Amorphous supramolecular structure of carboxymethyl cellulose in aqueous solution at different pH values as determined by rheology, small angle X-ray and light scattering

Carbohydrate Polymers

Volumn 111, Issue , 2014, Pages 492-504

  Dogsa, Iztok ^a   Tomšič, Matija ^a   Orehek, Janez ^b   Benigar, Elizabeta ^a   Jamnik, Andrej ^a   Stopar, David ^a  

^a UNIVERSITY OF LJUBLJANA   (Slovenia)

^b Faculty of Chemistry and Chemical Technology University of Ljubljana Department of Physical Chemistry ^*  (Slovenia)

Author keywords

Carboxymethyl Cellulose; CMC; DLS; Macromolecular structure; SAXS; String of beads model; Supramolecular structure

Indexed keywords

CELLULOSE; DYNAMIC LIGHT SCATTERING; MACROMOLECULES; PH; VISCOSITY MEASUREMENT;

CARBOXY-METHYL CELLULOSE; CMC; DLS; MACROMOLECULAR STRUCTURES; SAXS; SUPRAMOLECULAR STRUCTURE;

RELAXATION PROCESSES;

CARBOXYMETHYLCELLULOSE; WATER;

CHEMISTRY; FLOW KINETICS; LIGHT; PH; RADIATION SCATTERING; SMALL ANGLE SCATTERING; X RAY DIFFRACTION;

CARBOXYMETHYLCELLULOSE SODIUM; HYDROGEN-ION CONCENTRATION; LIGHT; RHEOLOGY; SCATTERING, RADIATION; SCATTERING, SMALL ANGLE; WATER; X-RAY DIFFRACTION;

EID: 84901846797     PISSN: 01448617     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.carbpol.2014.04.020     Document Type: Article

References (63)

1. A.M. Adel, H. Abou-Youssef, A.A. El-Gendy, and A.M. Nada Carboxymethylated cellulose hydrogel. Sorption behavior and characterization Nature and Science 8 2010 244 256
2. A. Benchabane, and K. Bekkour Rheological properties of carboxymethyl cellulose (CMC) solutions Colloidid and Polymer Science 286 2008 1173 1180
3. B.J. Berne, and R. Pecora Dynamic light scattering with applications to chemistry, biology, and physics 2000 Dover Publications New York
4. W. Brown, and K. Mortensen Scattering in polymeric and colloidal systems 2000 Overseas Publishers Association Amsterdam
5. A. Burakowski, and J. Glinski Hydration numbers of nonelectrolytes from acoustic methods Chemical Reviews 112 2012 2059 2081
6. A. Burakowski, and J. Glinski Hydratation numbers of non-elecrolytes in aqueus solvents of fixed pH Interntional Journal of Termophysics 31 2010 16 25
7. C. Clasen, J.P. Plog, W.-M. Kulicke, M. Owens, C. Macosko, and L.E. Scriven et al. How dilute are dilute solutions in extensional flows? Journal of Rheology 50 2006 849 881 (Pubitemid 44724862)
8. J.H. Cummings, and A.M. Stephen Water-holding by dietary fibre in vitro and its relationship to faecal output in man Gut 20 1979 722 729 (Pubitemid 9253504)
9. T. Coviello, H. Maeda, Y. Yuguchi, H. Urakawa, K. Kajiwara, and M. Dentini et al. Conformational characteristics of oxidized sclerogluca Macromolecules 31 1998 1602 1607
10. S. Dayan, P. Maissa, M.J. Vellutini, and P. Sixou Intrinsic viscosity of cellulose derivatives and the persistent cylinder model of Yamakawa Polymer 23 1982 800 804 (Pubitemid 12518761)
11. P. de Gennes Scaling concepts in polymer physics 1979 Cornell University Press New York
12. P. Debye Zerstreuung von röntgenstrahlen. Scattering from non-crystalline substances Annalen der Physik 46 1915 809 823
13. I. Dogsa, M. Kriechbaum, D. Stopar, and P. Laggner Structure of bacterial extracellular polymeric substances at different pH values as determined by SAXS Biophysical Journal 89 2005 2711 2720 (Pubitemid 41401061)
14. I. Dogsa, J. Štrancar, P. Laggner, and D. Stopar Efficient modeling of polysaccharide conformations based on small-angle X-ray scattering experimental data Polymer 49 2008 1398 1406
15. J. Doutch, M. Bason, F. Franceschini, K. James, D. Clowes, and E.P. Gilbert Structural changes during starch pasting using simultaneous Rapid Visco Analysis and small-angle neutron scattering Carbohydrate Polymers 88 2012 1061 1071
16. J. Doutch, and E.P. Gilbert Characterisation of large scale structures in starch granules via small-angle neutron and X-ray scattering Carbohydrate Polymers 91 2013 444 451
17. K.I. Draget, B.T. Stokke, Y. Yuguchi, H. Urakawa, and K. Kajiwara Small-angle X-ray scattering and rheological characterization of alginate gels. 3. Alginic acid gels Biomacromolecules 4 2003 1661 1668 (Pubitemid 37455578)
18. M.O. Emeje, O.O. Kunle, and S.I. Ofoefule Effect of the molecular size of carboxymethylcellulose and some polymers on the sustained release of theophylline from a hydrophilic matrix Acta Pharmaceutica 56 2006 325 335 (Pubitemid 44422512)
19. E. Geissler, A.M. Hecht, F. Horkay, and M. Zrinyi Compressional modulus of swollen polyacrylamide networks Macromolecules 21 1988 2594 2599
20. E. Geissler, F. Horkay, A.M. Hecht, C. Rochas, P. Linder, and C. Bourgaux et al. Investigation of PDMS gels and solutions by small angle scatterin Polymer 38 1997 15 20 (Pubitemid 127428473)
21. Glinski, J., Burakowski, A. (2013). Modification of the Pasynski Method for determining the hydration numbers of nonelectrolytes. Chemical Physics Letters, 566, 21-24.
22. A.M. Hecht, F. Horkay, S. Mallam, and E. Geissler Scattering properties of polymer gels at the theta temperatur Macromolecules 25 1992 6915 6920 (Pubitemid 23606318)
23. A.M. Hecht, F. Horkay, and E. Geissler Neutron scattering investigations on bimodal polymer gels Journal of Physical Chemistry 105 2001 5637 5642 (Pubitemid 35339129)
24. I. Hoffmann, P. Heunemann, S. Prévost, R. Schweins, N.J. Wagner, and M. Gradzielski Self-aggregation of mixtures of oppositely charged polyelectrolytes and surfactants studied by rheology, dynamic light scattering and small-angle neutron scattering Langmuir 27 2011 4386 4396
25. C.W. Hoogendam, A. de Keizer, M.A. Cohen Stuart, B.H. Bijsterbosch, J.A.M. Smit, and J.A.P.P. van Dijk et al. Persistence length of carboxymethyl cellulose as evaluated from size exclusion chromatography and potentiometric titrations Macromolecules 31 1998 6297 6309 (Pubitemid 128563409)
26. F. Horkay, A.M. Hecht, M. Zrínyi, and E. Geissler Effect of cross-links on the structure of polymer gels Polymer Gels and Networks 4 1996 451 465 (Pubitemid 126412531)
27. F. Horkay, G.B. McKenna, P. Deschamps, and E. Geissler Neutron scattering properties of randomly cross-linked polyisoprene gels Macromolecules 33 2000 5215 5220
28. E. Josef, and H. Bianco-Peled Conformation of a natural polyelectrolyte in semidilute solutions with no added salt Soft Matter 8 2012 9156 9165
29. U. Kästner, H. Hoffmann, R. Dönges, and J. Hilbig Structure and solution properties of sodium carboxymethyl cellulose Colloids and Surfaces A: Physicochemical and Engineering Aspects 123 1997 307 328 (Pubitemid 27292722)
30. K. Kajiwara, and T. Miyamoto Progress in structural characterization of functional polysaccharides S. Dumitriu, Polysaccharides: Structural diversity and functional versatility 2005 Marcel Dekker New York 1 40
31. King, K. W., Smibert, R. M. (1963). Distinctive properties of beta-glucosidases and related enzymes derived from a commercial Aspergillus niger cellulose. Applied Microbiology, 11, 315-319.
32. A. Kjøniksen, S. Nilsson, K. Thuresson, B. Lindman, and B. Nyström Effect of surfactant on dynamic and viscoelastic properties of aqueous solutions of hydrophobically modified ethyl(hydroxyethyl) cellulose, with and without spacer Macromolecules 33 2000 877 886 (Pubitemid 30563078)
33. A. Kjøniksen, L. Nyström, and B.B. Lindman Effects of temperature, surfactant concentration, and salinity of the dynamics of dilute solutions of a nonionic cellulose derivative Langmuir 14 1998 5039 5045
34. O. Kratky, and H. Stabinger X-ray small-angle camera with block-collimation system an instrument of colloid research Colloid and Polymer Science 262 1984 345 360 (Pubitemid 14603812)
35. W.M. Kulicke, A.H. Kull, W. Kull, H. Thielking, J. Engelhart, and J.B. Pannek Characterization of aqueous carboxymethylcellulose solutions in terms of their molecular structure and its influence on rheological behavior Polymer 37 1996 2723 2731
36. C.N. Likos, M. Schmidt, H. Lwen, M. Ballauff, D. Ptschke, and P. Lindner Soft interaction between dissolved flexible dendrimers: Theory and experiment Macromolecules 34 2001 2914 2920 (Pubitemid 34216998)
37. C.N. Likos, S. Rosenfeldt, N. Dingenouts, M. Ballauff, P. Lindner, and N. Werner et al. Gaussian effective interaction between flexible dendrimers of fourth generation: A theoretical and experimental study Chemical Physics 117 2002 1869 1877 (Pubitemid 34923934)
38. T. Matsumoto, and H. Zenkoh A new molecular model for complexation between carboxymethylcellulose and alkaline - Earth metal ions in aqueous systems Food Hydrocolloids 6 1992 379 386
39. M. Moan, and C. Wolff Study of the conformational rigidity of polyelectrolytes by elastic neutron scattering: 1. Carboxymethylcelluloses in the intermediate momentum range Polymer 16 1975 776 780
40. A. Munter Scattering length density calculator 2003 National Institute of Standards and Technology, Center for Neutron Research Gaithersburg, MD http://www.ncnr.nist.gov/resources/sldcalc.html (accessed 01.02.12)
41. Y. Muroga, Y. Yamada, I. Noda, and M. Nagasawa Local conformation of polysaccharides in solution investigated by small-angle X-ray scattering Macromolecules 20 1987 3003 3006
42. K.L. Ngai, A.K. Rajagopal, and T.P. Lodge Star polymer diffusion in concentrated-solutions - Dependence on functionality via the coupling model Journal of Polymer Science Part B: Polymer Physics 28 1990 1367 1377 (Pubitemid 20707192)
43. K.L. Ngai, A.K. Rajagopal, R.W. Rendell, and S. Teitler Models of Kohlrausch relaxations IEEE Transactions on Electrical Insulation 21 1986 313 318
44. K.L. Ngai, A.K. Rajagopal, and S. Teitler Slowing down of relaxation in a complex system by constraint dynamics Journal of Chemical Physics 88 1988 5086 5094
45. N. Ninan, M. Muthiah, I. Park, A. Elain, S. Thomas, and Y. Grohens Pectin/carboxymethyl cellulose/microfibrillated cellulose composite scaffolds for tissue engineering Carbohydrate Polymers 98 2013 877 885
46. B. Nyström, A. Kjøniksen, and C. Iversen Characterization of association phenomena in aqueous systems of chitosan of different hydrophobicity Advances in Colloid and Interface Science 79 1999 81 103 (Pubitemid 128634237)
47. J. Orehek, I. Dogsa, M. Tomšič, A. Jamnik, D. Kočar, and D. Stopar Structural investigation of carboxymethyl cellulose biodeterioration by Bacillus subtilis subsp. subtilis NCIB 3610 International Biodeterioration Biodegradation 77 2013 10 17
48. D. Orthaber, A. Bergmann, and O. Glatter SAXS experiments on absolute scale with Kratky systems using water as a secondary standard Journal of Appied Crystallography 33 2000 218 225 (Pubitemid 32142126)
49. A.K. Rajagopal, K.L. Ngai, and S. Teitler Theoretical aspects of coupling model schemes of slow relaxation in complex correlated systems Journal of Non-Crystalline Solids 131-133 1991 282 288 (Pubitemid 21677921)
50. P. Roblin, G. Potocki-Véronèse, D. Guieysse, F. Guerin, M.A.V. Axelos, and J. Perez et al. SAXS Conformational tracking of amylose synthesized by amylosucrase Biomacromolecules 14 2013 232 239
51. L. Schäfer, and K. Elsner Calculation of the persistence length of a flexible polymer chain with short-range self-repulsion European Physical Journal E 13 2004 225 237 (Pubitemid 40877401)
52. L. Schulz, W. Burchard, and R. Dönges Evidence of supramolecular structures of cellulose derivatives in solution T.J. Heinze, W. Glasser, Cellulose derivatives modifications. Characterization, and nanostructures, ACS. Symp. Ser 688 1998 American Chemical Society Washington, DC 218 238 (Pubitemid 128436565)
53. J. Schurz Molekulare Uneinheitlichkeit und Lösungsinhomogenitat als Kernngrössen von Spinnmassen Lenzinger Berichte 55 1983 12 17
54. J. Sharma, and H.B. Bohidar Gelatin-glutaraldehyde supramolecular structures studied by laser lightscattering Eurpean Polymer Journal 36 2000 1409 1418
55. M. Shakun, H. Maier, T. Heinze, P. Kilz, and W. Radke Molar mass characterization of sodium carboxymethyl cellulose by SEC-MALLS Carbohydrate Polymers 95 2013 550 559
56. M. Shakun, T. Heinze, and W. Radke Determination of the DS distribution of non-degraded sodium carboxymethyl cellulose by gradient chromatography Carbohydrate Polymers 98 2013 943 950
57. N.J. Turro Supramolecular structure and dynamics special feature: Supramolecular structure and dynamics Proceedings of the National Academy of Sciences of the United States of America 102 2005 10765
58. C. Wandrey, A. Bartowiak, and S.E. Harding Materials for encapsulation N.J. Zuidam, V. Nedović, Encapsulation Technologies for active food ingredients and food processing 2009 Springer New York 31 95
59. S. Wang, J. Blazek, E. Gilbert, and L. Copeland New insights on the mechanism of acid degradation of pea starch Carbohydrate Polymers 87 2012 1941 1949
60. H. Yamakawa, and M. Fujii Intrinsic viscosity of wormlike chains. Determination of the shift factor Macromolecules 7 1974 128 135
61. Y. Yuguchi Nano-structure analysis of sugar chains by small angle X-ray scattering Trends in Glycoscience and Glycotechnology 21 2009 1 12
62. Y. Yuguchi, H. Urakawa, and K. Kajiwara The effect of potassium salt on the structural characterization of gellan gum gel Food Hydrocolloids 16 2002 191 195 (Pubitemid 34168733)
63. B.H. Zimm The scattering of light and the radial distribution function of high polymer solutions Journal of Chemical Physics 16 1948 1093 1099