Dogmas and misconceptions in heterogeneous photocatalysis. Some enlightened reflections

Journal of Physical Chemistry B

Volumn 109, Issue 39, 2005, Pages 18515-18521

  Emeline, A V ^a   Ryabchuk, V K ^b   Serpone, N ^c,d  

^a KANAGAWA ACADEMY OF SCIENCE AND TECHNOLOGY   (Japan)

^b ST PETERSBURG STATE UNIVERSITY   (Russian Federation)

^c UNIVERSITY OF PAVIA   (Italy)

^d Gina Cody School of Engineering and Computer Science   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; CATALYSTS; CHARGE CARRIERS; DESORPTION; PHOTONS;

KINETIC MODELS; PHOTOCATALYSTS KINETICS; PHOTOGENERATED FREE CHARGE CARRIERS; SURAFACE PHOTOCHEMICAL REACTIONS;

PHOTOCATALYSIS;

EID: 26844563677     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0523367     Document Type: Article

References (63)

1. Ollis, D. F. J. Phys. Chem. B 2005, 109, 2439.
2. Emeline, A. V.; Ryabchuk, V. K.; Serpone, N. J. Photochem. Photobiol., A 2000, 133, 89.
3. Xu, Y.; Langford, C. H. J. Photochem. Photobiol., A 2000, 133, 67.
4. Martyanov, I.; Savinov, E. J. Photochem. Photobiol., A 2000, 134, 219.
5. (a) Wu, J.-F.; Hung, C.-H.; Yuan, C.-S. J. Photochem. Photobiol., A 2005, 170, 299
6. (b) Xu, T.; Cai, Y.; O'Shea, K. E. Ext. Abstr. ACS Natl. Meet., Div. Environ. Chem. 2005, 45, 335.
7. (c) Raillard, C.; Hequet, V.; Le Cloirec, P.; Legrand, J. Water Sci. Technol. 2004, 49, 111.
8. (d) McMurray, T. A.; Byrne, J. A.; Dunlop, P. S. M.; Winkelman, J. G. M.; Eggins, B. R.; McAdams, E. T. Appl. Catal., A 2004, 262, 105;
9. (e) Al-Rasheed, R.; Cardin, D. J. Chemosphere 2003, 51, 925.
10. (f) Li, X. Z.; Liu, H.; Cheng, L.; Tong, H. J. Environ. Sci. Technol. 2003, 37, 3989.
11. (g) Arsla, I.; Balcioglu, I. A.; Bahnemann, D. W. Dyes Pigm. 2000, 47, 207.
12. (h) Arsla, I.; Balcioglu, I. A.; Bahnemann, D. W. Appl. Catal., B 2000, 26, 193.
13. (i) Martinez, M. A.; Nunez, A.; Lopez, R.; Morales, F.; Nunez, O. Acta Cient. Venez. 1999, 50, 81.
14. (j) Augugliaro, V.; Galvez, J. B.; Vasquez, J. C.; Lopez, E. G.; Loddo, V.; Munoz, M. J. L.; Rodriguez, S. M.; Marci, G.; Palmisano, L.; Schiavello, M.; Ruiz, J. S. Catal. Today 1999, 54, 245.
15. (k) Ilisz, I.; Laszlo, Z.; Dombi, A. Appl. Catal., A1999, 180, 25.
16. (l) Noguchi, T.; Fujishima, A.; Sawunyama, P.; Hashimoto, K. Environ. Sci. Technol. 1998, 32, 3831.
17. (m) Augugliaro, V.; Loddo, V.; Marci, G.; Palmisano, L.; Lopez-Munoz, M. J. J. Catal. 1997, 166, 272.
18. (n) Inel, Y.; Oekte, A. N. Toxicol. Environ. Chem. 1996, 55, 115.
19. (o) Inel, Y.; Oekte, A. N. J. Photochem. Photobiol, A 1996, 96, 175.
20. (p) Tang, W. Z.; An, H. Chemosphere 1995, 31, 4157.
21. (q) Trillas, M.; Peral, J.; Domenech, X. Appl. Catal., B 1995, 5, 377.
22. (r) Brezova, V.; Stasko, A. J. Catal. 1994, 147, 156.
23. (s) O'Shea, K. E.; Cardona, C. J. Org. Chem. 1994, 59, 5005.
24. (t) Lozano, A.; Garcia, J.; Domenech, X.; Casado J. J. Photochem. Photobiol., A 1992, 69, 237.
25. Al-Ekabi, H.; Serpone, N.; Pelizzetti, E.; Minero, C.; Fox, M. A.; Draper, R. B. Langmuir 1989, 5, 250.
26. (a) Kabel, R. L.; Johanson, L. N. AIChE J. 1962, 8, 621.
27. (b) Chu, C. Ind. Eng. Chem. Fundam. 1967, 7, 509.
28. (c) Chan, A. Y. V.; Dalla Lana, I. G. Can. J. Chem. Eng. 1978, 56, 751.
29. (d) Hesse, D. Chem.-Ing.-Technol. 1979, 57, 828.
30. (e) Santacesaria, E. Catal. Today 1997, 34, 393.
31. (f) Peppley, B. A.; Amphlett, J. C.; Kerans, L. M.; Mann, R. F.; Roberge, P. R. Proc. Intersoc. Energy Convers. Eng. Conf. 1997, 32, 831.
32. (g) Sun, M.; Prins, R. J. Catal. 2001, 201, 138.
33. (h) Setinc, M.; Levee, J. Chem. Eng. Sci. 2001, 56, 6081.
34. (i) Karinen, R. S.; Krause, A.; Outi, I. Ind. Eng. Chem. Res. 2001, 40, 6073.
35. (j) Arena, F.; Parmaliana, A. Acc. Chem. Res. 2003, 36, 667.
36. (k) Vogelaar, B. M.; Kagani, N.; van Langeveid, A. D.; Eijsbouts, S.; Moulijin, J. A. In Abstracts of Papers, 226th ACS National Meeting, New York, Sept 7-11, 2003; American Chemical Society: Washington DC, 2003.
37. Lee, W.; Batchelor, B. Chemosphere 2004, 56, 999.
38. Thomson, S. J.; Webb, G. Heterogeneous Catalysis; Oliver & Boyd: Edinburgh, London, 1968.
39. Rapoport, V. L.; Antipenko, B. M.; Malkin, M. G. Kinet. Ratal. 1968, 9, 1306.
40. Volodin, A. M.; Bolshov, V. A.; Konovalova, T. A. Mol. Eng. 1994, 4, 201.
41. Emeline, A. V.; Ryabchuk, V. K. Russ. J. Phys. Chem. 1997, 7, 2085.
42. Ryabchuk, V. K.; Basov, L. L.; Solonitzin, Yu. P. Khim. Fiz. 1989, 8, 1475.
43. Dolgikh, Yu. K.; Basov, L. L.; Ryabchuk, V. K. React. Kinet. Catal. Lett. 1986, 32, 119.
44. Solonitsin, Yu. P.; Basov, L. L.; Ryabchuk, V. K. Russ. J. Phys. Chem. 1980, 54, 2619.
45. Mesheryakov, E. P.; Emeline, A. V.; Ryabchuk, V. K.; Minakova, T. S. Kinet. Katal. 1992, 33, 469.
46. Basov, L. L.; Kuzmin, G. N.; Prudnikov, I. M.; Solonitzyn, Yu. P. Usp. Fotoniki 1977, 6, 82.
47. Fox, M. A.; Dulay, M. T. Chem. Rev. 1993, 93, 341.
48. Pichat, P.; Herrmann, J.-M. In Photocatalysis-Fundamentals and Applications; Serpone, N., Pelizzetti, E., Eds.; John Wiley & Sons: New York, 1989; p 218-250
49. Turchi, C. S.; Ollis, D. F. J. Catal. 1990, 122, 178.
50. Terzian, R.; Serpone, N. J. Photochem. Photobiol., A 1995, 89, 163.
51. (a) Al-Ekabi, H.; Serpone, N. In Photocatalysis. Fundamentals and Applications; Serpone, N.; Pelizzetti, E., Eds.; John Wiley & Sons: New York, 1989; p 457.
52. (b) Ollis, D. F.; Pelizzetti, E.; Serpone, N. In Photocatalysis. Fundamentals and Applications, Serpone, N.; Pelizzetti, E., Eds.; John Wiley & Sons: New York, 1989; p 639.
53. Emeline, A. V.; Rudakova, A. V.; Ryabchuk, V. K.; Serpone, N. J. Phys. Chem. B 1998, 102, 10906.
54. Fermi, E. Molecules, Crystals and Quantum Statistics; Benjamin Publishers: New York, 1966.
55. Pleskov, Yu. V.; Gurevich, Yu. Ya. Semiconductor Photoelectrochemistry; Consultants Bureau: New York, 1986
56. Bonch-Bruevich, V. L.; Kalashnikov, S. G. The Physics of Semiconductors, 2nd ed.; Nauka: Moscow, 1990.
57. Bube, R. H. Photoconductivity of Solids; J. Wiley & Sons Inc.: New York, 1960.
58. Actually, both restrictions are always present because they are general. Whereas the energy conservation is easily covered by the emission of photons, the momentum conservation is overcome because of the uncertainty principle. Indeed, for a free charge carrier, the momentum has a finite value, but its positional coordinates are uncertain; that is, whereas the free charge carrier belongs to the whole crystal (i.e., it is delocalized over the whole crystal) the coordinates of the trapped charge carrier are pretty well-defined by the coordinates of the defects. In classical physics, this is equivalent to an inelastic collision of a charge carrier with a very massive body. Thus, the momentum of the trapped carrier is also elusive.
59. Solonitsyn, Yu. P. Kinet. Katal. 1966, 7, 480.
60. Solonitsyn, Yu. P.; Kuzmin, G. N.; Shurigin, F. L.; Yurkin V. M. Kinet. Katal. 1976, 17, 1267
61. (a) Bickley, R. I. Catalysis 1982, 5, 308;
62. (b) Chem. Phys. Solid Surf. 1977, 7, 118.
63. Serpone, N.; Emeline A. V. Int. J. Photoenergy 2002, 4, 91.