Enhanced olivine carbonation within a basalt as compared to single-phase experiments: Reevaluating the potential of CO2 mineral sequestration

Environmental Science and Technology

Volumn 48, Issue 10, 2014, Pages 5512-5519

  Sissmann, Olivier ^a,b,c   Brunet, Fabrice ^d   Martinez, Isabelle ^a   Guyot, François ^e   Verlaguet, Anne ^f,h   Pinquier, Yves ^b   Daval, Damien ^g  

^a INSTITUT DE PHYSIQUE DU GLOBE DE PARIS   (France)

^b ECOLE NORMALE SUPÉRIEURE   (France)

^c IFP ENERGIES NOUVELLES   (France)

^d UMR 7327   (France)

^e UNIVERSITÉ PIERRE ET MARIE CURIE   (France)

^f SORBONNE UNIVERSITÉ   (France)

^g UNIVERSITÉ DE STRASBOURG   (France)

^h CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

BASALT; CARBON DIOXIDE; CARBONATION; EXPERIMENTAL MINERALOGY; EXPERIMENTS; MAGNESIA; MAGNESITE;

BASALTIC ROCKS; BATCH EXPERIMENTS; CLINOPYROXENES; LABORATORY DATUM; MINERAL SEQUESTRATION; SAN CARLOS OLIVINES; TEXTURAL PROPERTIES; THOLEIITIC BASALTS;

OLIVINE;

CALCIUM CARBONATE; CALCIUM ION; CARBON DIOXIDE; CARBONIC ACID; FACTOR A; IRON; MAGNESIUM ION; MAGNETITE; OLIVINE; SILICON DIOXIDE; TITANIUM; UNCLASSIFIED DRUG; WATER;

BASALT; CARBON DIOXIDE; CARBON SEQUESTRATION; GRAIN SIZE; LABORATORY METHOD; OLIVINE; REACTION KINETICS;

ARTICLE; BASALT; CARBON SEQUESTRATION; CHEMICAL ANALYSIS; CHEMICAL COMPOSITION; CHEMICAL REACTION; DISSOLUTION; ELECTRON MICROSCOPY; EVALUATION RESEARCH; GRAIN; KINETICS; MINERAL METABOLISM;

ALUMINUM; ALUMINUM SILICATES; CARBON DIOXIDE; CARBONATES; IRON COMPOUNDS; MAGNESIUM COMPOUNDS; MICROSCOPY, ELECTRON, SCANNING; MINERALS; POROSITY; SILICATES; SILICON; SOLUTIONS; THERMODYNAMICS; X-RAY DIFFRACTION;

EID: 84901008907     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es405508a     Document Type: Article

References (39)

1. Dessert, C.; Dupré, B.; Gaillardet, J.; François, L. M.; Allègre, C. J. Basalt weathering laws and the impact of basalt weathering on the global carbon cycle Chem. Geol. 2003, 202, 257-273
2. McGrail, B. P.; Schaef, H. T.; Ho, A. M.; Chien, Y.-J.; Dooley, J. J.; Davidson, C. L. Potential for carbon dioxide sequestration in flood basalts J. Geophys. Res.: Solid Earth 2006, 111 B12201
3. 2 storage Proc. Natl. Acad. Sci. U.S.A. 2008, 105, 17295-17300
4. Gislason, S. R.; Wolff-Boenisch, D.; Stefansson, A.; Oelkers, E. H.; Gunnlaugsson, E.; Sigurdardottir, H.; Sigfusson, B.; Broecker, W. S.; Matter, J. M.; Stute, M.; Axelsson, G.; Fridriksson, T. Mineral sequestration of carbon dioxide in basalt: A pre-injection overview of the CarbFix project Int. J. Greenhouse Gas Control 2010, 4, 537-545
5. Schaef, H. T.; McGrail, B. P. Dissolution of Columbia River basalt under mildly acidic conditions as a function of temperature: Experimental results relevant to the geological sequestration of carbon dioxide Appl. Geochem. 2009, 24, 980-987
6. Alfredsson, H. A.; Oelkers, E. H.; Hardarsson, B. S.; Franzson, H.; Gunnlaugsson, E.; Gislason, S. R. The geology and water chemistry of the Hellisheidi, SW-Iceland carbon storage site Int. J. Greenhouse Gas Control 2013, 12, 399-418
7. 2 geological storage: The environmental mineralogy perspective C. R. Geosci. 2011, 343, 246-259
8. 2 sequestration by olivine: Potential, quantification Appl. Geochem. 2010, 25, 1383-1396
9. Bearat, H.; McKelvy, M. J.; Chizmeshya, A. V. G.; Gormley, D.; Nunez, R.; Carpenter, R. W.; Squires, K.; Wolf, G. H. Carbon sequestration via aqueous olivine mineral carbonation: Role of passivating layer formation Environ. Sci. Technol. 2006, 40, 4802-4808
10. 2 Chem. Geol. 2011, 284, 193-209
11. 2 pressure Environ. Sci. Technol. 2013, 47, 168-173
12. Saldi, G. D.; Daval, D.; Morvan, G.; Knauss, K. G. The role of Fe and redox conditions in olivine carbonation rates: An experimental study of the rate limiting reactions at 90 and 150 °C in open and closed systems Geochim. Cosmochim. Acta 2013, 118, 157-183
13. 2 in geological media: Criteria and approach for site selection in response to climate change Energy Convers. Manage. 2000, 41, 953-970
14. Gerdemann, S. J.; OConnor, W. K.; Dahlin, D. C.; Penner, L. R.; Rush, H. Ex situ aqueous mineral carbonation Environ. Sci. Technol. 2007, 41, 2587-2593
15. Gudbrandsson, S.; Wolff-Boenisch, D.; Gislason, S. R.; Oelkers, E. H. An experimental study of crystalline basalt dissolution from 2 < pH < 11 and temperatures from 5 to 75 °C Geochim. Cosmochim. Acta 2011, 75, 5496-5509
16. 2 Chem. Geol. 2013, 351, 245-256
17. McCrea, J. M. On the isotopic chemistry of carbonates and a paleotemperature scale J. Chem. Phys. 1950, 18, 849-857
18. Barnes, C. S.; Koretsky, M. D. ThermoSolver Software; John Wiley and Sons: Hoboken, NJ, 2004, (accompanies the textbook Engineering and Chemical Thermodynamics, 2nd ed., by M. D. Koretsky).
19. van der Lee, J.; De Windt, L. CHESS Tutorial and Cookbook, Updated for Version 3.0; Manual no. LHM/RD/02/13; Ecole des Mines de Paris: Fontainebleau, France, 2002; p 116.
20. Wolery, T. J.; Daveler, S. A. EQ6, a Computer Program for Reaction Path Modeling of Aqueous Geochemical Systems: Theoretical Manual, Users Guide, and Related Documentation, version 7.0; Lawrence Livermore National Laboratory: Livermore, CA, 1992; p 349.
21. 2-water system Am. Mineral. 2010, 95, 853-862
22. Oelkers, E. H.; Schott, J. Experimental study of anorthite dissolution and the relative mechanism of feldspar hydrolysis Geochim. Cosmochim. Acta 1995, 59, 5039-5053
23. Stillings, L. L.; Brantley, S. L. Feldspar dissolution at 25 °C and pH 3: Reaction stoichiometry and the effect of cations Geochim. Cosmochim. Acta 1995, 59, 1483-1496
24. Rosenbauer, R. J.; Thomas, B.; Bischoff, J. L.; Palandri, J. Carbon sequestration via reaction with basaltic rocks: Geochemical modeling and experimental results Geochim. Cosmochim. Acta 2012, 89, 116-133
25. Sissmann, O.; Daval, D.; Brunet, F.; Guyot, F.; Verlaguet, A.; Pinquier, Y.; Findling, N.; Martinez, I. The deleterious effect of secondary phases on olivine carbonation yield: Insight from time-resolved aqueous-fluid sampling and FIB-TEM characterization Chem. Geol. 2013, 357, 186-202
26. Saldi, G. D.; Schott, J.; Pokrovsky, O. S.; Gautier, Q.; Oelkers, E. H. An experimental study of magnesite precipitation rates at neutral to alkaline conditions and 100-200 °C as a function of pH, aqueous solution composition and chemical affinity Geochim. Cosmochim. Acta 2012, 83, 93-109
27. 2-rich brine through peridotites Environ. Sci. Technol. 2009, 43, 1226-1231
28. Johnson, N. C.; Thomas, B.; Maher, K.; Rosenbauer, R. J.; Bird, D.; Brown, G. E., Jr. Olivine dissolution and carbonation under conditions relevant for in situ carbon storage Chem. Geol. 2014, 373, 93-105
29. Andreani, M.; Daniel, I.; Pollet-Villard, M. Aluminum speeds up the hydrothermal alteration of olivine Am. Mineral. 2013, 98, 1738-1744
30. King, H. E.; Plumper, O.; Geisler, T.; Putnis, A. Experimental investigations into the silicification of olivine: Implications for the reaction mechanism and acid neutralization Am. Mineral. 2011, 96, 1503-1511
31. Hellmann, R.; Wirth, R.; Daval, D.; Barnes, J.-P.; Penisson, J.-M.; Tisserand, D.; Epicier, T.; Florin, B.; Hervig, R. L. Unifying natural and laboratory chemical weathering with interfacial dissolution-reprecipitation: A study based on the nanometer-scale chemistry of fluid-silicate interfaces Chem. Geol. 2012, 294-295, 203-216
32. King, H. E.; Plumper, O.; Putnis, A. Effect of secondary phase formation on the carbonation of olivine Environ. Sci. Technol. 2010, 44, 6503-6509
33. Morris, P. M.; Wogelius, R. A. Phthalic acid complexation and the dissolution of forsteritic glass studied via in situ FTIR and X-ray scattering Geochim. Cosmochim. Acta 2008, 72, 1970-1985
34. Cailleteau, C.; Angeli, F.; Devreux, F.; Gin, S.; Jestin, J.; Jollivet, P.; Spalla, O. Insight into silicate-glass corrosion mechanisms Nat. Mater. 2008, 7, 978-983
35. Jollivet, P.; Gin, S.; Schumacher, S. Forward dissolution rate of silicate glasses of nuclear interest in clay-equilibrated groundwater Chem. Geol. 2012, 330-331, 207-217
36. Wogelius, R. A.; Walther, J. V. Olivine dissolution kinetics at near-surface conditions Chem. Geol. 1992, 97, 101-112
37. 2, and organic acids Geochim. Cosmochim. Acta 1991, 55, 943-954
38. 2 Geochim. Cosmochim. Acta 2006, 70, 4403-4416
39. Rosso, J. J.; Rimstidt, D. J. A high resolution study of forsterite dissolution rates Geochim. Cosmochim. Acta 2000, 64, 797-811