Measurements of total hydroxyl radical reactivity during CABINEX 2009 – Part 1: Field measurements

Atmospheric Chemistry and Physics

Volumn 14, Issue 6, 2014, Pages 2923-2937

  Hansen, R F ^a,h   Griffith, S M ^a   Dusanter, S ^a,b,c   Rickly, P S ^a   Stevens, P S ^a   Bertman, S B ^d   Carroll, M A ^e   Erickson, M H ^f   Flynn, J H ^g   Grossberg, N ^g   Jobson, B T ^f   Lefer, B L ^g   Wallace, H W ^f  

^a INDIANA UNIVERSITY   (United States)

^b ECOLE DES MINES DE DOUAI   (France)

^c UNIV LILLE   (France)

^d WESTERN MICHIGAN UNIVERSITY   (United States)

^e UNIVERSITY OF MICHIGAN   (United States)

^f Washington State University   (United States)

^g University of Houston   (United States)

^h UNIVERSITY OF LEEDS   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERE-BIOSPHERE INTERACTION; ATMOSPHERIC CHEMISTRY; FOREST CANOPY; FOREST FLOOR; HYDROXYL RADICAL; MEASUREMENT METHOD; OXIDATION; TRACE GAS; VOLATILE ORGANIC COMPOUND;

MICHIGAN; UNITED STATES;

EID: 84896995464     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-14-2923-2014     Document Type: Article

References (49)

1. Apel, E. C., Riemer, D. D., Hills, A., Baugh, W., Orlando, J., Faloona, I., Tan, D., Brune, W., Lamb, B., Westberg, H., Carroll, M. A., Thornberry, T., and Geron, C. D.: Measurement and interpretation of isoprene fluxes and isoprene, methacrolein, and methyl vinyl ketone mixing ratios at the PROPHET site during the 1998 intensive, J. Geophys. Res., 107, 4034, doi:10.1029/2000JD000225, 2002.
2. Atkinson, R.: Gas-Phase Tropospheric Chemistry of Volatile Organic Compounds: 1. Alkanes and Alkenes, J. Phys. Chem. Ref. Data, 26, 215-290, 1997.
3. Atkinson, R.: Kinetics of the gas-phase reactions of OH radicals with alkanes and cycloalkanes, Atmos. Chem. Phys., 3, 2233- 2307, doi:10.5194/acp-3-2233-2003, 2003.
4. Atkinson, R., Arey, J., Aschmann, S. M., Corchnoy, S. B., and Shu, Y.: Rate Constants for the Gas-Phase Reactions of cis-3-Hexen- 1-ol, cis-3-Hexenylacetate, trans-2-Hexenal, and Linalool with OH and NO3 Radicals and O3 at 296±2K, and OH Radical Formation Yields from the O3 Reactions, Int. J. Chem. Kinet., 27, 941-955, 1995.
5. Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., Troe, J., and IUPAC Subcommittee: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II - gas phase reactions of organic species, Atmos. Chem. Phys., 6, 3625-4055, doi:10.5194/acp-6-3625-2006, 2006. (Pubitemid 44369557)
6. Bryan, A. M., Bertman, S. B., Carroll, M. A., Dusanter, S., Edwards, G. D., Forkel, R., Griffith, S., Guenther, A. B., Hansen, R. F., Helmig, D., Jobson, B. T., Keutsch, F. N., Lefer, B. L., Pressley, S. N., Shepson, P. B., Stevens, P. S., and Steiner, A. L.: Incanopy gas-phase chemistry during CABINEX 2009: sensitivity of a 1-D canopy model to vertical mixing and isoprene chemistry, Atmos. Chem. Phys., 12, 8829-8849, doi:10.5194/acp-12-8829- 2012, 2012.
7. Carroll, M. A., Bertman, S. B., and Shepson, P. B.: Overview of the Program on Research for Oxidants: PHotochemistry, Emissions, and Transport (PROPHET) 1998 summer intensive, J. Geophys. Res., 106, 24275-24288, 2001.
8. Chatani, S., Shimo, N., Matsunaga, S., Kajii, Y., Kato, S., Nakashima, Y., Miyazaki, K., Ishii, K., and Ueno, H.: Sensitivity analyses of OH missing sinks over Tokyo metropolitan area in the summer of 2007, Atmos. Chem. Phys., 9, 8975-8986, doi:10.5194/acp-9-8975-2009, 2009.
9. Di Carlo, P., Brune, W. H., Martinez, M., Harder, H., Lesher, R., Ren, X., Thornberry, T., Carroll, M. A., Young, V., Shepson, P. B., Reimer, D., Apel, E., and Campbell, C.: Missing OH Reactivity in a Forest: Evidence for Unknown Reactive Biogenic VOCs, Science, 304, 722-725, 2004. (Pubitemid 38560875)
10. Dolgorouky, C., Gros, V., Sarda-Esteve, R., Sinha, V., Williams, J., Marchand, N., Sauvage, S., Poulain, L., Sciare, J., and Bonsang, B.: Total OH reactivity measurements in Paris during the 2010 MEGAPOLI winter campaign, Atmos. Chem. Phys., 12, 9593- 9612, doi:10.5194/acp-12-9593-2012, 2012.
11. Dusanter, S., Vimal, D., and Stevens, P. S.: Technical note: Measuring tropospheric OH and HO2 by laser-induced fluorescence at low pressure. A comparison of calibration techniques, Atmos. Chem. Phys., 8, 321-340, doi:10.5194/acp-8-321-2008, 2008.
12. Dusanter, S., Vimal, D., Stevens, P. S., Volkamer, R., and Molina, L. T.: Measurements of OH and HO2 concentrations during the MCMA-2006 field campaign - Part 1: Deployment of the Indiana University laser-induced fluorescence instrument, Atmos. Chem. Phys., 9, 1665-1685, doi:10.5194/acp-9-1665-2009, 2009.
13. Edwards, P. M., Evans, M. J., Furneaux, K. L., Hopkins, J., Ingham, T., Jones, C., Lee, J. D., Lewis, A. C., Moller, S. J., Stone, D., Whalley, L. K., and Heard, D. E.: OH reactivity in a South East Asian tropical rainforest during the Oxidant and Particle Photochemical Processes (OP3) project, Atmos. Chem. Phys., 13, 9497-9514, doi:10.5194/acp-13-9497-2013, 2013.
14. Ehhalt, D. H.: Atmospheric chemistry - Radical ideas, Science, 279, 1002-1003, 1998.
15. Goldstein, A. H. and Galbally, I. E.: Known and unexplored organic constituents in the earth's atmosphere, Environ. Sci. Technol., 41, 1514-1521, 2007. (Pubitemid 46362448)
16. Griffith, S. M., Hansen, R. F., Dusanter, S., Stevens, P. S., Alaghmand, M., Bertman, S. B., Carroll, M. A., Erickson, M., Galloway, M., Grossberg, N., Hottle, J., Hou, J., Jobson, B. T., Kammrath, A., Keutsch, F. N., Lefer, B. L., Mielke, L. H., O'Brien, A., Shepson, P. B., Thurlow, M., Wallace, W., Zhang, N., and Zhou, X. L.: OH and HO2 radical chemistry during PROPHET 2008 and CABINEX 2009 -Part 1: Measurements and model comparison, Atmos. Chem. Phys., 13, 5403-5423, doi:10.5194/acp-13-5403-2013, 2013.
17. Guenther, A. B., Zimmerman, P. R., Harley, P. C., Monson, R. K., and Fall, R.: Isoprene and Monoterpene Emission Rate Variability - Model Evaluations and Sensitivity Analyses, J. Geophys. Res.-Atmos., 98, 12609-12617, 1993.
18. Hansen, R. F., Griffith, S. M., Dusanter, S., Stevens, P. S., Bertman, S. B., Bryan, A. M., Carroll, M. A., Erickson, M. H., Flynn, J. H., Galloway, M. M., Grossberg, N., Hou, J., Jobson, B. T., Keutsch, F. N., Lefer, B. L., O'Brien, A., Shepson, P. B., Steiner, A. L., Thurlow, M., Wallace, H. W., Zhang, N., and Zhou, X. L.: Measurements of Total Hydroxyl Radical Reactivity during the CABINEX 2009 Field Campaign: Part 2 - Modeling of Hydroxyl Radical Reactivity, Atmos. Chem. Phys., in preparation, 2014.
19. Holzinger, R., Lee, A., Paw, K. T., and Goldstein, U. A. H.: Observations of oxidation products above a forest imply biogenic emissions of very reactive compounds, Atmos. Chem. Phys., 5, 67-75, doi:10.5194/acp-5-67-2005, 2005. (Pubitemid 40335293)
20. Ingham, T., Goddard, A., Whalley, L. K., Furneaux, K. L., Edwards, P. M., Seal, C. P., Self, D. E., Johnson, G. P., Read, K. A., Lee, J. D., and Heard, D. E.: A flow-tube based laser-induced fluorescence instrument to measure OH reactivity in the troposphere, Atmos. Meas. Tech., 2, 465-477, doi:10.5194/amt-2-465-2009, 2009.
21. Jobson, B. T. and McCoskey, J. K.: Sample drying to improve HCHO measurements by PTR-MS instruments: laboratory and field measurements, Atmos. Chem. Phys., 10, 1821-1835, doi:10.5194/acp-10-1821-2010, 2010.
22. Karl, T., Guenther, A., Turnipseed, A., Tyndall, G., Artaxo, P., and Martin, S.: Rapid formation of isoprene photo-oxidation products observed in Amazonia, Atmos. Chem. Phys., 9, 7753-7767, doi:10.5194/acp-9-7753-2009, 2009.
23. Karl, T., Harley, P., Emmons, L., Thornton, B., Guenther, A., Basu, C., Turnipseed, A., and Jardine, K.: Efficient Atmospheric Cleansing of Oxidized Organic Trace Gases by Vegetation, Science, 330, 816-819, 2010.
24. Kesselmeier, J. and Staudt, M.: Biogenic Volatile Organic Compounds (VOC): An Overview on Emission, Physiology, and Ecology, J. Atmos. Chem., 33, 23-88, 1999. (Pubitemid 29151350)
25. Kim, S., Karl, T., Helmig, D., Daly, R., Rasmussen, R., and Guenther, A.: Measurement of atmospheric sesquiterpenes by proton transfer reaction-mass spectrometry (PTR-MS), Atmos. Meas. Tech., 2, 99-112, doi:10.5194/amt-2-99-2009, 2009.
26. Kim, S., Guenther, A., Karl, T., and Greenberg, J.: Contributions of primary and secondary biogenic VOC tototal OH reactivity during the CABINEX (Community Atmosphere-Biosphere INteractions Experiments)-09 field campaign, Atmos. Chem. Phys., 11, 8613-8623, doi:10.5194/acp-11-8613-2011, 2011.
27. Kovacs, T. A. and Brune,W. H.: Total OH Loss Rate Measurement, J. Atmos. Chem., 39, 105-122, 2001. (Pubitemid 32536951)
28. Kovacs, T. A., Brune, W. H., Harder, H., Martinez, M., Simpas, J. B., Frost, G. J., Williams, E., Jobson, T., Stroud, C., Young, V., Fried, A., and Wert, B.: Direct measurements of urban OH reactivity during Nashville SOS in summer 1999, J. Environ. Monitor., 5, 68-74, 2003. (Pubitemid 36223169)
29. Lou, S., Holland, F., Rohrer, F., Lu, K., Bohn, B., Brauers, T., Chang, C. C., Fuchs, H., Häseler, R., Kita, K., Kondo, Y., Li, X., Shao, M., Zeng, L., Wahner, A., Zhang, Y., Wang, W., and Hofzumahaus, A.: Atmospheric OH reactivities in the Pearl River Delta - China in summer 2006: measurement and model results, Atmos. Chem. Phys., 10, 11243-11260, doi:10.5194/acp-10-11243- 2010, 2010.
30. Mao, J., Ren, X., Brune, W. H., Olson, J. R., Crawford, J. H., Fried, A., Huey, L. G., Cohen, R. C., Heikes, B., Singh, H. B., Blake, D. R., Sachse, G. W., Diskin, G. S., Hall, S. R., and Shetter, R. E.: Airborne measurement of OH reactivity during INTEX-B, Atmos. Chem. Phys., 9, 163-173, doi:10.5194/acp-9- 163-2009, 2009.
31. Mao, J., Ren, X., Chen, S., Brune, W. H., Chen, Z., Martinez, M., Harder, H., Lefer, B., Rappenglück, B., Flynn, J., and Leuchner, M.: Atmospheric oxidation capacity in the summer of Houston 2006: Comparison with summer measurements in other metropolitan studies, Atmos. Environ., 44, 4107-4115, 2010.
32. Mao, J., Ren, X., Zhang, L., Van Duin, D. M., Cohen, R. C., Park, J.-H., Goldstein, A. H., Paulot, F., Beaver, M. R., Crounse, J. D., Wennberg, P. O., DiGangi, J. P., Henry, S. B., Keutsch, F. N., Park, C., Schade, G. W., Wolfe, G. M., Thornton, J. A., and Brune, W. H.: Insights into hydroxyl measurements and atmospheric oxidation in a California forest, Atmos. Chem. Phys., 12, 8009-8020, doi:10.5194/acp-12-8009-2012, 2012.
33. Mogensen, D., Smolander, S., Sogachev, A., Zhou, L., Sinha, V., Guenther, A.,Williams, J., Nieminen, T., Kajos, M. K., Rinne, J., Kulmala, M., and Boy, M.: Modelling atmospheric OH-reactivity in a boreal forest ecosystem, Atmos. Chem. Phys., 11, 9709- 9719, doi:10.5194/acp-11-9709-2011, 2011.
34. Nölscher, A. C., Williams, J., Sinha, V., Custer, T., Song, W., Johnson, A. M., Axinte, R., Bozem, H., Fischer, H., Pouvesle, N., Phillips, G., Crowley, J. N., Rantala, P., Rinne, J., Kulmala, M., Gonzales, D., Valverde-Canossa, J., Vogel, A., Hoffmann, T., Ouwersloot, H. G., Vilà-Guerau de Arellano, J., and Lelieveld, J.: Summertime total OH reactivity measurements from boreal forest during HUMPPA-COPEC 2010, Atmos. Chem. Phys., 12, 8257-8270, doi:10.5194/acp-12-8257-2012, 2012.
35. Ren, X., Harder, H., Martinez, M., Lesher, R. L., Oliger, A., Shirley, T., Adams, J., Simpas, J. B., and Brune, W. H.: HOx concentrations and OH reactivity observations in New York City during PMTACS-NY2001, Atmos. Environ., 37, 3627-3637, 2003a. (Pubitemid 36809171)
36. Ren, X., Harder, H., Martinez, M., Lesher, R. L., Oliger, A., Simpas, J. B., Brune, W. H., Schwab, J. J., Demerjian, K. L., He, Y., Zhou, X. L., and Gao, H. G.: OH and HO2 chemistry in the urban atmosphere of New York City, Atmos. Environ., 37, 3639-3651, 2003b. (Pubitemid 36809172)
37. Ren, X., Brune, W. H., Mao, J. Q., Mitchell, M. J., Lesher, R. L., Simpas, J. B., Metcalf, A. R., Schwab, J. J., Cai, C. X., Li, Y. Q., Demerjian, K. L., Felton, H. D., Boynton, G., Adams, A., Perry, J., He, Y., Zhou, X. L., and Hou, J.: Behavior of OH and HO2 in the winter atmosphere in New York city, Atmos. Environ., 40, 252-263, 2006a. (Pubitemid 44415548)
38. Ren, X., Brune, W. H., Oliger, A., Metcalf, A. R., Simpas, J. B., Shirley, T., Schwab, J. J., Bai, C., Roychowdhury, U., Li, Y., Cai, C., Demerjian, K. L., He, Y., Zhou, X., Gao, H., and Hou, J.: OH, HO2, and OH reactivity during the PMTACS-NY Whiteface Mountain 2002 campaign: Observations and model comparison, J. Geophys. Res., 111, D10S03, doi:10.1029/2005JD006126, 2006b.
39. Sadanaga, Y., Yoshino, A., Kato, S., Yoshioka, A., Watanabe, K., Miyakawa, Y., Hayashi, I., Ichikawa, M., Matsumoto, J., Nishiyama, A., Akiyama, N., Kanaya, Y., and Kajii, Y.: The importance of NO2 and volatile organic compounds in the urban air from the viewpoint of the OH reactivity, Geophys. Res. Lett., 31, L08102, doi:10.1029/2004gl019661, 2004a. (Pubitemid 38893024)
40. Sadanaga, Y., Yoshino, A., Watanabe, K., Yoshioka, A., Wakazono, Y., Kanaya, Y., and Kajii, Y.: Development of a Measurement System of OH reactivity in the atmosphere by using a laserinduced pump and probe technique, Rev. Sci. Instrum., 75, 2648- 2655, 2004b.
41. Schade, G.W., Goldstein, A. H., and Lamanna, M. S.: Are monoterpene emissions influenced by humidity?, Geophys. Res. Lett., 26, 2187-2190, 1999.
42. Seeley, J. V., Jayne, J. T., and Molina, M. J.: High-Pressure Fast- Flow Technique for Gas Kinetics Studies, Int. J. Chem. Kinet., 25, 571-594, 1993.
43. Shetter, R. E., Junkermann, W., Swartz, W. H., Frost, G. J., Crawford, J. H., Lefer, B. L., Barrick, J. D., Hall, S. R., Hofzumahaus, A., Bais, A., Calvert, J. G., Cantrell, C. A., Madronich, S., Muller, M., Kraus, A., Monks, P. S., Edwards, G. D., McKenzie, R., Johnston, P., Schmitt, R., Griffioen, E., Krol, M., Kylling, A., Dickerson, R. R., Lloyd, S. A., Martin, T., Gardiner, B., Mayer, B., Pfister, G., Roth, E. P., Koepke, P., Ruggaber, A., Schwander, H., and van Weele, M.: Photolysis frequency of NO2: Measurement and modeling during the International Photolysis Frequency Measurement and Modeling Intercomparison (IPMMI), J. Geophys. Res.-Atmos., 108, 8544, doi:10.1029/2002JD002932, 2003.
44. Sinha, V., Williams, J., Crowley, J. N., and Lelieveld, J.: The Comparative Reactivity Method - a new tool to measure total OH Reactivity in ambient air, Atmos. Chem. Phys., 8, 2213-2227, doi:10.5194/acp-8-2213-2008, 2008.
45. Sinha, V., J., W., Lelieveld, J., Ruuskanen, T. M., Kajos, M. K., Patokoski, J., Hellen, H., Hakola, H., Mogensen, D., Boy, M., Rinne, J., and Kumala, M.: OH Reactivity Measurements within a Boreal Forest: Evidence for Unknown Reactive Emissions, Environ. Sci. Technol., 44, 6614-6620, 2010.
46. Sinha, V., Williams, J., Diesch, J. M., Drewnick, F., Martinez, M., Harder, H., Regelin, E., Kubistin, D., Bozem, H., Hosaynali- Beygi, Z., Fischer, H., Andrés-Hernández, M. D., Kartal, D., Adame, J. A., and Lelieveld, J.: Constraints on instantaneous ozone production rates and regimes during DOMINO derived using in-situ OH reactivity measurements, Atmos. Chem. Phys., 12, 7269-7283, doi:10.5194/acp-12-7269-2012, 2012.
47. Westberg, H., Lamb, B., Hafer, R., Hills, A., Shepson, P., and Vogel, C.: Measurement of isoprene fluxes at the PROPHET site, J. Geophys. Res., 106, 24347-24358, 2001.
48. Wolfe, G. M., Thornton, J. A., Bouvier-Brown, N. C., Goldstein, A. H., Park, J.-H., McKay, M., Matross, D. M., Mao, J., Brune, W. H., LaFranchi, B. W., Browne, E. C., Min, K.-E., Wooldridge, P. J., Cohen, R. C., Crounse, J. D., Faloona, I. C., Gilman, J. B., Kuster, W. C., de Gouw, J. A., Huisman, A., and Keutsch, F. N.: The Chemistry of Atmosphere-Forest Exchange (CAFE) Model - Part 2: Application to BEARPEX-2007 observations, Atmos. Chem. Phys., 11, 1269-1294, doi:10.5194/acp-11-1269- 2011, 2011.
49. Yoshino, A., Sadanaga, Y., Watanabe, K., Kato, S., Miyakawa, Y., Matsumoto, J., and Kajii, Y.: Measurement of total OH reactivity by laser-induced pump and probe technique - comprehensive observations in the urban atmosphere of Tokyo, Atmos. Environ., 40, 7869-7881, 2006. (Pubitemid 44750782)