Observations of oxidation products above a forest imply biogenic emissions of very reactive compounds

Atmospheric Chemistry and Physics

Volumn 5, Issue 1, 2005, Pages 67-75

  Holzinger, R ^a   Lee, A ^a   Paw U, K T ^b   Goldstein, A H ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 14744304542     PISSN: 16807316     EISSN: None     Source Type: Journal    
DOI: 10.5194/acp-5-67-2005     Document Type: Article

References (29)

1. x, Atmos. Environ., 34 (12-14), 2063-2101, 2000.
2. Bauer, M. R., Hultman, N. E., Panek, J. A., and Goldstein, A. H.: Ozone deposition to a ponderosa pine plantation in the Sierra Nevada Mountains (CA): A comparison of two different climatic years, J. Geopbys. Res., 105 (D17), 22 123-22 136, 2000.
3. Chen, C. H. P. and Blackwelder, R. F.: Large-Scale Motion in a Turbulent Boundary-Layer - Study Using Temperature Contamination, J. Fluid Mech., 89 (NOV), 1-31, 1978.
4. Ciccioli, P., Brancaleoni, E., Frattoni, M., Di Palo, V., Valentini, R., Tirone, G., Seufert, G., Bertin, N., Hansen, U., Csiky, O., Lenz, R., and Sharma, M.: Emission of reactive terpene compounds from orange orchards and their removal by within-canopy processes, J. Geophys. Res., 104 (D7), 8077-8094, 1999.
5. Di Carlo, P., Brune, W. H., Martinez, M., Harder, H., Lesher, R., Ren, X., Thornberry, T., Carroll, M. A., Young, V., Shepson, P. B., Riemer, D., Apel, E., and Campbell, C.: Missing OH Reactivity in a Forest: Evidence for Unknown Reactive Biogenic VOCs, Science, 304, 722-725, 2004.
6. Dillon, M. B., Lamanna, M. S., Schade, G. W., Goldstein, A. H., and Cohen, R. C.: Chemical evolution of the Sacramento urban plume: Transport and oxidation, J. Geophys. Res., 107 (D5-6), doi:10.1029/ 2001JD000969, 2002.
7. Dreyfus, G. B., Schade, G. W., and Goldstein, A. H.: Observational constraints on the contribution of isoprene oxidation to ozone production on the western slope of the Sierra Nevada, California, J. Geophys. Res., 107 (D19), doi:10.1029/2001JD001490, 2002.
8. Faloona, I., Tan, D., Brune, W., Hurst, J., Barket, D., Couch, T. L., Shepson, P., Apel, E., Riemer, D., Thornberry, T., Carroll, M. A., Sillman, S., Keeler, G. J., Sagady, J., Hooper, D., and Paterson, K.: Nighttime observations of anomalously high levels of hydroxyl radicals above a deciduous forest canopy, J. Geophys. Res., 106 (D20), 24 315-24 333, 2001.
9. Fuentes, J. D., Lerdau, M., Atkinson, R., Baldocchi, D., Bottenheim, J. W., Ciccioli, P., Lamb, B., Geron, C., Gu, L., Guenther, A., Sharkey, T. D., and Stockwell, W.: Biogenic hydrocarbons in the atmospheric boundary layer: A review, B. Am. Meteorl. Soc., 81 (7), 1537-1575, 2000.
10. Goldstein, A. H., Hultman, N. E., Fracheboud, J. M., Bauer, M. R., Panek, J. A., Xu, M., Qi, Y., Guenther, A. B., and Baugh, W.: Effects of climate variability on the carbon dioxide, water, and sensible heat fluxes above a ponderosa pine plantation in the Sierra Nevada (CA), Agr. Forest Meteorol., 101 (2-3), 113-129, 2000.
11. Goldstein, A. H., McKay, M., Kurpius, M. R., Schade, G. W., Lee, A., Holzinger, R., and Rasmussen, R.: Forest thinning experiment confirms ozone deposition to forest canopy is dominated by reaction with biogenic VOCs, Geophys. Res. Lett., 31 (L22106), doi:10.1029/2004GL021259, 2004.
12. Hakola, H., Arey, J., Aschmann, S. M., and Atkinson, R.: Product Formation from the Gas-Phase Reactions of Oh Radicals and O3 with a Series of Monoterpenes, J. Atmos. Chem., 18 (1), 75-102, 1994.
13. Hatakeyama, S., Izumi, K., Fukuyama, T., Akimoto, H., and Washida, N.: Reactions of Oh with Alpha-Pinene and Beta-Pinene in Air - Estimate of Global Co Production from the Atmospheric Oxidation of Terpenes, J. Geophys. Res., 96 (D1), 947-958, 1991.
14. Kavouras, I. G., Mihalopoulos, N., and Stephanou, E. G.: Formation and gas/particle partitioning of monoterpenes photo-oxidation products over forests, Geophys. Res. Lett., 26 (1), 55-58, 1999.
15. Kurpius, M. R. and Goldstein, A. H.: Gas-phase chemistry dominates O-3 loss to a forest, implying a source of aerosols and hydroxyl radicals to the atmosphere, Geophys. Res. Lett., 30 (7), doi:10.1029/2002GL016785, 2003.
16. Lamanna, M. S. and Goldstein, A. H.: In situ measurements of C-2-C-10 volatile organic compounds above a Sierra Nevada ponderosa pine plantation, J. Geophys. Res., 104 (D17), 21 247-21 262, 1999.
17. Lee, A., Schade, G. W., Holzinger, R., and Goldstein, A. H.: A comparison of new measurements of total monoterpene flux with improved measurements of speciated monoterpene flux, Atmos. Chem. Phys. Discuss., 4, 7819-7835, 2004, SRef-ID: 1680-7375/acpd/2004-4-7819.
18. Lindinger, W., Hansel, A., and Jordan, A.: On-line monitoring of volatile organic compounds at pptv levels by means of proton-transfer-reaction mass spectrometry (PTR-MS) - Medical applications, food control and environmental research, Int. J. Mass Spectrom., 173 (3), 191-241, 1998.
19. O'Dowd, C. D., Aalto, P., Hameri, K., Kulmala, M., and Hoffmann, T.: Aerosol formation - Atmospheric particles from organic vapours, Nature, 416 (6880): 497-498, 2002.
20. Paulson, S. E., Chung, M. Y., and Hasson, A. S.: OH radical formation from the gas-phase reaction of ozone with terminal alkenes and the relationship between structure and mechanism, J. Phys. Chem. A, 103 (41), 8125-8138, 1999.
21. Paw U, K. T., Brunet, Y., Collineau, S., Shaw, R. H., Maitani, T., Qui, J., and Hipps, L.: Corrigendum: On Coherent Structures in Turbulence above and within Agricultural Plant Canopies, Agr. Forest Meteorol., 63 (1-2), 127-127, 1993.
22. Paw U, K. T., Qiu, J., Sun, H. B., Watanabe, T., and Brunet, Y.: Surface Renewal Analysis - a New Method to Obtain Scalar Fluxes, Agr. Forest Meteorol., 74 (1-2), 119-137, 1995.
23. Schade, G. W., and Goldstein, A. H.: Fluxes of oxygenated volatile organic compounds from a ponderosa pine plantation, J. Geophys. Res., 106 (D3), 3111-3123, 2001.
24. Schade, G. W. and Goldstein, A. H.: Increase of monoterpene emissions from a pine plantation as a result of mechanical disturbances, Geophys. Res. Lett., 30 (7), doi:10.1029/2002GL016138, 2003.
25. Schade, G. W., Goldstein, A. H., Gray, D. W., and Lerdau, M. T.: Canopy and leaf level 2-methyl-3-buten-2-ol fluxes from a ponderosa pine plantation, Atmos. Environ., 34 (21), 3535-3544, 2000.
26. Schade, G. W., Goldstein, A. H., and Lamanna, M. S.: Are monoterpene emissions influenced by humidity?, Geophys. Res. Lett., 26 (14), 2187-2190, 1999.
27. Snyder, R. L., Spano, D., and Paw U, K. T.: Surface renewal analysis for sensible and latent heat flux density, Bound.-Lay. Meteorol., 77 (3-4), 249-266, 1996.
28. Spano, D., Snyder, R. L., Duce, P., and Paw U, K. T.: Estimating sensible and latent heat flux densities from grapevine canopies using surface renewal, Agr. Forest Meteorol., 104 (3), 171-183, 2000.
29. Zapata, N. and Martinez-Cob, A.: Evaluation of the surface renewal method to estimate wheat evapotranspiration, Agr. Water Manage., 55 (2), 141-157, 2002.