Constraints on instantaneous ozone production rates and regimes during DOMINO derived using in-situ OH reactivity measurements

Atmospheric Chemistry and Physics

Volumn 12, Issue 15, 2012, Pages 7269-7283

  Sinha, V ^a,b   Williams, J ^a   Diesch, J M ^a   Drewnick, F ^a   Martinez, M ^a   Harder, H ^a   Regelin, E ^a   Kubistin, D ^a   Bozem, H ^a,e   Hosaynali Beygi, Z ^a   Fischer, H ^a   Andres Hernandez M D ^c   Kartal, D ^c   Adame, J A ^d   Lelieveld, J ^a  

^a MAX PLANCK INSTITUTE FOR CHEMISTRY   (Germany)

^b INDIAN INSTITUTE OF SCIENCE EDUCATION AND RESEARCH MOHALI   (India)

^c UNIVERSITY OF BREMEN   (Germany)

^d INSTITUTO NACIONAL DE TÉCNICA AEROESPACIAL   (Spain)

^e JOHANNES GUTENBERG UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

AIR MASS; ATMOSPHERIC POLLUTION; DIEL VARIATION; NITROGEN OXIDES; OZONE;

ANDALUCIA; HUELVA [ANDALUCIA]; HUELVA [HUELVA (PRV)]; MADRID [MADRID (ADS/PRV)]; MADRID [SPAIN]; SEVILLA; SEVILLE; SPAIN;

EID: 84869025350     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-12-7269-2012     Document Type: Article

References (47)

1. Adame, J. A., Lozano, A., Bolivar, J. P., De la Morena, B. A., Contreras, J., and Godoy, F.: Behavior, distribution and variability of surface ozone at an arid region in the south of Iberian Peninsula (Seville, Spain), Chemosphere, 70, 841-849, 2008. (Pubitemid 350148280)
2. Adame, J. A., Bolivar, J. P., and de la Morena, B. A.: Surface ozone measurements in the southwest of the Iberian Peninsula (Huelva, Spain), Environ. Sci. Pollut. R., 17, 355-368, 2010a.
3. Adame, J. A., Serrano, E., Bolivar, J. P., and de la Morena, B. A.: On the Tropospheric Ozone Variations in a Coastal Area of Southwestern Europe under a Mesoscale Circulation, J. Appl. Meteorol. Clim., 49, 748-759, 2010b.
4. Alastuey, A., Querol, X., Plana, F., Viana, M., Ruiz, C. R., de la Campa, A. S., de la Rosa, J., Mantilla, E., and dos Santos, S. G.: Identification and chemical characterization of industrial particulate matter sources in southwest Spain, J. Air Waste Manage., 56, 993-1006, 2006. (Pubitemid 46028265)
5. Ammann, C., Brunner, A., Spirig, C., and Neftel, A.: Technical note: Water vapour concentration and flux measurements with PTR-MS, Atmos. Chem. Phys., 6, 4643-4651, doi:10.5194/acp-6-4643-2006, 2006. (Pubitemid 44600397)
6. Atkinson, R., Aschmann, S. M., Winer, A. M., and Carter, W. P. L.: Rate Constants for the Gas-Phase Reactions of OH Radicals and O3 with Pyrrole at 2951k and Atmospheric-Pressure, Atmos. Environ., 18, 2105-2107, 1984.
7. Atkinson, R.: Kinetics of the gas-phase reactions of OH radicals with alkanes and cycloalkanes, Atmos. Chem. Phys., 3, 2233-2307, doi:10.5194/acp-3- 2233-2003, 2003.
8. Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., and Troe, J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I-gas phase reactions of Ox, HOx, NOx and SOx species, Atmos. Chem. Phys., 4, 1461-1738, doi:10.5194/acp-4-1461-2004, 2004. (Pubitemid 39342128)
9. Butler, T. M., Lawrence, M. G., Taraborrelli, D., and Lelieveld, J.: Multi-day ozone production potential of volatile organic compounds calculated with a tagging approach, Atmos. Environ., 45, 4082-4090, doi:10.1016/j.atmosenv. 2011.03.040, 2011.
10. Cantrell, C. A., Shetter, R. E., Lind, J. A., McDaniel, A. H., Calvert, J. G., Parrish, D. D., Fehsenfeld, F. C., Buhr, M. P., and Trainer, M.: An Improved Chemical Amplifier Technique for Peroxy Radical Measurements, J. Geophys. Res., 98, 2897-2909, doi:10.1029/92JD02842, 1993. (Pubitemid 23380955)
11. Crowley, J. N., Thieser, J., Tang, M. J., Schuster, G., Bozem, H., Beygi, Z. H., Fischer, H., Diesch, J.-M., Drewnick, F., Borrmann, S., Song, W., Yassaa, N., Williams, J., P̈ohler, D., Platt, U., and Lelieveld, J.: Variable lifetimes and loss mechanisms for NO3 and N2O5 during the DOMINO campaign: contrasts between marine, urban and continental air, Atmos. Chem. Phys., 11, 10853-10870, doi:10.5194/acp-11-10853-2011, 2011.
12. Di Carlo, P., Brune, W. H., Martinez, M., Harder, H., Lesher, R., Ren, X. R., Thornberry, T., Carroll, M. A., Young, V., Shepson, P. B., Riemer, D., Apel, E., and Campbell, C.: Missing OH reactivity in a forest: Evidence for unknown reactive biogenic VOCs, Science, 304, 722-725, 2004. (Pubitemid 38560875)
13. Diesch, J.-M., Drewnick, F., Zorn, S. R., von der Weiden-Reinm̈uller, S.-L., Martinez, M., and Borrmann, S.: Variability of aerosol, gaseous pollutants and meteorological characteristics associated with changes in air mass origin at the SW Atlantic coast of Iberia, Atmos. Chem. Phys., 12, 3761-3782, doi:10.5194/acp-12-3761-2012, 2012.
14. Draxler, R. R. and Rolph, G. D.: HYSPLIT (HYbrid Single-Particle Lagrangian Integrated Trajectory), Model access via NOAA ARL READY Website http://ready.arl.noaa.gov/HYSPLIT.php, NOAA Air Resources Laboratory, Silver Spring, MD, USA, 2011.
15. Fuchs, H., Bohn, B., Hofzumahaus, A., Holland, F., Lu, K. D., Nehr, S., Rohrer, F., and Wahner, A.: Detection of HO2 by laserinduced fluorescence: calibration and interferences from RO2 radicals, Atmos. Meas. Tech., 4, 1209-1225, doi:10.5194/amt-4-1209-2011, 2011.
16. Hastie, D. R., Weißenmayer, M., Burrows, J. P., and Harris, G. W.: Calibrated chemical amplifier for atmospheric ROx measurements, Anal. Chem., 63, 2048-2057, 1991.
17. Hosaynali Beygi, Z., Fischer, H., Harder, H. D., Martinez, M., Sander, R., Williams, J., Brookes, D. M., Monks, P. S., and Lelieveld, J.: Oxidation photochemistry in the Southern Atlantic boundary layer: unexpected deviations of photochemical steady state, Atmos. Chem. Phys., 11, 8497-8513, doi:10.5194/acp-11-8497-2011, 2011.
18. Ingham, T., Goddard, A., Whalley, L. K., Furneaux, K. L., Edwards, P. M., Seal, C. P., Self, D. E., Johnson, G. P., Read, K. A., Lee, J. D., and Heard, D. E.: A flow-tube based laser-induced fluorescence instrument to measure OH reactivity in the troposphere, Atmos. Meas. Tech., 2, 465-477, doi:10.5194/amt-2-465-2009, 2009.
19. Kartal, D., Andŕes-Herńandez, M. D., Reichert, L., Schlager, H., and Burrows, J. P.: Technical Note: Characterisation of a DUALER instrument for the airborne measurement of peroxy radicals during AMMA 2006, Atmos. Chem. Phys., 10, 3047-3062, doi:10.5194/acp-10-3047-2010, 2010.
20. Keenan, T., Niinemets, Ü ., Sabate, S., Gracia, C., and Peñuelas, J.: Seasonality of monoterpene emission potentials in Quercus ilex and Pinus pinea: Implications for regional VOC emissions modeling, J. Geophys. Res., 114, D22202, doi:10.1029/2009JD011904, 2009.
21. Kirchner, F., Jeanneret, F., Clappier, A., Kruger, B., van den Bergh, H., and Calpini, B.: Total VOC reactivity in the planetary boundary layer 2. A new indicator for determining the sensitivity of the ozone production to VOC and NOx, J. Geophys. Res.-Atmos., 106, 3095-3110, doi:10.1029/2000jd900603, 2001.
22. Kovacs, T. A. and Brune, W. H.: Total OH loss rate measurement, J. Atmos. Chem., 39, 105-122, 2001. (Pubitemid 32536951)
23. Kovacs, T. A., Brune, W. H., Harder, H., Martinez, M., Simpas, J. B., Frost, G. J., Williams, E., Jobson, T., Stroud, C., Young, V., Fried, A., and Wert, B.: Direct measurements of urban OH reactivity during Nashville SOS in summer 1999, J. Environ. Monit., 5, 68-74, 2003. (Pubitemid 36223169)
24. Lee, J. D., Young, J. C., Read, K. A., Hamilton, J. F., Hopkins, J. R., Lewis, A. C., Bandy, B. J., Davey, J., Edwards, P., Ingham, T., Self, D. E., Smith, S. C., Pilling, M. J., and Heard, D. E.: Measurement and calculation of OH reactivity at a United Kingdom coastal site, J. Atmos. Chem., 64, 53-76, doi:10.1007/s10874-010-9171-0, 2009.
25. Lelieveld, J., Dentener, F. J., Peters, W., and Krol, M. C.: On the role of hydroxyl radicals in the self-cleansing capacity of the troposphere, Atmos. Chem. Phys., 4, 2337-2344, doi:10.5194/acp-4-2337-2004, 2004. (Pubitemid 40077750)
26. Lewis, A. C., Carslaw, N., Marriott, P. J., Kinghorn, R. M., Morrison, P., Lee, A. L., Bartle, K. D., and Pilling, M. J.: A larger pool of ozone-forming carbon compounds in urban atmospheres, Nature, 405, 778-781, 2000. (Pubitemid 30407846)
27. Lou, S., Holland, F., Rohrer, F., Lu, K., Bohn, B., Brauers, T., Chang, C.C., Fuchs, H., Ḧaseler, R., Kita, K., Kondo, Y., Li, X., Shao, M., Zeng, L., Wahner, A., Zhang, Y., Wang, W., and Hofzumahaus, A.: Atmospheric OH reactivities in the Pearl River Delta-China in summer 2006: measurement and model results, Atmos. Chem. Phys., 10, 11243-11260, doi:10.5194/acp-10-11243- 2010, 2010.
28. Mao, J., Ren, X., Brune, W. H., Olson, J. R., Crawford, J. H., Fried, A., Huey, L. G., Cohen, R. C., Heikes, B., Singh, H. B., Blake, D. R., Sachse, G. W., Diskin, G. S., Hall, S. R., and Shetter, R. E.: Airborne measurement of OH reactivity during INTEX-B, Atmos. Chem. Phys., 9, 163-173, doi:10.5194/acp-9- 163-2009, 2009.
29. Martinez, M., Harder, H., Kovacs, T. A., Simpas, J. B., Bassis, J., Lesher, R., Brune, W. H., Frost, G. J., Williams, E. J., Stroud, C. A., Jobson, B. T., Roberts, J. M., Hall, S. R., Shetter, R. E., Wert, B., Fried, A., Alicke, B., Stutz, J., Young, V. L., White, A. B., and Zamora, R. J.: OH and HO2 concentrations, sources, and loss rates during the Southern Oxidants Study in Nashville, Tennessee, summer 1999, J. Geophys. Res.-Atmos., 108, 4617, doi:10.1029/2003JD003551, 2003.
30. Martinez, M., Harder, H., Kubistin, D., Rudolf, M., Bozem, H., Eerdekens, G., Fischer, H., Kl̈upfel, T., Gurk, C., K̈onigstedt, R., Parchatka, U., Schiller, C. L., Stickler, A., Williams, J., and Lelieveld, J.: Hydroxyl radicals in the tropical troposphere over the Suriname rainforest: airborne measurements, Atmos. Chem. Phys., 10, 3759-3773, doi:10.5194/acp-10-3759-2010, 2010.
31. Monks, P. S., Granier, C., Fuzzi, S., Stohl, A.,Williams, M. L., Akimoto, H., Amann, M., Baklanov, A., Baltensperger, U., Bey, I., Blake, N., Blake, R. S., Carslaw, K., Cooper, O. R., Dentener, F., Fowler, D., Fragkou, E., Frost, G. J., Generoso, S., Ginoux, P., Grewe, V., Guenther, A., Hansson, H. C., Henne, S., Hjorth, J., Hofzumahaus, A., Huntrieser, H., Isaksen, I. S. A., Jenkin, M. E., Kaiser, J., Kanakidou, M., Klimont, Z., Kulmala, M., Laj, P., Lawrence, M. G., Lee, J. D., Liousse, C., Maione, M., McFiggans, G., Metzger, A., Mieville, A., Moussiopoulos, N., Orlando, J. J., O'Dowd, C. D., Palmer, P. I., Parrish, D. D., Petzold, A., Platt, U., Poschl, U., Prevot, A. S. H., Reeves, C. E., Reimann, S., Rudich, Y., Sellegri, K., Steinbrecher, R., Simpson, D., ten Brink, H., Theloke, J., van derWerf, G. R., Vautard, R., Vestreng, V., Vlachokostas, C., and von Glasow, R.: Atmospheric composition change-global and regional air quality, Atmos. Environ., 43, 5268-5350, 2009.
32. Ren, X. R., Harder, H., Martinez, M., Lesher, R. L., Oliger, A., Shirley, T., Adams, J., Simpas, J. B., and Brune,W. H.: HOx concentrations and OH reactivity observations in New York City during PMTACS-NY2001, Atmos. Environ., 37, 3627-3637, 2003. (Pubitemid 36809171)
33. Ren, X. R., Brune, W. H., Oliger, A., Metcalf, A. R., Simpas, J. B., Shirley, T., Schwab, J. J., Bai, C. H., Roychowdhury, U., Li, Y. Q., Cai, C. X., Demerjian, K. L., He, Y., Zhou, X. L., Gao, H. L., and Hou, J.: OH, HO2, and OH reactivity during the PMTACS-NY Whiteface Mountain 2002 campaign: Observations and model comparison, J. Geophys. Res.-Atmos., 111, D10S03, doi:10.1029/ 2005JD006126, 2006. (Pubitemid 44043262)
34. Sadanaga, Y., Yoshino, A., Kato, S., Yoshioka, A., Watanabe, K., Miyakawa, Y., Hayashi, I., Ichikawa, M., Matsumoto, J., Nishiyama, A., Akiyama, N., Kanaya, Y., and Kajii, Y.: The importance of NO2 and volatile organic compounds in the urban air from the viewpoint of the OH reactivity, Geophys. Res. Lett., 31, L08102, doi:10.1029/2004GL019661, 2004a. (Pubitemid 38893024)
35. Sadanaga, Y., Yoshino, A., Watanabe, K., Yoshioka, A., Wakazono, Y., Kanaya, Y., and Kajii, Y.: Development of a measurement system of OH reactivity in the atmosphere by using a laserinduced pump and probe technique, Rev. Sci. Instrum., 75, 2648-2655, 2004b.
36. Sadanaga, Y., Yoshino, A., Kato, S., and Kajii, Y.: Measurements of OH reactivity and photochemical ozone production in the urban atmosphere, Environ. Sci. Technol., 39, 8847-8852, 2005.
37. Seinfeld, J. H. and Pandis. S. N.: Chapter 6, Atmospheric Chemistry and Physics-From Air Pollution to Climate Change, Second Edition ed., John Wiley & Sons, Inc, New Jersey, USA, 2006.
38. Shirley, T. R., Brune, W. H., Ren, X., Mao, J., Lesher, R., Cardenas, B., Volkamer, R., Molina, L. T., Molina, M. J., Lamb, B., Velasco, E., Jobson, T., and Alexander, M.: Atmospheric oxidation in the Mexico City Metropolitan Area (MCMA) during April 2003, Atmos. Chem. Phys., 6, 2753-2765, doi:10.5194/acp-6- 2753-2006, 2006. (Pubitemid 44048096)
39. Sinha, V., Williams, J., Crutzen, P. J., and Lelieveld, J.: Methane emissions from boreal and tropical forest ecosystems derived from in-situ measurements, Atmos. Chem. Phys. Discuss., 7, 14011-14039, doi:10.5194/acpd-7- 14011-2007, 2007. (Pubitemid 47509192)
40. Sinha, V., Williams, J., Crowley, J. N., and Lelieveld, J.: The Comparative Reactivity Method-a new tool to measure total OH Reactivity in ambient air, Atmos. Chem. Phys., 8, 2213-2227, doi:10.5194/acp-8-2213-2008, 2008.
41. Sinha, V., Custer, T. G., Kluepfel, T., andWilliams, J.: The effect of relative humidity on the detection of pyrrole by PTR-MS for OH reactivity measurements, Int. J. Mass Spectrom., 282, 108-111, 2009.
42. Sinha, V., Williams, J., Lelieveld, J., Ruuskanen, T. M., Kajos, M. K., Patokoski, J., Hellen, H., Hakola, H., Mogensen, D., Boy, M., Rinne, J., and Kulmala, M.: OH Reactivity Measurements within a Boreal Forest: Evidence for Unknown Reactive Emissions, Environ. Sci. Technol., 44, 6614-6620, 2010.
43. Sommariva, R., Brown, S. S., Roberts, J. M., Brookes, D. M., Parker, A. E., Monks, P. S., Bates, T. S., Bon, D., de Gouw, J. A., Frost, G. J., Gilman, J. B., Goldan, P. D., Herndon, S. C., Kuster, W. C., Lerner, B. M., Osthoff, H. D., Tucker, S. C., Warneke, C., Williams, E. J., and Zahniser, M. S.: Ozone production in remote oceanic and industrial areas derived from ship based measurements of peroxy radicals during TexAQS 2006, Atmos. Chem. Phys., 11, 2471-2485, doi:10.5194/acp-11-2471-2011, 2011.
44. Song, W. Williams, J., Yassaa, N., Martinez, M., Carnero, J. A. A., Hidalgo, P. J., Bozem, H., Lelieveld, J.: Winter and summer characterization of biogenic enantiomeric monoterpenes and anthropogenic BTEX compounds at a Mediterranean Stone Pine forest site, J. Atmos. Chem., 68, 233-250, doi:10.1007/s10874-012-9219-4, 2011.
45. S̈orgel, M., Regelin, E., Bozem, H., Diesch, J. M., Drewnick, F., Fischer, H., Harder, H., Held, A., Hosaynali-Beygi, Z., Martinez, M., and Zetzsch, C.: Quantification of the unknown HONO daytime source and its relation to NO2, Atmos. Chem. Phys., 11, 10433-10447, doi:10.5194/acp-11-10433-2011, 2011.
46. Staudt, M., Bertin, N., Frenzel, B., and Seufert, G.: Seasonal variation in amount and composition of monoterpenes emitted by young Pinus pinea trees-Implications for emission modeling, J. Atmos. Chem., 35, 77-99, doi:10.1023/a:1006233010748, 2000. (Pubitemid 30058042)
47. Yoshino, A., Sadanaga, Y., Watanabe, K., Kato, S., Miyakawa, Y., Matsumoto, J., and Kajii, Y.: Measurement of total OH reactivity by laser-induced pump and probe technique-comprehensive observations in the urban atmosphere of Tokyo, Atmos. Environ., 40, 7869-7881, 2006. (Pubitemid 44750782)