Iridium-catalyzed regioselective silylation of secondary alkyl C-H bonds for the synthesis of 1,3-diols

Journal of the American Chemical Society

Volumn 136, Issue 18, 2014, Pages 6586-6589

  Li, Bijie ^a,b   Driess, Matthias ^b   Hartwig, John F ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

IRIDIUM; REGIOSELECTIVITY;

C-H BOND CLEAVAGE; CATALYTIC CYCLES; DEHYDROGENATIVE COUPLING; FUNCTIONALIZATIONS; HYDROXYL GROUPS; MECHANISTIC STUDIES; REGIO-SELECTIVE; SECONDARY ALCOHOLS;

CATALYSIS;

ALCOHOL DERIVATIVE; ALKYL GROUP; ETHER DERIVATIVE; HYDROXYL GROUP; IRIDIUM; SILANE DERIVATIVE;

ARTICLE; CATALYSIS; CONFORMATION; CROSS COUPLING REACTION; DEHYDROGENATION; HYDROGEN BOND; OXIDATION; QUANTUM YIELD; REACTION ANALYSIS; SILYLATION; STEREOCHEMISTRY; SYNTHESIS;

EID: 84900328445     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja5026479     Document Type: Article

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