Enhanced permittivity and energy density in neat poly(vinylidene fluoride-trifluoroethylene-chlorotrifluoroethylene) terpolymer films through control of morphology

ACS Applied Materials and Interfaces

Volumn 6, Issue 12, 2014, Pages 9584-9589

  Smith, O'Neil L ^a   Kim, Yunsang ^b   Kathaperumal, Mohanalingam ^a   Gadinski, Matthew R ^d   Pan, Ming Jen ^c   Wang, Qing ^d   Perry, Joseph W ^a  

^a GEORGIA INSTITUTE OF TECHNOLOGY   (United States)

^b Georgia Institute of Technology   (United States)

^c NAVAL RESEARCH LABORATORY   (United States)

^d PENNSYLVANIA STATE UNIVERSITY   (United States)

Author keywords

capacitor; dielectric; energy density; high permittivity; terpolymer

Indexed keywords

CAPACITORS; CRYSTALLINE MATERIALS; DIELECTRIC MATERIALS; ELECTRIC FIELDS; FERROELECTRIC FILMS; HEAT TREATMENT; MORPHOLOGY; PERMITTIVITY; TERPOLYMERS;

CONTROL OF MORPHOLOGY; CRYSTALLINE MORPHOLOGIES; ENERGY DENSITY; HIGH ENERGY DENSITY CAPACITORS; HIGH PERMITTIVITY; LARGE DIELECTRIC CONSTANT; POLARIZATION BEHAVIOR; PROCESSING CONDITION;

POLYMER FILMS;

EID: 84903526803     PISSN: 19448244     EISSN: 19448252     Source Type: Journal    
DOI: 10.1021/am501968q     Document Type: Article

References (40)

1. Cao, Y.; Irwin, P. C.; Younsi, K. The Future of Nanodielectrics in the Electrical Power Industry IEEE. T. Dielect. El. Insul. 2004, 11, 797-807
2. Wang, Q.; Zhu, L. Polymer Nanocomposites for Electrical Energy Storage J. Polym. Sci., Polym. Phys. 2011, 49, 1421-1429
3. Nalwa, H. S. Handbook of Low and High Dielectric Constant Materials and Their Applications; Academic Press: New York, 1999.
4. Barber, P.; Balasubramanian, S.; Anguchamy, Y.; Gong, S.; Wibowo, A.; Gao, H.; Ploehn, H. J.; zur Loye, H. C. Polymer Composite and Nanocomposite Dielectric Materials for Pulse Power Energy Storage Materials 2009, 2, 1697-1733
5. Sarjeant, W. J.; Clelland, I. W.; Price, R. A. Capacitive Components for Power Electronics Proc. IEEE 2001, 89, 846-855
6. Sarjeant, W. J.; Zirnheld, J.; MacDougall, F. W. Capacitors IEEE. T. Plasma Sci. 1998, 26, 1368-1392
7. Starkweather, H. W.; Avakian, P.; Matheson, R. R.; Fontanella, J. J.; Wintersgill, M. C. Ultralow Temperature Dielectric Relaxations in Polyolefins Macromolecules 1992, 25, 6871-6875
8. Yao, K.; Chen, S.; Rahimabady, M.; Mirshekarloo, M. S.; Yu, S.; Tay, F. E. H.; Sritharan, T.; Lu, L. Nonlinear Dielectric Thin Films for High-Power Electric Storage with Energy Density Comparable with Electrochemical Supercapacitors IEEE. T. Ultrason. Ferro. 2011, 58, 1968-1974
9. Chu, B.; Zhou, X.; Ren, K.; Neese, B.; Lin, M.; Wang, Q.; Bauer, F.; Zhang, Q. M. A Dielectric Polymer with High Electric Energy Density and Fast Discharge Speed Science 2006, 313, 334-336
10. Ho, J.; Ramprasad, R.; Boggs, S. Effect of Alteration of Antioxidant by UV treatment on the Dielectric Strength of BOPP Capacitor Film IEEE. T. Dielect. El. Insul. 2007, 14, 1295-1301
11. Rabuffi, M.; Picci, G. Status Quo and Future Prospects for Metallized Polypropylene Energy Storage Capacitors IEEE. T. Plasma Sci. 2002, 30, 1939-1942
12. Wu, S.; Li, W. P.; Lin, M. R.; Burlingame, Q.; Chen, Q.; Payzant, A.; Xiao, K.; Zhang, Q. M. Aromatic Polythiourea Dielectrics with Ultrahigh Breakdown Field Strength, Low Dielectric Loss, and High Electric Energy Density Adv. Mater. 2013, 25, 1734-1738
13. Wu, S.; Lin, M. R.; Burlingame, Q.; Zhang, Q. M. Meta-aromatic polyurea with high dipole moment and dipole density for energy storage capacitors Appl. Phys. Lett. 2014, 104, 072903
14. Lorenzini, R. G.; Kline, W. M.; Wang, C. C.; Ramprasad, R.; Sotzing, G. A. The rational design of polyurea & polyurethane dielectric materials Polymer 2013, 54, 3529-3533
15. Zhu, L.; Wang, Q. Novel Ferroelectric Polymers for High Energy Density and Low Loss Dielectrics Macromolecules 2012, 45, 2937-2954
16. Lovinger, A. J.; Davis, D. D.; Cais, R. E.; Kometani, J. M. The Role of Molecular Defects on the Structure and Phase-Transition of Poly(Vinylidene Fluoride) Polymer 1987, 28, 617-626
17. Xia, F.; Cheng, Z. Y.; Xu, H. S.; Li, H. F.; Zhang, Q. M.; Kavarnos, G. J.; Ting, R. Y.; Abdul-Sedat, G.; Belfield, K. D. High Electromechanical Responses in a Poly(Vinylidene Fluoride-Trifluoroethylene-Chlorofluoroethylene) Terpolymer Adv. Mater. 2002, 14, 1574-1577
18. Xu, H. S.; Cheng, Z. Y.; Olson, D.; Mai, T.; Zhang, Q. M.; Kavarnos, G. Ferroelectric and Electromechanical Properties of Poly(Vinylidene-Fluoride- Trifluoroethylene-Chlorotrifluoroethylene) Terpolymer Appl. Phys. Lett. 2001, 78, 2360-2362
19. Lu, Y. Y.; Claude, J.; Neese, B.; Zhang, Q. M.; Wang, Q. A Modular Approach to Ferroelectric Polymers with Chemically Tunable Curie Temperatures and Dielectric Constants J. Am. Chem. Soc. 2006, 128, 8120-8121
20. Chung, T. C.; Petchsuk, A. Synthesis and Properties of Ferroelectric Fluoroterpolymers with Curie Transition at Ambient Temperature Macromolecules 2002, 35, 7678-7684
21. Gregorio, R.; Ueno, E. M. Effect of Crystalline Phase, Orientation and Temperature on the Dielectric Properties of Poly (Vinylidene Fluoride) (PVDF) J. Mater. Sci. 1999, 34, 4489-4500
22. Sencadas, V.; Gregorio, R.; Lanceros-Mendez, S. Alpha to Beta Phase Transformation and Microstructural Changes of PVDF Films Induced by Uniaxial Stretch J. Macromol. Sci. B 2009, 48, 514-525
23. Branciforti, M. C.; Sencadas, V.; Lanceros-Mendez, S.; Gregorio, R. New Technique of Processing Highly Oriented Poly(Vinylidene Fluoride) Films Exclusively in the Beta Phase J. Polm. Sci. Polym. Phys. 2007, 45, 2793-2801
24. Sencadas, V.; Gregorio, R.; Lanceros-Mendez, S. Processing and Characterization of a Novel Nonporous Poly(Vinilidene Fluoride) Films in the Beta Phase J. Non-Cryst. Solids 2006, 352, 2226-2229
25. Bao, H. M.; Song, J. F.; Zhang, J.; Shen, Q. D.; Yang, C. Z.; Zhang, Q. M. Phase Transitions and Ferroelectric Relaxor Behavior in P(VDF-TrFE-CFE) Terpolymers Macromolecules 2007, 40, 2371-2379
26. Ranjan, V.; Nardelli, M. B.; Bernholc, J. Electric Field Induced Phase Transitions in Polymers: A Novel Mechanism for High Speed Energy Storage Phys. Rev. Lett. 2012, 108, 087802-1-087802-5
27. Ranjan, V.; Yu, L.; Nardelli, M. B.; Bernholc, J. Phase Equilibria in High Energy Density PVDF-Based Polymers Phys. Rev. Lett. 2007, 99, 047801-1-047801-4
28. Su, H. B.; Strachan, A.; Goddard, W. A. Density Functional Theory and Molecular Dynamics Studies of the Energetics and Kinetics of Electroactive Polymers: PVDF and P(VDF-TrFE) Phys. Rev. B 2004, 70, 064101-1-064101-8
29. Lu, Y.; Claude, J.; Zhang, Q.; Wang, Q. Microstructures and Dielectric Properties of the Ferroelectric Fluoropolymers Synthesized via Reductive Dechlorination of Poly(Vinylidene Fluoride-co-Chlorotrifluoroethylene)s Macromolecules 2006, 39, 6962-6968
30. 3 and a Ferroelectric Polymer ACS Nano 2009, 3, 2581-2592
31. Kim, Y.; Kathaperumal, M.; Smith, O. L.; Pan, M. J.; Cai, Y.; Sandhage, K. H.; Perry, J. W. High-Energy-Density Sol-Gel Thin Film Based on Neat 2-Cyanoethyltrimethoxysilane ACS Appl. Mater. Interfaces 2013, 5, 1544-1547
32. Lovinger, A. J. Ferroelectric Polymers Science 1983, 220, 1115-1121
33. Hasegawa, R.; Takahash, Y.; Tadokoro, H.; Chatani, Y. Crystal Structures of 3 Crystalline Forms of Poly(Vinylidene fluoride) Polym. J. (Tokyo, Jpn.) 1972, 3, 600-610
34. Tashiro, K.; Takano, K.; Kobayashi, M.; Chatani, Y.; Tadokoro, H. Structure and ferroelectric Phase-Transition of vinylidene Fluoride- Trifluoroethylene Copolymers. 2. VDF 55-Percent Copolymer Polymer 1984, 25, 195-208
35. Skoog, D. A.; Holler, F. J.; Crouch, S. R. Principles of Instrumental Analysis, 6 th ed.; Thomas Higher Education: CA, 2007.
36. Cheng, Z. Y.; Olson, D.; Xu, H. S.; Xia, F.; Hundal, J. S.; Zhang, Q. M.; Bateman, F. B.; Kavarnos, G. J.; Ramotowski, T. Structural Changes and Transitional Behavior Studied from both Micro- and Macroscale in the High-Energy Electron-Irradiated Poly(Vinylidene Fluoride-Trifluoroethylene) Copolymer Macromolecules 2002, 35, 664-672
37. Weibull, W. A Statistical Distribution Function of Wide Applicability J. Appl. Mech-T. Asme. 1951, 18, 293-297
38. Dissado, L. A.; Fothergill, J. C.; Wolfe, S. V.; Hill, R. M. Weibull Statistics in Dielectric-Breakdown heoretical Basis, Applications and Implications IEEE Trans. Electr. Insul. 1984, 19, 227-233
39. Xia, F.; Zhang, Q. M. Schottky Emission at the Metal Polymer Interface and its Effect on the Polarization Switching of Ferroelectric Poly(Vinylidene Fluoride-Trifluoroethylene) Copolymer Thin Films Appl. Phys. Lett. 2004, 85, 1719-1721
40. Gao, K. C. Dielectric Phenomena in Solids; Elsevier Academic Press: San Diego, 2004.