Asymmetric α-allylation of α-branched aldehydes with allyl alcohols by synergistic catalysis using an achiral palladium complex and a chiral primary amino acid

Synthesis (Germany)

Volumn 46, Issue 10, 2014, Pages 1367-1373

  Yoshida, Masanori ^a   Masaki, Erika ^a   Terumine, Tatsuaki ^a   Hara, Shoji ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

aldehydes; allylation; amino acids; asymmetric catalysis; palladium

Indexed keywords

ALDEHYDES; ALLYLATION; AMINO ACIDS; CATALYSIS; ENANTIOSELECTIVITY; PALLADIUM; REACTION KINETICS;

ASYMMETRIC CATALYSIS; BRANCHED ALDEHYDES; HIGH ENANTIOSELECTIVITY; PALLADIUM COMPLEXES; PRIMARY AMINO ACID; STEREOGENIC CENTERS; SYNERGISTIC CATALYSIS; TRANSITION-METAL CATALYSIS;

PALLADIUM COMPOUNDS;

2 (3 CHLOROPHENYL) 2 METHYLPENT 4 ENAL; 2 (4 CHLOROPHENYL) 2 METHYLPENT 4 ENAL; 2 (4 FLUOROPHENYL) 2 METHYLPENT 4 ENAL; 2 (BENZYLOXYCARBONYLAMINO) 3 METHYLBUTANE 1,3 DIOL; 2 ETHYL 2 PHENYLPENT 4 ENAL; 2 METHYL 2 (3 METHYLPHENYL)PENT 4 ENAL; 2 METHYL 2 (4 METHYLPHENYL)PENT 4 ENAL; 2 METHYL 2 (NAPHTHALEN 2 YL)PENT 4 ENAL; 2 METHYL 2 (THIOPHEN 2 YL)PENT 4 ENAL; 2 METHYL 2 PHENYLPENT 4 ENAL; 3 (TERT BUTYLDIMETHYLSILOXY) DEXTRO VALINE; ALDEHYDE DERIVATIVE; ALLYL ALCOHOL; ALPHA AMINO ACID; N (BENZYLOXYCARBONYL) 3 (TERT BUTYLDIMETHYLSILOXY) DEXTRO VALINE BENZYL ESTER; N (BENZYLOXYCARBONYL) 3 HYDROXY DEXTRO VALINE; N (BENZYLOXYCARBONYL) 3 HYDROXY DEXTRO VALINE BENZYL ESTER; N (BENZYLOXYCARBONYL) O (TERT BUTYLDIMETHYLSILYL) 3,3 DIETHYL DEXTRO SERINE BENZYL ESTER; N (BENZYLOXYCARBONYL) SERINE METHYL ESTER; O (TERT BUTYLDIMETHYLSILYL) 3,3 DIETHYL DEXTRO SERINE; O (TERT BUTYLDIMETHYLSILYL) 3,3 DIETHYLD DEXTRO SERINE; PALLADIUM COMPLEX; UNCLASSIFIED DRUG;

ALLYLATION; ALPHA ALLYLATION; ARTICLE; ASYMMETRIC CATALYSIS; CATALYST; CHIRALITY; ENANTIOSELECTIVITY; STEREOCHEMISTRY;

EID: 84900498823     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0033-1340901     Document Type: Article

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