Hydrocarbation of C≡C bonds: Quantification of the nucleophilic reactivity of ynamides

Angewandte Chemie - International Edition

Volumn 53, Issue 19, 2014, Pages 4968-4971

  Laub, Hans A ^a   Evano, Gwilherm ^b   Mayr, Herbert ^a  

^a UNIVERSITY OF MUNICH   (Germany)

^b UNIVERSITÉ LIBRE DE BRUXELLES   (Belgium)

Author keywords

iminium ions; kinetic isotope effects; kinetics; linear free energy relationships; vinyl cations

Indexed keywords

ENZYME KINETICS; ISOTOPES; KINETICS; POSITIVE IONS;

DIARYLCARBENIUM IONS; ELECTROPHILIC REACTION; IMINIUM IONS; KINETIC ISOTOPE EFFECTS; LINEAR FREE ENERGY RELATIONSHIPS; NUCLEOPHILIC REACTIVITY; SECOND-ORDER RATE CONSTANTS; VINYL CATIONS;

RATE CONSTANTS;

EID: 84899938206     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201402055     Document Type: Article

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