S-allyl thiocarbamates from allylic alcohols by in situ [3,3]-sigmatropic rearrangement of a thiocarbonyldiimidazole adduct

Synthesis (Germany)

Volumn 44, Issue 17, 2012, Pages 2723-2734

  Mingat, Gaëlle ^a   Clayden, Jonathan ^a  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

Author keywords

alcohols; sigmatropic rearrangement; stereospecificity; sulfur; thiocarbamates

Indexed keywords

ALLYLIC ALCOHOL; HIGH YIELD; IMIDAZOLYL; IN-SITU; N-ALKYLANILINES; SIGMATROPIC REARRANGEMENTS; STEREOSPECIFICITY; THIOCARBAMATES; THIOL ESTERS;

ALCOHOLS; ESTERIFICATION; SULFUR;

ESTERS;

1H IMIDAZOLE 1 CARBOTHIOATE; 4 METHYLPENT 1 EN 3 YL 4 CHLOROPHENYL(METHYL)CARBAMOTHIOATE; 4 METHYLPENT 1 EN 3 YL 4 METHYL(4 TOLYL)CARBAMOTHIOATE; ALCOHOL; ALLYLTHIOCARBAMIC ACID DERIVATIVE; BUT 3 EN 2 YL 2 METHOXYPHENYL(METHYL)CARBAMOTHIOATE; BUT 3 EN 2 YL 3 CHLOROPHENYL(METHYL)CARBAMOTHIOATE; BUT 3 EN 2 YL 3 METHOXYPHENYL(METHYL)CARBAMOTHIOATE; BUT 3 EN 2 YL 4 CHLOROPHENYL(METHYL)CARBAMOTHIOATE; BUT 3 EN 2 YL 4 FLUOROPHENYL(METHYL)CARBAMOTHIOATE; BUT 3 EN 2 YL 4 METHOXYPHENYL(METHYL)CARBAMOTHIOATE; BUT 3 EN 2 YL MESITYL(METHYL)CARBAMOTHIOATE; BUT 3 EN 2 YL METHYL(4 TOLYL)CARBAMOTHIOATE; BUT 3 EN 2 YL METHYL(NAPHTHALEN 1 YL)CARBAMOTHIOATE; BUT 3 EN 2 YL METHYL[4 (TRIFLUOROMETHYL)PHENYL]CARBAMOTHIOATE; BUT 3 EN 2 YLMETHYL(PHENYL)CARBAMOTHIOATE; HEX 1 EN 3 YL 2 METHOXYPHENYL(METHYL)CARBAMOTHIOATE; HEX 1 EN 3 YL 3 CHLOROPHENYL(METHYL)CARBAMOTHIOATE; HEX 1 EN 3 YL 4 CHLOROPHENYL(METHYL)CARBAMOTHIOATE; HEX 1 EN 3 YL 4 FLUOROPHENYL(METHYL)CARBAMOTHIOATE; HEX 1 EN 3 YL 4 METHOXYPHENYL(METHYL)CARBAMOTHIOATE; HEX 1 EN 3 YL METHYL(4 TOLYL)CARBAMOTHIOATE; HEX 1,4 DIEN 3 YL 4 CHLOROPHENYL(METHYL)CARBAMOTHIOATE; HEX 1,4 DIEN 3 YL 4 FLUOROPHENYL(METHYL)CARBAMOTHIOATE; HEX 1,4 DIEN 3 YL 4 METHOXYPHENYL(METHYL)CARBAMOTHIOATE; HEX 1,4 DIEN 3 YL METHYL(4 TOLYL)CARBAMOTHIOATE; O BUTYL 2 ENYLMETHYL(PHENYL)CARBAMOTHIOATE; PHENYL(METHYL)CARBAMOTHIOATE; THIOCARBAMIC ACID DERIVATIVE; UNCLASSIFIED DRUG; UNINDEXED DRUG;

ARTICLE; CATALYSIS; CHEMICAL INTERACTION; CHEMICAL REACTION KINETICS; DRUG STRUCTURE; DRUG SYNTHESIS; NUCLEOPHILICITY; REPRODUCIBILITY; SOLVENT EFFECT; SUBSTITUTION REACTION;

EID: 84865465110     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0032-1316746     Document Type: Article

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