Comprehensive kinetic and mechanistic analysis of TiO2 photocatalytic reactions according to the direct-indirect model: (II) experimental validation

Journal of Physical Chemistry C

Volumn 118, Issue 26, 2014, Pages 14276-14290

  Montoya, Juan F ^a   Atitar, Mohamed F ^b   Bahnemann, Detlef W ^b   Peral, José ^a   Salvador, Pedro ^a  

^a UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

^b LEIBNIZ UNIVERSITY HANNOVER   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONITRILE; CHEMISORPTION; DESORPTION; DISSOLUTION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; KINETICS; MOLECULES; PHYSISORPTION; TITANIUM DIOXIDE;

ADSORPTION DESORPTION; ELECTRONIC INTERACTIONS; EXPERIMENTAL KINETICS; EXPERIMENTAL VALIDATIONS; ILLUMINATION INTENSITY; PHOTOCATALYTIC OXIDATIONS; PHOTOCATALYTIC REACTIONS; SPECIES INTERACTIONS;

PHOTOOXIDATION;

EID: 84903773670     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp4121657     Document Type: Article

References (80)

1. 2 Photocatalytic Reactions According to the Direct-Indirect Model: (I) Theoretical Approach J. Phys. Chem. C 2014, 10.1021/jp4121645
2. Zhang, L.; Mohamed, H. H.; Dillert, R.; Bahnemann, D. Kinetics and Mechanisms of Charge Transfer Processes in Photocatalytic Systems: A Review J. Photochem. Photobiol., C 2012, 13, 263-276
3. 2 Nanoparticle Suspensions J. Phys. Chem. B 2004, 108, 20278-20290
4. Monllor-Satoca, D.; Gomez, R.; Gonzalez-Hidalgo, M.; Salvador, P. The "Direct-Indirect" Model: An Alternative Kinetic Approach in Heterogeneous Photocatalysis Based on the Degree of Interaction of Dissolved Pollutant Species with the Semiconductor Surface Catal. Today 2007, 129, 247-255
5. Turchi, C. S.; Ollis, D. F. Photocatalytic Degradation of Organic Water Contaminants: Mechanisms Involving Hydroxyl Radical Attack J. Catal. 1990, 122, 178-192
6. 2 Aqueous Dispersions Appl. Catal., B 2009, 88, 50-58
7. 2 Aqueous Dispersions: An Analysis in the Light of the Direct-Indirect Kinetic Model Appl. Catal., B 2010, 94, 97-107
8. 2-Film Electrodes" by J. Yang, J. Dai, Ch. Chen, J. Zhao; J. Photochem. Photobiol. A: Chem. 208 (2009) 66-77 J. Photochem. Photobiol., A 2010, 210, 215-216
9. 2 Interface in the Presence and Absence of Organic Contaminants: the Role of Bridging Oxygen Ions and Adsorbed Water ChemPhysChem 2011, 12, 901-907
10. 2 under Anaerobic Conditions J. Phys. Chem. Lett. 2013, 4, 1415-1422
11. Cassano, A. E.; Martin, C. A.; Brandi, R. J.; Alfano, O. M. Photoreactor Analysis and Design: Fundamentals and Applications Ind. Eng. Chem. Res. 1995, 34, 2155-2201
12. Dillert, R.; Cassano, A. E.; Goslich, R.; Bahnemann, D. Large Scale Studies in Solar Catalytic Wastewater Treatment Catal. Today 1999, 54, 267-282
13. Cassano, A. E.; Alfano, O. M. Reaction Engineering of Suspended Solid Heterogeneous Photocatalytic Reactors Catal. Today 2000, 58, 167-197
14. Sagawe, G.; Brandi, J.; Bahnemann, D.; Cassano, A. E. Photocatalytic Reactors for Treating Water Pollution with Solar Illumination. I: A simplified Analysis for Batch Reactors Chem. Eng. Sci. 2003, 58, 2587-2599
15. Sagawe, G.; Brandi, J.; Bahnemann, D.; Cassano, A. E. Photocatalytic Reactors for Treating Water Pollution with Solar Illumination. II: A simplified Analysis for Flow Reactors Chem. Eng. Sci. 2003, 58, 2601-2615
16. Sagawe, G.; Brandi, R. J.; Bahnemann, D.; Cassano, A. E. Photocatalytic Reactors for Treating Water Pollution with Solar Illumination. III: a Simplified Analysis for Recirculating Reactors Sol. Energy 2004, 77, 471-489
17. Mueses, M. A.; Machuca-Martinez, F.; Puma, G. L. Effective Quantum Yield and Reaction Rate Model for Evaluation of Photocatalytic Degradation of Water Contaminants in Heterogeneous Pilot-Scale Solar Photoreactors Chem. Eng. J. 2013, 215, 937-947
18. Hoffmann, M. R.; Martin, S. T.; Choi, W.; Bahnemann, D. W. Environmental Applications of Semiconductor Photocatalysis Chem. Rev. 1995, 95, 69-96
19. Peral, J.; Domenech, X.; Ollis, D. F. Heterogeneous Photocatalysis for Purification, Decontamination and Deodorization of Air J. Chem. Technol. Biotechnol. 1997, 70, 117-140
20. Matthews, R. W. Kinetics of Photocatalytic Oxidation of Organic Solutes over Titanium Dioxide J. Catal. 1988, 111, 264-272
21. Matthews, R. W. Photooxidation of Organic Impurities in Water Using Thin Films of Titanium Dioxide J. Phys. Chem. 1987, 91, 3328-3333
22. Minero, C.; Catozzo, F.; Pelizzetti, E. Role of Adsorption in Photocatalyzed Reactions of Organic Molecules in Aqueous Titania Suspensions Langmuir 1992, 8, 481-486
23. 2 for Water Treatment: Parameters Affecting the Kinetics and Mechanisms of Photocatalysis Appl. Catal., B 2010, 99, 398-406
24. Minero, C. Kinetic Analysis of Photoinduced Reactions at the water Semiconductor Interface Catal. Today 1999, 54, 205-216
25. Emeline, A. V.; Ryabchuk, V.; Serpone, N. Factors Affecting the Efficiency of a Photocatalyzed Process in Aqueous Metal-Oxide Dispersions: Prospect of Distinguishing Between Two Kinetic Models J. Photochem. Photobiol., A 2000, 133, 89-97
26. Emeline, A. V.; Ryabchuk, V. K.; Serpone, N. Dogmas and Misconceptions in Heterogeneous Photocatalysis. Some Enlightened Reflections J. Phys. Chem. B 2005, 109, 18515-18521
27. Ollis, D. F. Kinetics of Liquid Phase Photocatalyzed Reactions: An Illuminating Approach J. Phys. Chem. B 2005, 109, 2439-2444
28. Ollis, D. Kinetic Disguises in Heterogeneous Photocatalysis Top. Catal. 2005, 35, 217-223
29. Mills, A.; Wang, J.; Ollis, D. F. Kinetics of Liquid Phase Semiconductor Photoassisted Reactions: Supporting Observations for a Pseudo-Steady-State Model J. Phys. Chem. B 2006, 110, 14386-14390
30. Mills, A.; Wang, J.; Ollis, D. F. Dependence of the Kinetics of Liquid-Phase Photocatalyzed Reactions on Oxygen Concentration and Light Intensity J. Catal. 2006, 243, 1-6
31. Ohtani, B. Preparing Articles on Photocatalysis: Beyond The Illusions, Misconceptions and Speculation Chem. Lett. 2008, 37, 216-229
32. Minero, C.; Bedini, A.; Maurino, V. Glycerol as a Probe Molecule to Uncover Oxidation Mechanism in Photocatalysis Appl. Catal., B 2012, 128, 135-143
33. 2 New Photochemical Processes Chem. Rev. 2006, 106, 4428-4453
34. 2(110) Chem. Soc. Rev. 2008, 37, 2328-2353
35. 2 Photocatalysis Surf. Sci. Rep. 2011, 66, 185-297
36. 2 in the Aqueous Phase Langmuir 1994, 10, 3587-3597
37. Weisz, A. D.; García Rodenas, L.; Morando, P. J.; Regazzoni, A. E.; Blesa, M. A. FTIR Study of the Adsorption of Single Pollutants and Mixtures of Pollutants onto Titanium Dioxide in Water: Oxalic and Salicylic Acids Catal. Today 2002, 76, 103-112
38. Araujo, P. Z.; Mendive, C. B.; Rodenas, L. A. G.; Morando, P. J.; Regazzoni, A. E.; Blesa, M. A.; Bahnemann, D. FT-IR-ATR as a Tool to Probe Photocatalytic Interfaces Colloids Surf., A 2005, 265, 73-80
39. Lana-Villarreal, T.; Rodes, A.; Perez, J. M.; Gomez, R. A Spectroscopic and Electrochemical Approach to the Study of the Interactions and Photoinduced Electron Transfer between Catechol and Anatase Nanoparticles in Aqueous Solution J. Am. Chem. Soc. 2005, 127, 12601-12611
40. 2 by FTIR-ATR Catal. Today 2005, 101, 237-244
41. 2 Phys. Chem. Chem. Phys. 2006, 8, 3232-3247
42. Mendive, C. B.; Bredow, T.; Feldhoff, A.; Blesa, M.; Bahnemann, D. Adsorption of Oxalate on Rutile Particles in Aqueous Solutions: a Spectroscopic, Electron-Microscopic and Theoretical Study Phys. Chem. Chem. Phys. 2008, 10, 1960-1974
43. 2-Assisted Photooxidation of Phenol and p-Halophenols under Weak Room Light Irradiance J. Photochem. Photobiol., A 2008, 194, 189-199
44. Mendive, C. B.; Bredow, T.; Feldhoff, A.; Blesa, M. A.; Bahnemann, D. Adsorption of Oxalate on Anatase (100) and Rutile (110) Particles in Aqueous Systems: Experimental Results vs. Theoretical Predictions Phys. Chem. Chem. Phys. 2009, 11, 1794-1808
45. Minella, M.; Faga, M. G.; Maurino, V.; Minero, C.; Pelizzetti, E.; Coluccia, S.; Martra, G. Effect of Fluorination on the Surface Properties of Titania P25 Powder: An FTIR Study Langmuir 2010, 26, 2521-2527
46. Kim, S.; Choi, W. Visible-Light-Induced Photocatalytic Degradation of 4-Chlorophenol and Phenolic Compounds in Aqueous Suspension of Pure Titania: Demonstrating the Existence of a Surface-Complex-Mediated Path J. Phys. Chem. B 2005, 109, 5143-5149
47. Hatchard, C. G.; Parker, C. A. A New Sensitive Chemical Actinometer. II. Potassium Ferrioxalate as a Standard Chemical Actinometer Proc. R. Soc. London, Ser. A 1956, 235, 518-536
48. 2 Polycrystalline Surfaces: A Study of Environmental Interfaces by NEXAFS, XPS, and UPS Langmuir 2007, 23, 9551-9554
49. Wang, Y.; Hang, K.; Anderson, N. A.; Lian, T. Comparison of Electron Transfer Dynamics in Molecule-to-Nanoparticle and Intramolecular Charge Transfer Complexes J. Phys. Chem. B 2003, 107, 9434-9440
50. 2 Surface Langmuir 2004, 20, 2753-2759
51. 2: Influence of Contacting Solvent and Interphacial Electron Transfer J. Phys. Chem. C 2008, 112, 12786-12794
52. Greaves, S. J.; Griffith, W. P. Vibrational-Spectra of Catechol, Catechol-D2 and Catechol-D6 and the Catecholate Monoanion Spectrochim. Acta, Part A 1991, 47, 133-140
53. Gunzler, H.; Gremlich, H. U. IR Spectroscopy. An Introduction, Wiley-VCH: Weinheim, 2002.
54. Zierkiewicz, W.; Michalska, D.; Zeegers-Huyskens, T. Molecular Structures and Infrared Spectra of p -Chlorophenol and p -Bromophenol. Theoretical and Experimental Studies J. Phys. Chem. A 2000, 104, 11685-11692
55. Zierkiewicz, W.; Michalska, D.; Czarnik-Matusewicz, B.; Rospenk, M. Molecular Structure and Infrared Spectra of 4-Fluorophenol: A Combined Theoretical and Spectroscopic Study J. Phys. Chem. A 2003, 107, 4547-4554
56. a from Anodic Voltammetry Data J. Electroanal. Chem. 1993, 353, 57-69
57. 2 from an Aqueous Solution Langmuir 1998, 14, 6479-6484
58. 2(110): Experimental Characterization and First-Principles Calculations Phys. Rev. B 2006, 74, 125318-1-125318-11
59. 2 Photocatalytic Activities Ber. Bunsen-Ges. 1990, 94, 1439-1443
60. Kormann, C.; Bahnemann, D. W.; Hoffmann, M. R. Photolysis of Chloroform and Other Organic Molecules in Aqueous Titanium Dioxide Suspensions Environ. Sci. Technol. 1991, 25, 494-500
61. 2 Aqueous Suspension: Initial Photonic Efficiency and Initial Oxidation Rate as a Function of Methylviologen Concentration and Light Intensity J. Photochem. Photobiol., A 2000, 134, 219-226
62. 2 and Multiactivity Test for Water Treatment Application Environ. Sci. Technol. 2008, 42, 294-300
63. Fox, M. A.; Chen, C. C. Mechanistic Features of the Semiconductor Photocatalyzed Olefin-to-Carbonyl Oxidative Cleavage J. Am. Chem. Soc. 1981, 103, 6757-6759
64. Pysh, E. S.; Yang, N. C. Polarographic Oxidation Potentials of Aromatic Compounds J. Am. Chem. Soc. 1963, 85, 2124-2130
65. Wardman, P. Reduction Potentials of One-Electron Couples Involving Free Radicals in Aqueous Solution J. Phys. Chem. Ref. Data 1989, 18, 1637-1755
66. Li, C.; Hoffman, M. Z. One-Electron Redox Potentials of Phenols in Aqueous Solution J. Phys. Chem. B 1999, 103, 6653-6656
67. Grampp, G.; Landgraf, S.; Mureçanu, C. Redox Properties and Bond Dissociations Energies of Phenoxyl Radicals Electrochim. Acta 2004, 49, 537-544
68. Serpone, N.; Terzian, R.; Lawless, D.; Kennepohl, P.; Sauvé, G. On the Usage of Turnover Numbers and Quantum Yields in Heterogeneous Photocatalysis J. Photochem. Photobiol., A 1993, 73, 11-16
69. 2 Powder Bull. Chem. Soc. Jpn. 1985, 58, 2015-2022
70. 2 Sintering Temperature on Photocatalytic Removal of Phenol, Anisole, and Pyridine in Water J. Photochem. Photobiol., A 2006, 180, 130-135
71. Minero, C.; Mariella, G.; Maurino, V.; Pelizzetti, E. Photocatalytic Transformation of Organic Compounds in the Presence of Inorganic Anions. 1. Hydroxyl-Mediated and Direct Electron-Transfer Reactions of Phenol on a Titanium Dioxide-Fluoride System Langmuir 2000, 16, 2632-2641
72. Minero, C.; Mariella, G.; Maurino, V.; Vione, D.; Pelizzetti, E. Photocatalytic Transformation of Organic Compounds in the Presence of Inorganic Ions. 2. Competitive Reactions of Phenol and Alcohols on a Titanium Dioxide-Fluoride System Langmuir 2000, 16, 8964-8972
73. 2 Surface Fluorination on Photocatalytic Reactions and Photoelectrochemical Behaviors J. Phys. Chem. B 2004, 108, 4086-4093
74. 2 Catalysts Appl. Catal., B 2010, 100, 346-354
75. 2-catalyzed Photoreactions Faraday Discuss. Chem. Soc. 1984, 78, 151-163
76. 2 J. Phys. Chem. 1984, 88, 709-711
77. 2 Particles: Reactivity of Free and Trapped Holes J. Phys. Chem. B 1997, 101, 4265-4275
78. Lawless, D.; Serpone, N.; Meisel, D. Role of Hydroxyl Radicals and Trapped Holes in Photocatalysis. A Pulse Radiolysis Study J. Phys. Chem. 1991, 95, 5166-5170
79. Rajh, T.; Saponjic, Z. V.; Micic, O. I. Reactions of Hydrous Titanium Oxide Colloids with Strong Oxidizing Agents Langmuir 1992, 8, 1265-1270
80. 2 Aqueous Suspensions: A Revision in the Light of the Electronic Structure of Adsorbed Water J. Phys. Chem. C 2007, 111, 17038-17043