Surface strontium segregation of solid oxide fuel cell cathodes proved by in situ depth-resolved x-ray absorption spectroscopy

ECS Electrochemistry Letters

Volumn 3, Issue 4, 2014, Pages

  Orikasa, Yuki ^a   Crumlin, Ethan J ^b   Sako, Shinnosuke ^a   Amezawa, Koji ^c   Uruga, Tomoya ^d   Biegalski, Michael D ^c   Christen, Hans M ^e   Uchimoto, Yoshiharu ^a   Yang, Shao Horn ^b  

^a KYOTO UNIVERSITY   (Japan)

^b Massachusetts Institute of Technology   (United States)

^c TOHOKU UNIVERSITY   (Japan)

^d JAPAN SYNCHROTRON RADIATION RESEARCH INSTITUTE   (Japan)

^e OAK RIDGE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COBALT COMPOUNDS; ELECTRONIC STRUCTURE; OXYGEN; SOLID OXIDE FUEL CELLS (SOFC); STRONTIUM; X RAY ABSORPTION SPECTROSCOPY;

AMBIENT OXYGEN; DEPTH RESOLUTION; DEPTH-RESOLVED; HIGH TEMPERATURE; OXYGEN EXCHANGE KINETICS; PRACTICAL OPERATING CONDITIONS; SURFACE REGION; X-RAY ADSORPTION;

SURFACE SEGREGATION;

EID: 84903197192     PISSN: 21628726     EISSN: 21628734     Source Type: Journal    
DOI: 10.1149/2.006404eel     Document Type: Article

References (45)

1. S. B. Adler, Chem. Rev., 104, 4791 (2004).
2. C.-s. Chen, S.-j. Feng, S. Ran, D.-c. Zhu,W. Liu, and H. J. M. Bouwmeester, Angew. Chem. Int. Ed., 42, 5196 (2003).
3. V. Neburchilov, H. Wang, J. J. Martin, and W. Qu, J. Power Sources, 195, 1271 (2010).
4. Y. Teraoka, T. Nobunaga, K. Okamoto, N.Miura, and N. Yamazoe, Solid State Ionics, 48, 207 (1991).
5. J. Suntivich, H. A. Gasteiger, N. Yabuuchi, H. Nakanishi, J. B. Goodenough, and Y. Shao-Horn, Nature Chem., 3, 546 (2011).
6. T. Kawada, J. Suzuki, M. Sase, A. Kaimai, K. Yashiro, Y. Nigara, J. Mizusaki, K. Kawamura, and H. Yugami, J. Electrochem. Soc., 149, E252 (2002).
7. L. M. van der Haar, M. W. den Otter, M. Morskate, H. J. M. Bouwmeester, and H. Verweij, J. Electrochem. Soc., 149, J41 (2002).
8. S. P. Simner, M. D. Anderson, M. H. Engelhard, and J. W. Stevenson, Electrochem. Solid-State Lett., 9, A478 (2006).
9. Y. Chen, W. Jung, Z. H. Cai, J. J. Kim, H. L. Tuller, and B. Yildiz, Energ. Environ. Sci., 5, 7979 (2012).
10. W. Jung and H. L. Tuller, Energ. Environ. Sci., 5, 5370 (2012).
11. D. Oh, D. Gostovic, and E. D. Wachsman, J. Mater. Res., 27, 1992 (2012).
12. S. Li, W. Jin, P. Huang, N. Xu, J. Shi, and Y. S. Lin, J. Membr. Sci., 166, 51 (2000).
13. H. Yokokawa, H. Tu, B. Iwanschitz, and A. Mai, J. Power Sources, 182, 400 (2008).
14. M. Finsterbusch, A. Lussier, J. A. Schaefer, and Y. U. Idzerda, Solid State Ionics, 212, 77 (2012).
15. A. K. Huber, M. Falk,M. Rohnke, B. Luerssen, L. Gregoratti,M. Amati, and J. Janek, Phys. Chem. Chem. Phys., 14, 751 (2012).
16. A. E. Becerra-Toledo and L. D. Marks, Surf. Sci., 604, 1476 (2010).
17. H. Ding, A. V. Virkar, M. Liu, and F. Liu, Phys. Chem. Chem. Phys., 15, 489 (2013).
18. G. J. la O, R. F. Savinell, and Y. Shao-Horn, J. Electrochem. Soc., 156, B771 (2009).
19. Y. Orikasa, T. Ina, T.Nakao,A.Mineshige,K.Amezawa,M. Oishi,H.Arai, Z. Ogumi, and Y. Uchimoto, J. Phys. Chem. C, 115, 16433 (2011).
20. M. Imamura, N. Matsubayashi, and H. Shimada, J. Phys. Chem. B, 104, 7348 (2000).
21. B. Luerssen, E. Mutoro, H. Fischer, S. Gunther, R. Imbihl, and J. Janek, Angew. Chem. Int. Ed., 45, 1473 (2006).
22. C. Zhang, M. E. Grass, A. H. McDaniel, S. C. DeCaluwe, F. El Gabaly, Z. Liu, K. F. McCarty, R. L. Farrow, M. A. Linne, Z. Hussain, G. S. Jackson, H. Bluhm, and B. W. Eichhorn, Nature Mater., 9, 944 (2010).
23. E. J. Crumlin, E.Mutoro, Z. Liu,M. E. Grass, M. D. Biegalski, Y. L. Lee, D. Morgan, H. M. Christen, H. Bluhm, and Y. Shao-Horn, Energ. Environ. Sci., 5, 6081 (2012).
24. E. Mutoro, E. J. Crumlin, H. Popke, B. Luerssen, M. Amati, M. K. Abyaneh, M. D. Biegalski, H. M. Christen, L. Gregoratti, J. Janek, and Y. Shao-Horn, J. Phys. Chem. Lett., 3, 40 (2012).
25. T. Okumura, T. Nakatsutsumi, T. Ina, Y. Orikasa, H. Arai, T. Fukutsuka, Y. Iriyama, T. Uruga, H. Tanida, Y. Uchimoto, and Z. Ogumi, J. Mater. Chem., 21, 10051 (2011).
26. D. Takamatsu, T.Nakatsutsumi, S. Mori,Y.Orikasa,M.Mogi,H.Yamashige,K. Sato, T. Fujimoto, Y. Takanashi, H. Murayama, M. Oishi, H. Tanida, T. Uruga, H. Arai, Y. Uchimoto, and Z. Ogumi, J. Phys. Chem. Lett., 2, 2511 (2011).
27. G. J. la O', S. J. Ahn, E. Crumlin, Y. Orikasa, M. D. Biegalski, H. M. Christen, and Y. Shao-Horn, Angew. Chem. Int. Ed., 49, 5344 (2010).
28. Z. X. Feng, E. J. Crumlin,W. T. Hong, D. Lee, E. Mutoro, M. D. Biegalski, H. Zhou, H. Bluhm, H. M. Christen, and Y. Shao-Horn, J. Phys. Chem. Lett., 4, 1512 (2013).
29. E. J. Crumlin, S. J. Ahn, D. Lee, E. Mutoro, M. D. Biegalski, H. M. Christen, and Y. Shao-Horn, J. Electrochem. Soc., 159, F219 (2012).
30. E. J. Crumlin, E. Mutoro, S. J. Ahn, G. J. la O', D. N. Leonard, A. Borisevich, M. D. Biegalski, H. M. Christen, and Y. Shao-Horn, J. Phys. Chem. Lett., 1, 3149 (2010).
31. T. Noma, H. Miyata, and S. Ino, Jpn. J. Appl. Phys., Part 2, 31, L900 (1992).
32. M. H. R. Lankhorst, H. J. M. Bouwmeester, and H. Verweij, J. Solid State Chem., 133, 555 (1997).
33. J. Mizusaki, Y. Mima, S. Yamauchi, K. Fueki, and H. Tagawa, J. Solid State Chem., 80, 102 (1989).
34. R. Le Toquin, W. Paulus, A. Cousson, C. Prestipino, and C. Lamberti, J. Am. Chem. Soc., 128, 13161 (2006).
35. R. Bertacco, J. P. Contour, A. Barthélemy, and J. Olivier, Surf. Sci., 511, 366 (2002).
36. P. A. W. van der Heide, Surf Interface Anal, 33, 414 (2002).
37. M. Kubicek, A. Limbeck, T. Frömling, H. Hutter, and J. Fleig, J. Electrochem. Soc., 158, B727 (2011).
38. Y.-L. Lee, J. Kleis, J. Rossmeisl, and D. Morgan, Phys. Rev. B: Condens. Matter, 80, 224101 (2009).
39. L. M. van der Haar, M. W. den Otter, M. Morskate, H. J. M. Bouwmeester, and H. Verweij, J. Electrochem. Soc., 149, J41 (2002).
40. J. Zhao, J. Sunarso,W. Zhou, Z. P. Shao, R. Ran, and S. M. Liu, J. Electrochem. Soc., 158, H299 (2011).
41. E. Bucher and W. Sitte, Solid State Ionics, 192, 480 (2011).
42. E. Bucher, W. Sitte, F. Klauser, and E. Bertel, Solid State Ionics, 208, 43 (2012).
43. Z. Cai, M. Kubicek, J. Fleig, and B. Yildiz, Chem. Mater., 24, 1116 (2012).
44. E. Mutoro, E. J. Crumlin,M. D. Biegalski, H. M. Christen, and Y. Shao-Horn, Energ. Environ. Sci., 4, 3689 (2011).
45. M. Kubicek, A. Limbeck, T. Froemling, H. Hutter, and J. Fleig, J. Electrochem. Soc., 158, B727 (2011).