A new synthetic route to heteroarylsilanes via ruthenium-catalyzed C-H/SiR3 coupling

Chemistry Letters

Volumn , Issue 7, 2000, Pages 750-751

  Kakiuchi, Fumitoshi ^a   Matsumoto, Mitsutaka ^a   Sonoda, Motohiro ^a   Fukuyama, Takahide ^a   Chatani, Naoto ^a   Murai, Shinji ^a   Furukawa, Naoyuki ^b   Seki, Yoshio ^b  

^a OSAKA UNIVERSITY   (Japan)

^b KAGAWA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0034339519     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2000.750     Document Type: Article

References (18)

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12. 8
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17. 3 also exhibited a high activity, this complex was not good catalyst for other substrates. For example, in the case of the reaction of 1-methyl-3-acetylpyrrol 14 with the vinylsilane 6, the yield was decreased to 6%.
18. In the ruthenium-catalyzed dehydrogenative silylation of olefins using triorganovinylsilanes, β-silyl elimination has been documented by Wakatsuki and co-workers. See, Ref 7a.