, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, FRG, 2003
    • (2003) Industrial Dyes
  • 3
    • 0004240038 scopus 로고    scopus 로고
    • B. L. Feringa, Wiley-VCH Verlag GmbH, Weinheim, FRG
    • Molecular Switches, ed. B. L. Feringa, Wiley-VCH Verlag GmbH, Weinheim, FRG, 2001
    • (2001) Molecular Switches
  • 8
    • 67651184536 scopus 로고    scopus 로고
    • Y. Zhao and T. Ikeda, John Wiley & Sons, Inc., Hoboken, NJ, USA
    • Smart Light-Responsive Materials, ed. Y. Zhao and T. Ikeda, John Wiley & Sons, Inc., Hoboken, NJ, USA, 2009
    • (2009) Smart Light-Responsive Materials
  • 82
    • 85044354091 scopus 로고
    • Generation of Z-azobenzene in the present work is similar to the method discovered by Hartley, in 1937: when azobenzene placed in a glass bottle was exposed to sunlight for several days, Z-AB was generated. See
    • Generation of Z-azobenzene in the present work is similar to the method discovered by Hartley, in 1937: when azobenzene placed in a glass bottle was exposed to sunlight for several days, Z-AB was generated. See: G. S. Hartley Nature, 1937, 140, 281.
    • (1937) Nature , vol.140 , pp. 281
    • Hartley, G.S.1
  • 83
    • 85035218668 scopus 로고    scopus 로고
    • The choice of the model chemistry will be commented in the following section
    • The choice of the model chemistry will be commented in the following section
  • 85
    • 85035215469 scopus 로고    scopus 로고
    • 10-15 cm long, glass and stainless steel
    • 10-15 cm long, glass and stainless steel
  • 87
    • 84892584557 scopus 로고    scopus 로고
    • The average relaxation time of the electronically excited azobenzene is 121 fs. See, for example:, ; and collection of references cited therein. For such a fast relaxation, the steady state spectroscopy allows only for detecting spectra of the electronically relaxed molecules
    • The average relaxation time of the electronically excited azobenzene is 121 fs. See, for example: A. J. Neukirch, L. C. Shamberger, E. Abad, B. J. Haycock, H. Wang, J. Ortega, O. V. Prezhdo, J. P. Lewis J. Chem. Theory Comput., 2014, 10, 14-23. ; and collection of references cited therein. For such a fast relaxation, the steady state spectroscopy allows only for detecting spectra of the electronically relaxed molecules
    • (2014) J. Chem. Theory Comput. , vol.10 , pp. 14-23
    • Neukirch, A.J.1    Shamberger, L.C.2    Abad, E.3    Haycock, B.J.4    Wang, H.5    Ortega, J.6    Prezhdo, O.V.7    Lewis, J.P.8
  • 92
    • 85035194537 scopus 로고    scopus 로고
    • A reason for the E to Z reaction suppression could be ascribed to the specific interaction with the matrix cage and the ability of one of the conformers to fit better within the crystal cage than the other one. Such blocked isomerization reaction can sometimes be unblocked by raising the matrix temperature. We plan to carry out such experiments in future
    • A reason for the E to Z reaction suppression could be ascribed to the specific interaction with the matrix cage and the ability of one of the conformers to fit better within the crystal cage than the other one. Such blocked isomerization reaction can sometimes be unblocked by raising the matrix temperature. We plan to carry out such experiments in future
  • 106
    • 85035222739 scopus 로고    scopus 로고
    • -1), and then the choice of either B97-1 or PW91 functional gives similar quantitative results
    • -1), and then the choice of either B97-1 or PW91 functional gives similar quantitative results


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.