The role of Fe and redox conditions in olivine carbonation rates: An experimental study of the rate limiting reactions at 90 and 150°C in open and closed systems

Geochimica et Cosmochimica Acta

Volumn 118, Issue , 2013, Pages 157-183

  Saldi, Giuseppe D ^a   Daval, Damien ^a,b   Morvan, Gilles ^b   Knauss, Kevin G ^a  

^a LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^b EOST LHYGES   (France)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS SOLUTION; DISSOLUTION; EXPERIMENTAL MINERALOGY; FORSTERITE; IRON; OLIVINE; REACTION KINETICS; REACTION RATE; REDOX CONDITIONS;

EID: 84879345517     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.gca.2013.04.029     Document Type: Article

References (118)

1. Abu-Jaber N., Kimberley M. Origin of ultramafic-hosted vein magnesite deposits. Ore Geol. Rev. 1992, 7:155-191.
2. 2-rich brine through peridotites. Environ. Sci. Technol. 2009, 43:1226-1231.
3. Barnes C.S. ThermoSolver: an integrated educational thermodynamics software program. H.B. Thesis Abstr. 2006, 46p.
4. Barnes C.S., Koretsky M.D. In Engineering and Chemical Thermodynamics 2004, John Wiley and Sons, 553p.
5. Béarat H., McKelvy M., Chizmeshya A., Gormley D., Nunez R., Carpenter R., Squires K., Wolf G. Carbon sequestration via aqueous olivine mineral carbonation: role of passivating layer formation. Environ. Sci. Technol. 2006, 40:4802-4808.
6. Bénézeth P., Saldi G.D., Dandurand J.-L., Schott J. Experimental determination of the solubility product of magnesite at 50 to 200°C. Chem. Geol. 2011, 286:21-31.
7. Blum A., Lasaga A. Role of surface speciation in the low-temperature dissolution of minerals. Nature 1988, 331:431-433.
8. 2-mineral sequestration by cyclic hydraulic fracturing and Si-rich fluid infiltration into serpentinites at Malentrata (Tuscany, Italy). Chem. Geol. 2009, 265:209-226.
9. Brunauer S., Emmett P., Teller E. Adsorption of gases in multimolecular layers. J. Am. Chem. Soc. 1938, 60:309-319.
10. Carlson L., Schwertmann U. Natural ferrihydrites in surface deposits from Finland and their association with silica. Geochim. Cosmochim. Acta 1981, 45:421-429.
11. Case D.H., Wang F., Giammar D.E. Precipitation of magnesium carbonates as a function of temperature, solution composition, and presence of a silicate mineral substrate. Environ. Eng. Sci. 2011, 28:881-889.
12. Chen Y., Brantley S.L. Dissolution of forsteritic olivine at 65°C and 2
13. 2 sequestration in serpentinite aquifers. Appl. Geochem. 2004, 19:787-802.
14. 2/Si(111). Surf. Interface Anal. 2007, 39:711-714.
15. Daval D., Hellmann R., Saldi G.D., Wirth R., Knauss K.G. Linking nm-scale measurements of the anisotropy of silicate surface reactivity to macroscopic dissolution rate laws: new insights based on diopside. Geochim. Cosmochim. Acta 2013, 107:121-134.
16. Daval D., Martinez I., Corvisier J., Findling N., Goffé B., Guyot F. Carbonation of Ca-bearing silicates, the case of wollastonite: experimental investigations and kinetic modeling. Chem. Geol. 2009, 265:63-78.
17. 4) dissolution kinetics determined by X-ray absorption spectroscopy. Chem. Geol. 2010, 275:161-175.
18. 2. Chem. Geol. 2011, 284:193-209.
19. Davis C.C., Chen H.-W., Edwards M. Modeling silica sorption to iron hydroxide. Environ. Sci. Technol. 2002, 36:582-587.
20. Davis C.C., Knocke W.M., Edwards M. Implications of aqueous silica sorption to iron hydroxide: mobilization of iron colloids and interference with sorption of arsenate and humic substances. Environ. Sci. Technol. 2001, 35:3158-3162.
21. 25Mg CP QCPMG NMR. Phys. Chem. Chem. Phys. 2009, 11:7013-7021.
22. Davison W., Seed G. The kinetics of the oxidation of ferrous iron in synthetic and natural-waters. Geochim. Cosmochim. Acta 1983, 47:67-79.
23. Decarreau A., Bonnin D., Badaut-Trauth D., Couty R., Kaiser P. Synthesis and crystallogenesis of ferric smectite by evolution of Si-Fe coprecipitates in oxidizing conditions. Clay Mineral. 1987, 22:207-223.
24. Deelman J. C. (2003) Note on magnesite formation (studies on irreversible geochemical reactions 9). Carnets de Géologie/Notebooks on Geology, Maintenon, Letter 2003/03.
25. 29Si solid-state NMR. Lagmuir 2001, 17:1399-1405.
26. Dubrawski J.V., Channon A.-L. Examination of the siderite-magnesite mineral series by Fourier infrared spectroscopy. Am. Mineral. 1989, 74:187-190.
27. Dufaud F., Martinez I., Shilobreeva S. Experimental study of Mg-rich silicates carbonation at 400 and 500°C and 1kbar. Chem. Geol. 2009, 265:79-87.
28. 2 metasomatism during regional metamorphism of the ultrabasic rocks of the Ochser serpentinite (Zillertaler Alpen, Tyrol, Austria). Monograph series on Mineral Deposits 1989, No. 28:95-104. Gebrüder Borntraeger, Berlin-Stuttgart.
29. Duro L., El Aamrani F., Rovira M., Giménez J., Casas I., de Pablo J., Bruno J. The dissolution of high-FeO olivine rock from the Lovasjärvi intrusion (SE-Finland) at 25°C as a function of pH. Appl. Geochem. 2005, 20:1284-1291.
30. 2 with forsterite: evidence for magnesite formation at low temperatures. Geochim. Cosmochim. Acta 2012, 91:271-282.
31. Fenter P., Sturchio N.C. Mineral-water interfacial structures revealed by synchrotron X-ray scattering. Prog. Surf. Sci. 2004, 77:171-258.
32. 4) solid solutions from aqueous solutions. J. Cryst. Growth 1999, 200:227-235.
33. 4 (forsterite). J. Cryst. Growth 1971, 8:307-308.
34. 2 sequestration by olivine: potential, quantification. Appl. Geochem. 2010, 25:1383-1396.
35. Gerdemann S., O'Connor W., Dahlin D., Penner L., Rush H. Ex situ aqueous mineral carbonation. Environ. Sci. Technol. 2007, 41:2587-2593.
36. Giammar D., Bruant R.G., Peters C.A. Forsterite dissolution and magnesite precipitation at conditions relevant for deep saline aquifer storage and sequestration of carbon dioxide. Chem. Geol. 2005, 217:257-276.
37. Gislason S., Wolff-Boenisch D., Stefánsson A. Mineral sequestration of carbon dioxide in basalt: a pre-injection overview of the CarbFix project. Int. J. Greenhouse Gas Control 2010, 5:537-545.
38. Grundl T., Delwiche J. Kinetics of ferric oxyhydroxide precipitation. J. Contam. Hydrol. 1993, 14:71-87.
39. Guy C., Schott J. Multisite surface reaction versus transport control during the hydrolysis of a complex oxide. Chem. Geol. 1989, 78:181-204.
40. 2 geological storage: the environmental mineralogy perspective. CR Geosci. 2011, 343:246-259.
41. 2. Chem. Geol. 2012, 306-307:146-159.
42. 2 pressure. Chem. Eng. Sci. 2008, 63:1012-1028.
43. Hänchen M., Prigiobbe V., Storti G., Seward T., Mazzotti M. Dissolution kinetics of fosteritic olivine at 90-150°C including effects of the presence of CO2. Geochim. Cosmochim. Acta 2006, 70:4403-4416.
44. Hansen L.D., Dipple G.M., Gordon T.M., Kellett D.A. Carbonated serpentinite (listwanite) at Atlin, British Columbia: a geological analogue to carbon dioxide sequestration. Can. Mineral. 2005, 43:225-239.
45. Hellmann R., Wirth R., Daval D., Barnes J.-P., Penisson J.-M., Tisserand D., Epicier T., Florin B., Hervig R.L. Unifying natural and laboratory chemical weathering with interfacial dissolution-reprecipitation: a study based on the nanometer-scale chemistry of fluid-silicate interfaces. Chem. Geol. 2012, 294-295:203-216.
46. Herzog H. (2002) Carbon Sequestration via Mineral Carbonation: Overview and Assessment. MIT Laboratory for Energy and the Environment, pp. 1-11.
47. Hövelmann J., Austrheim H., Beinlich A., Munz I.A. Experimental study of the carbonation of partially serpentinized and weathered peridotites. Geochim. Cosmochim. Acta 2011, 75:6760-6779.
48. Iler R.K. The Chemistry of Silica: Solubility, Polymerization, Colloid and Surface and Surface Properties, and Biochemistry 1979, John Wiley and Sons, 867p.
49. Jambor J.L., Dutrizac J.E. Occurrence and constitution of natural and synthetic ferrihydrite, a widespread iron oxyhydroxide. Chem. Rev. 1998, 98:2549-2586.
50. 2. Environ. Sci. Technol. 2009, 43:6314-6319.
51. 4 production in serpentinization systems at elevated P-Ts. Geophys. Res. Lett. 2010, 37:L14306.
52. 2 storage. Proc. Natl. Acad. Sci. U.S.A. 2008, 105:17295-17300.
53. King H.E., Plümper O., Putnis A. Effect of secondary phase formation on the carbonation of olivine. Environ. Sci. Technol. 2010, 44:6503-6509.
54. King H.E., Plümper O., Geisler T., Putnis A. Experimental investigations into the silicification of olivine: implications for the reaction mechanism and acid neutralization. Am. Mineral. 2011, 96:1503-1511.
55. Klein F., Garrido C.J. Thermodynamic constraints on mineral carbonation of serpentinized peridotite. Lithos 2011, 126:147-160.
56. Knauss K., Copenhaver S. The solubility of p-xylene in water as a function of temperature and pressure and calculated thermodynamic quantities. Geochim. Cosmochim. Acta 1995, 59:2443-2448.
57. Konhauser K.O., Ferris F.G. Diversity of iron and silica precipitation by microbial mats in hydrothermal waters, Iceland: implications for Precambrian iron formations. Geology 1996, 24:323-326.
58. Lackner K., Wendt C., Butt D., Joyce E., Sharp D.H. Carbon dioxide disposal in carbonate minerals. Energy 1995, 20:1153-1170.
59. Lincoln S.F., Merbach A.E. Substitution reactions of solvated metal cations. Advances in Inorganic Chemistry 1995, Vol. 42:1-88. Academic Press.
60. Lindahl I. and Nilsson L. P. (2008) Geology of the soapstone deposits of the Linnajavri area, Hamarøy, Nordland, north Norwegian Caledonides - Norway's largest reserves of soapstone. In Geology for Society (ed. T. Slagstad). Geological Survey of Norway Special Publication 11, 19-35.
61. Luce R., Bartlett R., Parks G. Dissolution kinetics of magnesium silicates. Geochim. Cosmochim. Acta 1972, 36:35-50.
62. 2 sequestration. Geochem. Geophys. Geosys. 2007, 8:Q02001.
63. McGrail B.P., Schaef H.T., Ho A.M., Chien Y.-J., Dooley J.J., Davidson C.L. Potential for carbon dioxide sequestration in flood basalts. J. Geophys. Res. 2006, 111:B12201.
64. IPCC Special Report on Carbon Dioxide Capture and Storage 2005, Cambridge University Press, New York, 431 pp. B. Metz, O. Davidson, H. de Coninck, M. Loos, L. Meyer (Eds.).
65. Millero F.J., Sotolongo S., Izaguirre M. The oxidation kinetics of Fe(II) in seawater. Geochim. Cosmochim. Acta 1987, 51:793-801.
66. Möller P. Magnesite: Geology, Mineralogy, Geochemistry, Formation of Mg-Carbonates. Monograph Series on Mineral Deposits 1989, No. 28. Gebrüder Borntraeger, Berlin-Stuttgart, pp. 300.
67. 2 in aqueous solution - basic principles and a simple heuristic description. Chemosphere 2007, 68:2080-2084.
68. Morris R.C., Fletcher A.B. Increased solubility of quartz following ferrous-ferric iron reactions. Nature 1987, 330:558-561.
69. Noguera C., Fritz B., Clement A., Amal Y. Simulation of the nucleation and growth of binary solid solutions in aqueous solutions. Chem. Geol. 2010, 269:89-99.
70. O'Connor W. K., Dahlin D. C., Nilsen D. N., Rush G. E., Walters R. P. and Turner P. C. (2000) CO2 storage in solid form: a study of direct mineral carbonation. In Fifth International Conference on Greenhouse Gas Control Technologies, Cairns, Australia, August 13-August 16, 2000.
71. Oelkers E.H. An experimental study of forsterite dissolution rates as a function of temperature and aqueous Mg and Si concentrations. Chem. Geol. 2001, 175:485-494.
72. 2 sequestration. Chem. Geol. 2005, 217:183-186.
73. 2. Elements 2008, 4:333-337.
74. Parkhurst D. L. and Appelo C. A. J. (1999) User's guide to PHREEQC (version 2) - a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations. US Geological Survey Water-resources Investigation Report 99-4259. 312 p.
75. Pham A.N., Rose A.L., Feitz A.J., Waite T.D. Kinetics of Fe(III) precipitation in aqueous solutions at pH 6.0-9.5 and 25°C. Geochim. Cosmochim. Acta 2006, 70:640-650.
76. Pokrovski G., Schott J., Farges F., Hazemann J. Iron (III)-silica interactions in aqueous solution: insights from X-ray absorption fine structure spectroscopy. Geochim. Cosmochim. Acta 2003, 67:3559-3573.
77. Pokrovsky O., Schott J. Kinetics and mechanism of forsterite dissolution at 25°C and pH from 1 to 12. Geochim. Cosmochim. Acta 2000, 64:3313-3325.
78. Pokrovsky O.S., Schott J. Surface chemistry and dissolution kinetics of divalent metal carbonates. Environ. Sci. Technol. 2002, 36:426-432.
79. Prieto M. Thermodynamics of solid solutions-aqueous solution systems. Rev. Mineral. Geochem. 2009, 70:47-85.
80. 3 solid solutions from aqueous solutions. Geochim. Cosmochim. Acta 1997, 61:3383-3397.
81. 2 and salinity on olivine dissolution kinetics at 120°C. Chem. Eng. Sci. 2009, 64:3510-3515.
82. 2. Chem. Geol. 2012, 332-333:124-135.
83. Reardon E. Complexing of silica by iron (III) in natural waters. Chem. Geol. 1979, 25:339-345.
84. Rimstidt J.D., Brantley S.L., Olsen A.A. Systematic review of forsterite dissolution rate data. Geochim. Cosmochim. Acta 2012, 99:159-178.
85. Roekens E.J., van Grieken R.E. Kinetics of iron (II) oxidation in seawater of various pH. Mar. Chem. 1983, 13:195-202.
86. 2 metasomatism in a basalt-hosted petroleum reservoir, Nuussuaq, West Greenland. Lithos 2006, 92:55-82.
87. Rose A.L., Waite T.D. Kinetic model of Fe(II) oxidation in seawater in the absence and presence of natural organic matter. Environ. Sci. Technol. 2002, 36:433-444.
88. Rosenbauer R.J., Thomas B., Bischoff J.L., Palandri J. Carbon sequestration via reaction with basaltic rocks: geochemical modeling and experimental results. Geochim. Cosmochim. Acta 2012, 89:116-133.
89. Rosso J., Rimstidt J. A high resolution study of forsterite dissolution rates. Geochim. Cosmochim. Acta 2000, 64:797-811.
90. Ruiz-Agudo E., Putnis C.V., Rodriguez-Navarro C., Putnis A. Mechanism of leached layer formation during chemical weathering of silicate minerals. Geology 2012, 40:947-950.
91. Saldi G.D., Jordan G., Schott J., Oelkers E. Magnesite growth rates as a function of temperature and saturation state. Geochim. Cosmochim. Acta 2009, 73:5646-5657.
92. Saldi G.D., Schott J., Pokrovsky O.S., Gautier Q., Oelkers E.H. An experimental study of magnesite precipitation rates at neutral to alkaline conditions and 100 to 200°C as a function of pH, aqueous solution composition and chemical affinity. Geochim. Cosmochim. Acta 2012, 83:93-109.
93. Santelli C.M., Welch S.A., Westrich H.R., Banfield J.F. The effect of Fe-oxidizing bacteria on Fe-silicate mineral dissolution. Chem. Geol. 2001, 180:99-115.
94. Sayles F.L., Fyfe W.S. The crystallization of magnesite from aqueous solution. Geochim. Cosmochim. Acta 1973, 37:87-99.
95. Savage P.E., Yu J., Stylski N., Brock E.E. Kinetics of methane oxidation in supercritical water. J. Supercrit. Fluids 1998, 12:141-153.
96. Schott J., Berner R. X-ray photoelectron studies of the mechanism of iron silicate dissolution during weathering. Geochim. Cosmochim. Acta 1983, 47:2233-2240.
97. Schott J., Pokrovsky O.S., Oelkers E.H. The link between mineral dissolution/precipitation kinetics and solution chemistry. Rev. Mineral. Geochem. 2009, 70:207-258.
98. Seyfried W., Gordon P., Dickson F. New reaction cell for hydrothermal solution equipment. Am. Mineral. 1979, 64:646-649.
99. Siever R., Woodford N. Dissolution kinetics and the weathering of mafic minerals. Geochim. Cosmochim. Acta 1979, 43:717-724.
100. Sigg L., Stumm W. The interaction of anions and weak acids with the hydrous goethite ([alpha]-FeOOH) surface. Colloid Surf. 1981, 2:101-117.
101. Sternbeck J. Kinetics of rhodochrosite crystal growth at 25°C: the role of surface speciation. Geochim. Cosmochim. Acta 1997, 61:785-793.
102. Stumm W., Lee F. Oxygenation of ferrous iron. Ind. Eng. Chem. 1961, 53:143-146.
103. 2 conditions. Geochim. Cosmochim. Acta 2012, 84:29-46.
104. 2 conditions and their implications for Precambrian weathering. Geochim. Cosmochim. Acta 2009, 73:3767-3781.
105. 4 single crystals. J. Cryst. Growth 1974, 23:121-124.
106. 4 by adsorption of iron(II) ion on γ-FeO(OH). J. Chem. Soc. Dalton Trans. 1983, 1983:189-194.
107. Velbel M.A. Formation of protective surface layers during silicate-mineral weathering under well-leached, oxidizing conditions. Am. Mineral. 1993, 78:405-414.
108. Velbel M.A. Dissolution of olivine during natural weathering. Geochim. Cosmochim. Acta 2009, 73:6098-6113.
109. Waltham C.A., Eick M.J. Kinetics of arsenic adsorption on goethite in the presence of sorbed silicic acid. Soil Sci. Soc. Am. 2002, 66:818-825.
110. 2 pressure. Environ. Sci. Technol. 2012, 10.1021/es301231n.
111. Wang J., Kalinichev A.G., Kirkpatrick R.J. Effects of substrate structure and composition on the structure, dynamics, and energetics of water at mineral surfaces: a molecular dynamics modeling study. Geochim. Cosmochim. Acta 2006, 70:562-582.
112. 1 compounds in near-critical and supercritical water. Chem. Rev. 2004, 104:5803-5821.
113. Weber W., Stumm W. Formation of a silicato-iron (III) complex in dilute aqueous solution. J. Inorg. Nucl. Chem. 1965, 27:237-239.
114. White A.F., Yee A. Aqueous oxidation-reduction kinetics associated with coupled electron-cation transfer from iron containing silicate at 25°C. Geochim. Cosmochim. Acta 1985, 49:1263-1275.
115. 2, and organic acids. Geochim. Cosmochim. Acta 1991, 55:943-954.
116. Wogelius R., Walther J. Olivine dissolution kinetics at near-surface conditions. Chem. Geol. 1992, 97:101-112.
117. 2 sequestration reactions using a novel microreaction system. Environ. Sci. Technol. 2004, 38:932-936.
118. 2: implications for mineral sequestration of carbon dioxide. Geochim. Cosmochim. Acta 2011, 75:5510-5525.