Characterization of adsorbates by transient measurements in Scanning Electrochemical Microscopy

Electrochimica Acta

Volumn 131, Issue , 2014, Pages 28-35

  Trinh, Dao ^a,b,d   Keddam, Michel ^a,b   Nóvoa, Xosé Ramón ^c   Vivier, Vincent ^a,b  

^a UMR 8235)   (France)

^b SORBONNE UNIVERSITÉ   (France)

^c UNIVERSITY OF VIGO   (Spain)

^d UNIVERSITÉ DE LA ROCHELLE   (France)

Author keywords

AC SECM; Adsorbate intermediate; Competitive adsorption; Electrochemical impedance spectroscopy; Scanning Electrochemical Microscopy

Indexed keywords

ADSORBATES; ADSORPTION; DISSOLUTION; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; IRON COMPOUNDS; SCANNING ELECTRON MICROSCOPY;

AC-SECM; COMPETITIVE ADSORPTION; DIFFERENTIAL CAPACITANCE; DISSOLUTION MECHANISM; ELECTROCHEMICAL IMPEDANCE; SCANNING ELECTROCHEMICAL MICROSCOPY; SIMULTANEOUS MEASUREMENT; TRANSIENT MEASUREMENT;

SCANNING PROBE MICROSCOPY;

EID: 84901188936     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2014.02.002     Document Type: Article

References (46)

1. M. Keddam, O.R. Mattos, and H. Takenouti Reaction model for iron dissolution studied by electrode impedance. II. Determination of the reaction model J. Electrochem. Soc. 128 1981 266 274
2. M. Keddam, O.R. Mattos, and H. Takenouti Reaction model for iron dissolution studied by electrode impedance. I. Experimental results and reaction model J. Electrochem. Soc. 128 1981 257 266
3. I. Epelboin, C. Gabrielli, M. Keddam, and H. Takenouti Model of the anodic behavior of iron in sulfuric acid medium Electrochim. Acta 20 1975 913 916
4. C. Cachet, F. Ganne, G. Maurin, J. Petitjean, V. Vivier, and R. Wiart EIS investigation of zinc dissolution in aerated sulfate medium. Part I: bulk zinc Electrochim. Acta 47 2001 509 518
5. C. Cachet, F. Ganne, S. Joiret, G. Maurin, J. Petitjean, V. Vivier, and R. Wiart EIS investigation of zinc dissolution in aerated sulphate medium. Part II: zinc coatings Electrochim. Acta 47 2002 3409 3422
6. C. Gabrielli, M. Keddam, N. Nadi, and H. Perrot a.c. Electrogravimetry on conducting polymers. Application to polyaniline Electrochim. Acta 44 1999 2095 2103
7. J. Agrisuelas, C., Gabrielli, J.J. García-Jareño, H., Perrot, F., Vicente, Kinetic and Mechanistic Aspects of a Poly(o-Toluidine)- Modified Gold Electrode. 2. Alternating Current Electrogravimetry Study in H2SO4 Solutions, J. Phys. Chem. C, 116 (2012) 15630-15640.
8. T.K.L. To, C. Debiemme-Chouvy, C. Gabrielli, and H. Perrot Redox Switching of Heteropolyanions Entrapped in Polypyrrole Films Investigated by ac Electrogravimetry Langmuir 28 2012 13746 13757
9. R. Antano-Lopez, M. Keddam, and H. Takenouti A new experimental approach to the time-constants of electrochemical impedance: frequency response of the double layer capacitance Electrochim. Acta 46 2001 3611 3617
10. R. Antano-Lopez, M. Keddam, and H. Takenouti Interface capacitance at mercury and iron electrodes in the presence of organic compound, Corros. Eng Sci. Technol. 39 2004 59 64
11. E.R. Larios-Duran, R. Antano-Lopez, M. Keddam, Y. Meas, H. Takenouti, and V. Vivier Dynamics of double-layer by AC Modulation of the Interfacial Capacitance and Associated Transfer Functions Electrochim. Acta 55 2010 6292 6298
12. W.J. Albery, and S. Bruckenstein Ring-disk electrodes. VII. Homogeneous and heterogeneous kinetics Trans. Faraday Soc. 62 1966 2596 2606
13. W.J. Albery, and S. Bruckenstein Ring-disk electrodes. V. First-order kinetic collection efficiencies at the ring electrode Trans. Faraday Soc. 62 1966 1946 1954
14. W.J. Albery, and S. Bruckenstein Ring-disk electrodes. II. Theoretical and experimental collection efficiencies Trans. Faraday Soc. 62 1966 1920 1931
15. S. Bruckenstein, K. Tokuda, and W.J. Albery Ring-disk electrodes. Part 17. Ring response to periodic disk electrode forcing functions, J. Chem. Soc Farad. T. 1 73 1977 823 829
16. W.J. Albery, R.G. Compton, and A.R. Hillman Ring-disk electrodes. Part 18. Collection efficiency for high frequency a.c, J. Chem. Soc Farad. T. 1 74 1978 1007 1019
17. W.J. Albery, and A.R. Hillman Ring-disk electrodes. Part 19. Adsorption studies at low frequency a.c, J. Chem. Soc Farad. T. 1 75 1979 1623 1634
18. N. Benzekri, M. Keddam, and H. Takenouti The a.c. response of a rotating ring-disk electrode: application to 2-D and 3-D film formation in anodic processes Electrochim. Acta 34 1989 1159 1166
19. N. Benzekri, R. Carranza, M. Keddam, and H. Takenouti The a.c. response of RRDE during the passivation of iron Corros. Sci. 31 1990 627 635
20. M. Itagaki, M. Tagaki, and K. Watanabe Active dissolution mechanisms of iron using EIS with channel flow double electrode. Influences of chloride and fluoride ions Electrochim. Acta 41 1996 1201 1207
21. G. Wittstock, M. Burchardt, S.E. Pust, Y. Shen, and C. Zhao Scanning electrochemical microscopy for direct imaging of reaction rates Angew. Chem. Int. Ed. 46 2007 1584 1617
22. S. Amemiya, A.J. Bard, F.R.F. Fan, M.V. Mirkin, and P.R. Unwin Scanning Electrochemical Microscopy, in: Annual Review of Analytical Chemistry vol. 1 2008 95 131
23. M.B. Jensen, and D.E. Tallman Application of SECM to corrosion studies Electroanal. Chem. 24 2012 171 286
24. N. Casillas, S.J. Charlebois, W.H. Smyrl, and H.S. White Scanning electrochemical microscopy of precursor sites for pitting corrosion on titanium J. Electrochem. Soc. 140 1993 L142 L145
25. N. Casillas, S. Charlebois, W.H. Smyrl, and H.S. White Pitting Corrosion of Titanium J. Electrochem. Soc. 141 1994 636 642
26. M.B. Jensen, A. Guerard, D.E. Tallman, and G.P. Bierwagen Studies of electron transfer at aluminum alloy surfaces by scanning electrochemical microscopy J. Electrochem. Soc. 155 2008 C324 C332
27. C. Gabrielli, S. Joiret, M. Keddam, H. Perrot, N. Portail, P. Rousseau, and V. Vivier Development of a Coupled SECM-EQCM Technique for the Study of Pitting Corrosion on Iron J. Electrochem. Soc. 153 2006 B68 B74
28. C. Gabrielli, S. Joiret, M. Keddam, H. Perrot, N. Portail, P. Rousseau, and V. Vivier A. SECM assisted EQCM study of iron pitting Electrochim. Acta 52 2007 7706 7714
29. C. Gabrielli, S. Joiret, M. Keddam, N. Portail, P. Rousseau, and V. Vivier Single pit on iron generated by SECM Electrochim. Acta 53 2008 7539 7548
30. J. Rodriguez-Lopez, M.A. Alpuche-Aviles, and A.J. Bard Interrogation of Surfaces for the Quantification of Adsorbed Species on Electrodes: Oxygen on Gold and Platinum in Neutral Media J. Am. Chem. Soc. 130 2008 16985 16995
31. Q. Wang, J. Rodriguez-Lopez, and A.J. Bard Reaction of Br2 with Adsorbed CO on Pt, Studied by the Surface Interrogation Mode of Scanning Electrochemical Microscopy J. Am. Chem. Soc. 131 2009 17046 17047
32. J. Rodriguez-Lopez, A. Minguzzi, and A.J. Bard Reaction of various reductants with oxide films on Pt electrodes as studied by the surface interrogation mode of scanning electrochemical microscopy (SI-SECM): Possible validity of a Marcus relationship J. Phys. Chem. C 114 2010 18645 18655
33. D. Trinh, M. Keddam, X.R. Novoa, and V. Vivier Alternating-Current Measurements in Scanning Electrochemical Microscopy, Part 1: Principle and Theory ChemPhysChem 12 2011 2169 2176
34. D. Trinh, M. Keddam, X.R. Novoa, and V. Vivier Alternating Current Measurements in Scanning Electrochemical Microscopy, Part 2: Detection of Adsorbates ChemPhysChem 12 2011 2177 2183
35. N. Garcia-Araez, V. Climent, E. Herrero, and J.M. Feliu On the electrochemical behavior of the Pt(100) vicinal surfaces in bromide solutions Surf. Sci. 560 2004 269 284
36. N. Garcia-Araez, V. Climent, E. Herrero, J. Feliu, and J. Lipkowski Thermodynamic studies of chloride adsorption at the Pt(111) electrode surface from 0.1 M HClO4 Solution J. Electroanal. Chem. 576 2005 33 41
37. N. Garcia-Araez, J.J. Lukkien, M.T.M. Koper, and J.M. Feliu Competitive adsorption of hydrogen and bromide on Pt(100): Mean-field approximation vs. Monte Carlo simulations J. Electroanal. Chem. 588 2006 1 14
38. C. Gabrielli, E. Ostermann, H. Perrot, V. Vivier, L. Beitone, and C. Mace Concentration mapping around copper microelectrodes studied by scanning electrochemical microscopy Electrochem. Commun. 7 2005 962 968
39. C. Gabrielli, M. Keddam, N. Portail, P. Rousseau, H. Takenouti, and V. Vivier Electrochemical Impedance Spectroscopy Investigations of a Microelectrode Behavior in a Thin-Layer Cell: Experimental and Theoretical Studies J. Phys. Chem. B 110 2006 20478 20485
40. C. Gabrielli, M. Keddam, and H. Takenouti Potential distribution at the surface of a ring-disk electrode J. Chim. Phys. PCB 69 1972 737 740
41. S. Ferro, and A. De Battisti The Bromine Electrode. Part I: Adsorption Phenomena at Polycrystalline Platinum Electrodes J. Appl. Electrochem. 34 2004 981 987
42. G.N. Salaita, D.A. Stern, F. Lu, H. Baltruschat, B.C. Schardt, J.L. Stickney, M.P. Soriaga, D.G. Frank, and A.T. Hubbard Structure and composition of a Platinum(111) surface as a function of pH and electrode potential in aqueous bromide solutions Langmuir 2 1986 828 835
43. S. Ferro, C. Orsan, and A. De Battisti The bromine electrode Part II: reaction kinetics at polycrystalline Pt J. Appl. Electrochem. 35 2005 273 278
44. M. Keddam, and H. Takenouti Mechanism of anodic dissolution of iron in acid solution CR Acad. Sci. II C 270 1970 283 286
45. J.O.M. Bockris, D. Drazic, and A.R. Despic The electrode kinetics of the deposition and dissolution of iron Electrochim. Acta 4 1961 325 361
46. K.E. Heusler Der Einfluß der Wasserstof fionenkonzentration auf das elektrochemische Verhalten des aktiven Eisens in sauren Lösungen Z. Elektrochem. 62 1958 582 587