EELS characterisation of bulk CaCu3Ti4O12 ceramics

Micron

Volumn 37, Issue 5, 2006, Pages 412-419

  Calvert, Clair C ^a   Rainforth, W Mark ^a   Sinclair, Derek C ^a   West, Anthony R ^a  

^a UNIVERSITY OF SHEFFIELD   (United Kingdom)

Author keywords

CaCu3Ti4O12; EDS; EELS; Permittivity

Indexed keywords

CALCIUM COMPOUNDS; ELECTRON ENERGY LOSS SPECTROSCOPY; GRAIN SIZE AND SHAPE; MICROSTRUCTURE; NANOSTRUCTURED MATERIALS; PERMITTIVITY; PEROVSKITE; X RAY SPECTROSCOPY;

CACU3TI4O12; CUBIC PEROVSKITE PHA; ENERGY DISPERSIVE X-RAY SPECTROMETRY (EDS); NEAR-EDGE STRUCTURE (NES);

CERAMIC MATERIALS;

EID: 33746884667     PISSN: 09684328     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.micron.2005.12.007     Document Type: Article

References (31)

1. 12 ceramics. Physical Review B.
2. 3 based microwave dielectrics. Journal of the European Ceramics Society 23 (2003) 2435-2441
3. 12. Journal of Solid State Chemistry 29 (1979) 291-298
4. 12. Journal of Physics: Condensed Matter 16 44 (2004) S5091-S5102
5. Brydson R., Sauer H., Engel W., Thomas J.M., Zeitler E., Kosugi N., and Kuroda H. Electron energy-loss and X-ray absorption spectroscopy of rutile and anatase: a test of structural sensitivity. Journal of Physics: Condensed Matter 1 (1989) 797-812
6. Brydson R., Sauer H., and Engel W. Electron energy loss near-edge structure as an analytical tool- the study of minerals. In: Disko M.M., Ahn C.C., and Fultz B. (Eds). Transmission Electron Energy Loss Spectroscopy in Materials Science (1992), The Minerals, Metals and Materials Society, Warrendale, IL 131-153
7. Brydson R., Sauer H., Engel W., and Hofer F. Electron energy-loss near-edge structures at the oxygen K edges of titanium (IV) oxygen compounds. Journal of Physics: Condensed Matter 4 (1992) 3429-3437
8. Burns R.G. Mineralogical applications of crystal field theory. Cambridge Topics in Mineral Physics and Chemistry. second ed. vol. 5 (1993), Cambridge University Press, London 551 pp
9. Calvert C.C., Brown A.P., and Brydson R. Determination of the local chemistry of iron in inorganic and organic materials. Journal of Electron Spectroscopy and Related Phenomenon 143 (2005) 173-187
10. de Groot F.M.F. X-ray-absorption and dichroism of transition-metals and their compounds. Journal of Electron Spectroscopy and Related Phenomenon 67 4 (1994) 529-622
11. de Groot F.M.F., Grioni M., Fuggle J.C., Ghijsen J., Sawatzky G.A., and Peterson H. Oxygen 1s X-ray-absorption edges of transition-metal oxides. Physical Review B 40 8 (1989) 5715-5723
12. de Groot F.M.F., Faber J., Michiels J.J.M., Czyzyk M.T., Abbate M., and Fuggle J.C. Oxygen 1s X-ray absorption of tetravalent titanium oxides: a comparison with single-particle calculations. Physical Review B 48 4 (1993) 2074-2080
13. Egerton R.F. Electron Energy-Loss Spectroscopy in the Electron Microscope. second ed. (1996), Plenum Press, New York 485 pp
14. Glazer A.M. The classification of tilted octahedra in perovskites. Acta Crystallographica B28 (1972) 3384-3392
15. 3 X-ray-absorption spectroscopy. Physical Review B 39 3 (1989) 1541-1545
16. 3. Ultramicroscopy 78 (1999) 221-231
17. Höche T., Olhe P., Keding R., Rüssel C., van Aken P., Schneider R., Kleebe H.-J., Wang X., Jacobson A.J., and Stemmer S. Synthesis and characterisation of mixed-valence barium titanates. Philosophical Magazine 83 2 (2003) 165-178
18. Homes C.C., Vogt T., Shapiro S.M., Wakimoto S., and Ramirez A.P. Optical response of high dielectric-constant perovskite related oxide. Science 293 (2001) 673-676
19. 12. Solid State Commumications 121 (2002) 625-629
20. 12 studied by magnetic Raman spectroscopy. Physical Reviews B 65 (2002) 0524061-0524064
21. Kurata H., Lefèvre E., Colliex C., and Brydson R. Electron energy-loss near-edge structures in the oxygen K-edge spectra of transition-metal oxides. Physical Review B 47 20 (1993) 13763-13768
22. 3 by TEM and EELS. Acta Materialia 50 (2002) 2151-2162
23. 2(001). Surface Science 397 (1998) 237-250
24. 12. Journal of Physics: Condensed Matter 15 (2003) 7365-7374
25. 2 (100) surfaces. Physical Reviews B 30 (1984) 2202-2211
26. 3, X=0 to 0.33. Journal of Solid State Chemistry 178 (2005) 1008-1016
27. 12: one-step internal barrier layer capacitor. Applied Physics Letters 80 12 (2002) 2153-2155
28. 12 phases. Journal of Solid State Chemistry 151 (2000) 323-325
29. 3. Philosophical Magazine Letters 75 1 (1997) 21-27
30. van der Laan G., Pattrick R.A.D., Henderson C.M.B., and Vaughan D.J. Oxidation state variations in copper minerals studied with Cu 2p X-ray absorption spectroscopy. Journal of Physics and Chemistry of Solids 53 9 (1992) 1185-1190
31. Walls, M.G., Tencé, M., 1990. EELS study of beam-induced decomposition of calcite in the STEM. Electron Microscopy and Analysis Group 1989, vol. 98, Institute of Physics Conference Series, pp. 225-258.