In situ carbonation of peridotite for CO2 storage

Proceedings of the National Academy of Sciences of the United States of America

Volumn 105, Issue 45, 2008, Pages 17295-17300

  Kelemen, Peter B ^a   Matter, Jürg ^a  

^a Lamont Doherty Earth Observatory of Columbia University   (United States)

Author keywords

Alteration and weathering; Carbon capture; Carbon sequestration; Exothermic; Mineral

Indexed keywords

CARBON DIOXIDE; CARBONIC ACID; MINERAL;

AIR TEMPERATURE; ARTICLE; CHEMICAL REACTION; DRILL; ENERGY EXPENDITURE; HEATING; HIGH TEMPERATURE; HYDRATION; HYDRAULIC CONDUCTIVITY; LOW TEMPERATURE; PRIORITY JOURNAL; STORAGE TEMPERATURE;

EID: 56249090410     PISSN: 00278424     EISSN: 10916490     Source Type: Journal    
DOI: 10.1073/pnas.0805794105     Document Type: Article

References (37)

1. Metz B, Davidson O, de Coninck H, Loos M, Meyer L, eds (2005) IPCC Special Report on Carbon Dioxide Capture and Storage (Cambridge Univ Press, New York), p 431.
2. Seifritz W (1990) CO2 disposal by means of silicates. Nature 345:486.
3. Lackner KS, Wendt CH, Butt DP, Joyce EL, Sharp DH (1995) Carbon dioxide disposal in carbonate minerals. Energy 20:1153-1170.
4. Lackner KS, Butt DP, Wendt CH (1997) Progress on binding CO2 in mineral substrates. Energy Convers Manage 38:S259-S264.
5. Mazzotti M, et al. (2005) Mineral carbonation and industrial uses of CO2. IPCC Special Report on Carbon Dioxide Capture and Storage, eds Metz B, Davidson O, de Coninck H, Loos M, Meyer L (Cambridge Univ Press, Cambridge, UK), pp 319-338.
6. Solomon S, et al. (2007) Technical summary. Climate Change 2007: The Physical Science Basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change, eds Solomon S, et al. (Cambridge Univ Press, Cambridge, UK), pp 20-91.
7. Nicolas A, Boudier E, Ildefonse B, Ball E (2000) Accretion of Oman and United Arab Emirates ophiolite: Discussion of a new structural map. Marine Geophys Res 21(3-4):147-179.
8. Fyfe WS (1974) Heats of chemical reactions and submarine heat production. Geophys J Roy Astr Soc 37(1):213-215.
9. Kelley DS, et al. (2001) An off-axis hydrothermal vent field near the Mid-Atlantic Ridge at 30 degrees N. Nature 412(6843):145-149.
10. Emmanuel S, Berkowitz B (2006) Suppression and stimulation of seafloor hydrothermal convection by exothermic mineral hydration. Earth Planet Sci Lett 243(3-4):657-668.
11. Allen DE, Seyfried WE (2004) Serpentinization and heat generation: Constraints from Lost City and Rainbow hydrothermal systems. Geochim Cosmochim Acta 68(6):1347-1354.
12. Zedef V, Russell MJ, Fallick AE, Hall AJ (2000) Genesis of vein stockwork and sedimentary magnesite and hydromagnesite deposits in the ultramafic terranes of southwestern Turkey: A stable isotope study. Econ Geol 95(2):429-445.
13. Wenner DB, Taylor HPJ (1974) D/H and 18O/16O studies of serpentinization of ultramafic rocks. Geochim Cosmochim Acta 38:1255-1286.
14. Weyhenmeyer CE (2000) Origin and evolution of groundwater in the alluvial aquifer of the Eastern Batinah Coastal Plain, Sultanate of Oman. PhD thesis (Geologisches Institut, Universität Bern), 202 pp.
15. Neal C, Stanger G (1985) Past and present serpentinization of ultramafic rocks: An example from the Semail ophiolite nappe of northern Oman. The Chemistry of Weathering, ed Drewer JI (D. Reidel Publishing Company, Dordrecht, Holland), pp 249-275.
16. Cipolli F, Gambardella B, Marini L, Ottonello G, Zuccolini MV (2004) Geochemistry of high-pH waters from serpentinites of the Gruppo di Voltri (Genova, Italy) and reaction path modeling of CO2 sequestration in serpentinite aquifers. Appl Geochem 19(5):787-802.
17. Bruni J, et al. (2002) Irreversible water-rock mass transfer accompanying the generation of the neutral, Mg-HCO3 and high-pH, Ca-OH spring waters of the Genova province, Italy. Appl Geochem 17(4):455-474.
18. Barnes I, O'Neil JR (1969) Relationship between fluids in some fresh alpine-type ultramafics and possible modern serpentinization, western United States. GSA Bull 80(10):1947-1960.
19. Barnes I, LaMarche VC, Himmelberg G (1967) Geochemical evidence of present-day serpentinization. Science 156(3776):830-832.
20. Hansen LD, Dipple GM, Gordon TM, Kellett DA (2005) Carbonated serpentinite (listwanite) at Atlin, British Columbia: A geological analogue to carbon dioxide sequestration. Can Mineral 43:225-239.
21. Nasir S, et al. (2007) Mineralogical and geochemical characterization of listwaenite from the Semail ophiolite, Oman. Chemie Der Erde 67:213-228.
22. Wilde A, Simpson L, Hanna S (2002) Preliminary study of Cenozoic alteration and platinum deposition in the Oman ophiolite. J Virtual Explorer 6:7-13.
23. Früh-Green G, Weissert H, Bernoulli D (1990) A multiple fluid history recorded in Alpine ophiolites. J Geol Soc London 147:959-970.
24. Trommsdorff V, Evans B, Pfeifer HR (1980) Ophicarbonate rocks: Metamorphic reactions and possible origin. Arch Sci Genève 33:3610364.
25. Naldrett AJ (1966) Talc-carbonate alteration of some serpentinized ultramafic rocks south of Timmins, Ontario. J Petrol 7:489-499.
26. Stanger G (1985) Silicified serpentinite in the Semail nappe of Oman. Lithos 18(1):13-22.
27. Python M, Ceuleneer G, Ishida Y, Barrat J-A, Arai S (2007) Oman diopsidites: A new lithology diagnostic of very high temperature circulation in mantle peridotite below oceanic spreading centers. Earth Planet Sci Lett 255:289-305.
28. Clark ID, Fontes JC (1990) Paleoclimatic reconstruction in northern Oman based on carbonates from hyperalkaline groundwaters. Quat Res 33(3):320-336.
29. Poupeau G, Saddiqi O, Michard A, Goffé B, Oberhänsli R (1998) Late thermal evolution of the Oman Mountains subophiolitic windows: Apatite fission-track thermochronology. Geology 26:1139-1142.
30. Valkó P, Economides MJ (1995) Hydraulic Fracture Mechanics (Wiley, Chichester), p 298.
31. Fredrich JT, Wong TF (1986) Micromechanics of thermally induced cracking in 3 crustal rocks. J Geophys Res 91:2743-2764.
32. Jamtveit B, Malthe-Sorenssen A, Kostenko O (2008) Reaction enhanced permeability during retrogressive metamorphism. Earth Planet Sci Lett 267:620-627.
33. Iyer K, Jamtveit B, Mathiesen J, Malthe-Sorenssen A, Feder J (2008) Reaction-assisted hierarchical fracturing during serpentinization. Earth Planet Sci Lett 267:503-516.
34. Fletcher RC, Buss HL, Brantley SL (2006) A spheroidal weathering model coupling porewater chemistry to soil thickness during steady-state denudation. Earth Planet Sci Lett 244:444-457.
35. Martin B, Fyfe WS (1970) Some experimental and theoretical observations on kinetics of hydration reactions with particular reference to serpentinization. Chem Geol 6(3):185-202.
36. Gottschalk M (1997) Internally consistent thermodynamic data for rock-forming minerals in the system SiO2-TiO2-Al2O3-Fe2O3-CaO-MgO-FeO-K2O-Na2O- H2O-CO2. Eur J Mineral 9:175-223.
37. Blackwell DD (1971) The thermal structure of the continental crust. The Structure and Physical Properties of the Earth's Crust, Geophysical Monograph 14, ed Heacock JG (American Geophysical Union, Washington, DC), pp 169-184.