메뉴 건너뛰기




Volumn 5, Issue 7, 2014, Pages 2831-2835

Oxygen nucleophiles as reaction partners in photoinduced, copper-catalyzed cross-couplings: O-arylations of phenols at room temperature

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CHEMICAL COMPOUNDS; COUPLINGS; FUNCTIONAL GROUPS; NUCLEOPHILES; OXYGEN; PHENOLS;

EID: 84901857548     PISSN: 20416520     EISSN: 20416539     Source Type: Journal    
DOI: 10.1039/c4sc00368c     Document Type: Article
Times cited : (92)

References (29)
  • 15
    • 54749111583 scopus 로고    scopus 로고
    • For early studies, see
    • A. W. Thomas Sci. Synth. 2007 31a 469 543
    • (2007) Sci. Synth. , vol.31 , pp. 469-543
    • Thomas, A.W.1
  • 22
    • 0030700314 scopus 로고    scopus 로고
    • We are aware of only three reports of copper-catalyzed cross-couplings of phenols with aryl halides that proceed at room temperature
    • J.-F. Marcoux S. Doye S. L. Buchwald J. Am. Chem. Soc. 1997 119 10539 10540
    • (1997) J. Am. Chem. Soc. , vol.119 , pp. 10539-10540
    • Marcoux, J.-F.1    Doye, S.2    Buchwald, S.L.3
  • 24
    • 84874115728 scopus 로고    scopus 로고
    • See also ref. 3d For a recent example of a photoinduced C-O bond-forming process that is not metal-catalyzed, see
    • S. G. Babu R. Karvembu Tetrahedron Lett. 2013 54 1677 1680.
    • (2013) Tetrahedron Lett. , vol.54 , pp. 1677-1680
    • Babu, S.G.1    Karvembu, R.2
  • 25
    • 84899083601 scopus 로고    scopus 로고
    • 2 is reduced to Cu(i) Under the standard conditions: The concentration of the aryl iodide is 0.15 M. Use of a higher concentration (0.5 M) led to a decreased yield, whereas a lower concentration (0.05 M) provided a somewhat higher yield (88%; three times the amount of solvent) A small amount of unreacted phenol is often observed No product resulting from arylation of the aliphatic alcohol was detected See footnote 15 in
    • Z. Xiao S. Cai Y. Shi B. Yang S. Gao Chem. Commun. 2014 50 5254 5257
    • (2014) Chem. Commun. , vol.50 , pp. 5254-5257
    • Xiao, Z.1    Cai, S.2    Shi, Y.3    Yang, B.4    Gao, S.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.