Nano-scale simultaneous observation of Li-concentration profile and Ti-, O electronic structure changes in an all-solid-state Li-ion battery by spatially-resolved electron energy-loss spectroscopy

Journal of Power Sources

Volumn 266, Issue , 2014, Pages 414-421

  Yamamoto, Kazuo ^a   Yoshida, Ryuji ^a   Sato, Takeshi ^a   Matsumoto, Hiroaki ^b   Kurobe, Hisanori ^a   Hamanaka, Tadashi ^a   Kato, Takehisa ^c   Iriyama, Yasutoshi ^c   Hirayama, Tsukasa ^a  

^a JAPAN FINE CERAMICS CENTER   (Japan)

^b HITACHI HIGH TECHNOLOGIES CORPORATION   (Japan)

^c NAGOYA UNIVERSITY   (Japan)

Author keywords

Chemical reaction; Electron energy loss spectroscopy; In situ formed electrode; Li distribution; Li ion battery

Indexed keywords

CHEMICAL REACTIONS; ELECTRODES; ELECTRON ENERGY LOSS SPECTROSCOPY; ELECTRON SCATTERING; ELECTRONIC STRUCTURE; GERMANIUM; LITHIUM; SOLID ELECTROLYTES; TITANIUM; TRANSMISSION ELECTRON MICROSCOPY;

AMORPHOUS PHASE; FORMATION MECHANISM; HIGH ENERGY DENSITIES; INTERFACIAL RESISTANCES; LI DISTRIBUTIONS; LI-ION BATTERIES; NANO-METER-SCALE; SIMULTANEOUS OBSERVATION;

LITHIUM BATTERIES;

EID: 84901761042     PISSN: 03787753     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jpowsour.2014.04.154     Document Type: Article

References (29)

1. M. Armand, and J.-M. Tarascon Nature 451 2008 652 657
2. J.B. Bates, N.J. Dudney, B. Neudecker, A. Ueda, and C.D. Evans Solid State Ionics 135 2000 33 45
3. B.J. Neudecker, N.J. Dudney, and J.B. Bates J. Electrochem. Soc. 147 2000 517 523
4. Y. Iriyama, T. Kako, C. Yada, T. Abe, and Z. Ogumi Solid State Ionics 176 2005 2371 2376
5. N. Ohta, K. Takada, L. Zhang, R. Ma, M. Osada, and T. Sasaki Adv. Mater. 18 2006 2226 2229
6. A. Sakuda, A. Hayashi, and M. Tatsumisago Chem. Mater. 22 2010 949 956
7. P. Birke, S. Scharner, R.A. Huggins, and W. Weppner J. Electrochem. Soc. 144 1997 L167 L169
8. Y. Iriyama, C. Yada, T. Abe, Z. Ogumi, and K. Kikuchi Electrochem. Commun. 8 2006 1287 1291
9. C. Yada, Y. Iriyama, T. Abe, K. Kikuchi, and Z. Ogumi Electrochem. Commun. 11 2009 413 416
10. J. Fu J. Am. Ceram. Soc. 80 1997 1901 1903
11. K. Yamamoto, Y. Iriyama, T. Asaka, T. Hirayama, H. Fujita, K. Nonaka, K. Miyahara, Y. Sugita, and Z. Ogumi Electrochem. Commun. 20 2012 113 116
12. K. Yamamoto, Y. Iriyama, T. Asaka, T. Hirayama, H. Fujita, C.A.J. Fisher, K. Nonaka, Y. Sugita, and Z. Ogumi Angew. Chem. Int. Ed. 49 2010 4414 4417
13. K. Yamamoto, T. Hirayama, and T. Tanji Microscopy 62 Suppl.1 2013 S29 S41
14. K. Kimoto, T. Sekiguchi, and T. Aoyama J. Electron Microsc. 46 1997 369 374
15. S. Terada, T. Aoyama, F. Yano, and Y. Mitsui J. Electron. Microsc. 51 2002 291 296
16. W. Ra, M. Nakayama, Y. Uchimoto, and M. Wakihara J. Phys. Chem. B 109 2005 1130 1134
17. M. Nakayama, T. Usui, Y. Uchimoto, M. Wakihara, and M. Yamamoto J. Phys. Chem. B 109 2005 4135 4143
18. http://www.ohara-inc.co.jp/jp/product/electronics/licgc.html
19. J.N. Reimers, and J.R. Dahn J. Electrochem. Soc. 139 1992 2091 2097
20. R.F. Egerton Electron Energy-Loss Spectroscopy in the Electron Microscope second ed. 1996 Plenum Press New York and London 269 277
21. C. Delmas, A. Nadiri, and J.L. Soubeyroux Solid State Ionics 28-30 1988 419 423
22. A. Aatiq, M. Menetrier, L. Croguennec, E. Suard, and C. Delmas J. Mater. Chem. 12 2002 2971 2978
23. A. Ohtomo, D.A. Muller, J.L. Grazul, and H.Y. Hwang Nature 419 2002 378 380
24. C.C. Calvert, W.M. Rainforth, D.C. Sinclair, and A.R. West Micron 37 2006 412 419
25. E. Stoyanov, F. Langenhorst, and G. Steinle-Neumann Am. Mineral. 92 2007 577 586
26. H. Kurata, E. Lefevre, C. Colliex, and R. Brydson Phys. Rev. B 47 1993 13763 13768
27. A. Bianconi, E. Fritsch, G. Calas, and J. Petiau Phys. Rev. B 32 1985 4292 4295
28. Y. Murakami, D. Shindo, M. Kikuchi, J.-M. Zuo, and J.C.H. Spence J. Electron. Microsc. 51 2002 99 103
29. K. Momma, and F. Izumi J. Appl. Crystallogr. 44 2011 1272 1276