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Volumn 5, Issue 4, 2014, Pages 1390-1395

Three-electron two-centred bonds and the stabilisation of cationic sulfur radicals

Author keywords

[No Author keywords available]

Indexed keywords

CATIONIC SULFURS; ELECTRON HOPPING; ELECTRONIC COMMUNICATIONS; FUNCTIONAL DERIVATIVES; SULFUR RADICALS;

EID: 84897731895     PISSN: 20416520     EISSN: 20416539     Source Type: Journal    
DOI: 10.1039/c3sc53432d     Document Type: Article
Times cited : (41)

References (50)
  • 2
    • 0003438540 scopus 로고
    • Cornell University Press, Ithaca, New York, It is less common to find three-electron two-centred systems with bond order greater than There are less examples of three-electron bonds involving s orbitals, as the prerequisite for them to contribute to three-electron systems is that they contribute to the frontier orbitals
    • L. Pauling, The Nature of the Chemical Bond, Cornell University Press, Ithaca, New York, 1960
    • (1960) The Nature of the Chemical Bond
    • Pauling, L.1
  • 3
    • 0003955397 scopus 로고
    • Clarendon Press Oxford, 158-161
    • C. A. Coulson, Valence, Clarendon Press Oxford, 1952, pp. 158-161
    • (1952) Valence
    • Coulson, C.A.1
  • 8
    • 84884190622 scopus 로고    scopus 로고
    • These states offer similar electronic stabilisation of the radical, but differ in conformational energy due to bond rotations In this instance, there is a minor σ contribution from the neighbouring C-H motifs
    • W. Sun H. Dai Y. Tao D. Xiao Y. Zhang Z. Wei X. Chen J. Phys. Chem. C 2013 117 18325
    • (2013) J. Phys. Chem. C , vol.117 , pp. 18325
    • Sun, W.1    Dai, H.2    Tao, Y.3    Xiao, D.4    Zhang, Y.5    Wei, Z.6    Chen, X.7


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.