Kinetic and mechanistic studies of carbon-to-metal hydrogen atom transfer involving os-centered radicals: Evidence for tunneling

Journal of the American Chemical Society

Volumn 136, Issue 9, 2014, Pages 3572-3578

  Lewandowska Andralojc, Anna ^a   Grills, David C ^a   Zhang, Jie ^a,d   Bullock, R Morris ^b   Miyazawa, Akira ^c   Kawanishi, Yuji ^c   Fujita, Etsuko ^a  

^a BROOKHAVEN NATIONAL LABORATORY   (United States)

^b PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^c NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

^d HENAN NORMAL UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ABSTRACTING; ACTIVATION ENERGY; ATOMS; CARBON; CARRIER MOBILITY; HYDROGEN; ISOTOPES; KINETICS; METALS; OSMIUM; QUANTUM THEORY; RATE CONSTANTS; XANTHENES;

DEUTERIUM KINETIC ISOTOPE EFFECT; HYDROGEN-ATOM TRANSFER; KINETIC ISOTOPE EFFECTS; METAL-CENTERED RADICALS; PREEXPONENTIAL FACTOR; QUANTUM-MECHANICAL TUNNELING; SPECTROSCOPIC MEASUREMENTS; TEMPERATURE-DEPENDENT MEASUREMENTS;

FREE RADICAL REACTIONS;

1,4 CYCLOHEXADIENE; ANTHRACENE; CARBON; DEUTERIUM; DIMER; HEPTANE; HYDROCARBON; HYDROGEN; ISOTOPE; METAL; OSMIUM; RADICAL; XANTHENE;

ARTICLE; BLEACHING; CHEMICAL REACTION KINETICS; DISSOCIATION; HYDROGEN BOND; INFRARED SPECTROSCOPY; LIGHT; OXIDATION; PHOTOLYSIS; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; TEMPERATURE;

EID: 84897695995     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja4123076     Document Type: Article

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