Fluorine- and niobium-doped TiO2: Chemical and spectroscopic properties of polycrystalline n-type-doped anatase

Journal of Physical Chemistry C

Volumn 118, Issue 16, 2014, Pages 8462-8473

  Biedrzycki, Jakub ^a   Livraghi, Stefano ^a   Giamello, Elio ^a   Agnoli, Stefano ^b   Granozzi, Gaetano ^b  

^a UNIVERSITY OF TURIN   (Italy)

^b UNIVERSITY OF PADOVA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

DOPING (ADDITIVES); FLUORINE; IONS; MATERIALS PROPERTIES; NIOBIUM;

CONDUCTIVITY PROPERTIES; N-TYPE MATERIALS; OPTICAL BANDS; OPTOELECTRONIC PROPERTIES; POLYCRYSTALLINE; PRISTINE OXIDE; SPECTROSCOPIC PROPERTY; TITANIUM ION;

TITANIUM DIOXIDE;

EID: 84899520538     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp501203h     Document Type: Article

References (73)

1. 2-New Photochemical Processes Chem. Rev. 2006, 106, 4428-4453
2. 2 Photocatalysis Surf. Sci. Rep. 2011, 66, 185-297
3. Serpone, N.; Pelizzetti, E. Photocatalysis: Fundamentals and Applications; Wiley & Sons: New York, 1989.
4. Fujishima, A.; Honda, K. Electrochemical Photolysis of Water at a Semiconductor Electrode Nature 1972, 238, 37-38
5. 2 Photocatalytic Disinfection Water Res. 2004, 38, 1069-1077
6. Nozawa, M.; Tanigawa, K.; Hosomi, M.; Chikusa, T.; Kawada, E. Removal and Decomposition of Malodorants by Using Titanium Dioxide Photocatalyst Supported on Fiber Activated Carbon Water Sci. Technol. 2001, 44, 127-133
7. Watanabe, T.; Nakajima, A.; Wang, R.; Minabe, M.; Koizumi, S.; Fujishima, A.; Hashimoto, K. Photocatalytic Activity and Photoinduced Hydrophilicity of Titanium Dioxide Coated Glass Thin Solid Films 1999, 351, 260-263
8. Hagfeld, A.; Grätzel, M. Light-Induced Redox Reactions in Nanocrysyalline Systems Chem. Rev. 1995, 95, 49-68
9. Asahi, R.; Morikawa, T.; Ohwaki, T.; Aoki, K.; Taga, Y. Visible Light Photocatalysis in Nitrogen-Doped Titanium Oxides Science 2001, 293, 269-271
10. 2 and Related Surface Phenomena Surf. Sci. Rep. 2008, 63, 515-582
11. 2: Theory and Experiment Chem. Phys. 2007, 339, 44-56
12. 2 Powders Chem. Mater. 2002, 14, 3808-3816
13. 2 Powders by Creation of Surface Oxygen Vacancies Chem. Phys. Lett. 2005, 401, 579-584
14. 2 J. Phys. Chem. C 2008, 112, 8951-8956
15. x Inorg. Chem. 1979, 18, 488-492
16. Wang, C. M.; Mallouk, T. E. Photoelectrochemistry and Interfacial Energetics of Titanium Dioxide Photoelectrodes in Fluoride-Containing Solution J. Phys. Chem. 1990, 94, 423-428
17. 3+ Species J. Phys. Chem. C 2009, 113, 20543-20552
18. 2 System J. Solid State Chem. 1988, 77, 255-263
19. 2 and Implications for Water Photocleavage Processes Chem. Phys. Lett. 1984, 106, 135-138
20. Livraghi, S.; Chiesa, M.; Paganini, M. C.; Giamello, E. On the Nature of Reduced States in Titanium Dioxide As Monitored by Electron Paramagnetic Resonance. I: The Anatase Case J. Phys. Chem. C 2011, 115, 25413-25421
21. 2 Appl. Phys. Lett. 2005, 86, 252101
22. 2 Appl. Phys. Lett. 2007, 91, 112113
23. 2 Films Curr. Appl. Phys. 2013, 13, 556-561
24. 5+ to Enhance Transparency and Charge Collection Efficiency in Dye-Sensitized Solar Cells J. Phys. Chem. C 2010, 114, 15849-15856
25. 2 Prepared by Hydrothermal Synthesis J. Am. Chem. Soc. 2012, 95, 3192-3196
26. 2 Nanocrystals with Tunable Infrared Absorption Chem. Mater. 2013, 25, 3383-3390
27. P Chester, P. Cross-Doping Agent for Rutile Masers J. Appl. Phys. 1961, 32, 866-868
28. 2 Phys. Rev. B 1973, 8, 3917-3927
29. 2(110) Surface by Molecular Beam Epitaxy Mater. Lett. 1996, 26, 217-221
30. 2 in Formic Acid Mineralization Photochem. Photobiol. Sci. 2011, 10, 343-349
31. Materials Analysis Using Diffraction, available at http://www.ing.unitn. it/∼maud.
32. 2 Phys. Rev. B 2000, 61, 13445-13457
33. 4 in Aqueous Chloride Solutions Colloids Surf., A 2008, 317, 366-376
34. 2 Epitaxial Films at High Temperatures J. Appl. Phys. 2006, 100, 096105
35. 2: Intrinsic Transparent Metallic Anatase Versus Highly Resistive Rutile Phase J. Appl. Phys. 2007, 102, 013701
36. 2:(Nb,N)- x Compounds on the Rate of Photocatalytic Methylene Blue Dye Degradation J. Phys. Chem. C 2013, 117, 8611-8618
37. 2 Thin Films Thin Solid Films 1997, 310, 161-166
38. 2 Films J. Phys. Chem. B 2006, 110, 1210-1220
39. 2 Nanoparticles Synthesized via Hydrothermal Crystallization J. Mater. Sci. 2009, 44, 6135-6143
40. 2-Anatase: A Real Alternative for Visible Light-Driven Photocatalysis Catal. Today 2009, 143, 286-292
41. 2-Mixed Oxide as Efficient Solar Photocatalytic: Preparation, Characterization, and Photocatalytic Activity Int. J. Photoenergy 2012, 548158
42. 2 Electrode Using Nb Doping for Highly Efficient Dye-Sensitized Solar Cells Prog. Photovoltaics 2012, 20, 904-911
43. 2 r.f. Sputtered Thin Films Appl. Surf. Sci. 2000, 156, 200-206
44. 2 Polymorphs As Seen by Electron Paramagnetic Resonance Spectroscopy Phys. Chem. Chem. Phys. 2013, 15, 9435-9447
45. 2(110)-(1 × 1) Surface J. Phys. Chem. C 2013, 117, 17680-17686
46. Tanuma, S.; Powell, C. J.; Penn, D. R. Calculations of Electron Inelastic Mean Free Paths Surf. Interface Anal. 1994, 21, 165-176
47. Sandell, A.; Sanyal, B.; Walle, L. E.; Uvdal, P.; Borg, A. Probing the Conduction Band Edge of Transition Metal Oxides by X-ray Absorption Spectroscopy J. Electron Spectrosc. Relat. Phenom. 2011, 183, 107-113
48. 2 Nanosheet on Pt(110) (1 × 2) J. Chem. Phys. 2011, 135, 054706
49. 2 Electrode for Dye-Sensitized Solar Cells Energy Environ. Sci. 2011, 4, 1480-1486
50. Martra, G.; Gianotti, E.; Coluccia, S. The Application of UV-Visible-NIR Spectroscopy to Oxides. In Metal Oxide Catalysis; Hargraves, J. S. J.; Jackson, D., Eds.; Wiley-VCH: Weinheim, Germany, 2008; Chapter 2, pp 51-94.
51. 3/Si(001) Heterojunctions Appl. Phys. Lett. 2000, 77, 1662-1664
52. Archana, P. S.; Jose, R.; Yosoff, M. M.; Ramakrishna, S. Near Band-Edge Electron in Electrospun Nb-Doped Anatase Nanofibers Probed by Electrochemical Impedence Spectroscopy Appl. Phys. Lett. 2011, 98, 152106
53. 2 Appl. Phys. Express 2008, 1, 111203
54. 2 Appl. Phys. Lett. 2008, 92, 252104
55. 2 from Density Functional Theory J. Phys. Chem. C 2009, 113, 346-358
56. 2 J. Phys. Chem. C 2010, 114, 5891-5897
57. 2(110) Surface Probed by Resonant Photoelectron Diffraction Phys. Rev. Lett. 2008, 100, 055501
58. Wendt, S.; Sprunger, P. T.; Lira, E.; Madsen, G. K. H. M.; Li, Z.; Hansen, J.; Matthiensen, J.; Blekinge-Rasmussen, A.; Lægsgaard, E.; Hammer, B.; Besenbacher, F. The Role of Interstitial Sites in the Ti 3d Defects State in the Band Gap of Titania Science 2008, 320, 1755-1759
59. 17O HYSCORE Angew. Chem. Int. Ed. 2011, 50, 8038-8040
60. Chiesa, M.; Paganini, M. C.; Giamello, E.; Murphy, D. M.; Di Valentin, C.; Pacchioni, G. Excess Electrons Stabilization on Ionic Oxide Surfaces Acc. Chem. Res. 2006, 39, 861-867
61. 2 Anatase Nanoparticles Chem. Phys. 2007, 339, 138-145
62. Diebold, U. The Surface Science of Titanium Dioxide Surf. Sci. Rep. 2003, 48, 53-229
63. 2 J. Phys. Chem. C 2007, 111, 10630-10638
64. 2 Matrix: Spectroscopic Properties and Photoinduced Electron Transfer J. Phys. Chem. C 2010, 114, 18553-18558
65. 2 from ab Initio Calculation Phys. Rev. B 2010, 81, 075111
66. 2 Phys. Chem. Chem. Phys. 2002, 4, 358-365
67. 3+ Ions and Electron Delocalization in Synthetic Blue Rutile Phys. Chem. Miner. 1998, 25, 338-346
68. 2 Nanoparticles Induced by Sub-Band-Gap Illumination J. Phys. Chem. C 2010, 114, 1240-1245
69. 2(110) Surf. Rev. Lett. 2000, 5-6, 613-617
70. Maurelli, S.; Livraghi, S.; Chiesa, M.; Giamello, E.; Van Doorslaer, S.; Di Valentin, C.; Pacchioni, G. Hydration Structure of the Ti(III) Cation as Revealed by Pulse EPR and DFT Studies: New Insights into a Textbook Case Inorg. Chem. 2011, 50, 2385-2394
71. 3+ Enhanced Photocatalyst for Hydrogen Production under Visible Light J. Am. Chem. Soc. 2010, 132, 11856-11857
72. 4 to Engineer Morphology, Oxygen Vacancy Concentration, and Photocatalytic Activity J. Am. Chem. Soc. 2012, 134, 6751-6761
73. 2 with Visible Light Photoactivity Inorg. Chem. 2013, 52, 3884-3890