Thermodynamic and kinetic study of the carbothermal reduction of SnO 2 for solar thermochemical fuel generation

Energy and Fuels

Volumn 28, Issue 2, 2014, Pages 1396-1405

  Leveîque, Gaël ^a   Abanades, Stéphane ^a  

^a CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84894555229     PISSN: 08870624     EISSN: 15205029     Source Type: Journal    
DOI: 10.1021/ef402182g     Document Type: Article

References (22)

1. 2 using metal oxide catalysts Ind. Eng. Chem. Res. 2012, 51, 11828-11840
2. 2O with renewable or nuclear energy Renewable Sustainable Energy Rev. 2011, 15, 1-23
3. Abbas, H. F.; Wan Daud, W. M. A. Hydrogen production by methane decomposition: A review Int. J. Hydrogen Energy 2010, 35, 1160-1190
4. Rodat, S.; Abanades, S.; Sans, J.-L.; Flamant, G. Hydrogen production from solar thermal dissociation of natural gas: development of a 10 kW solar chemical reactor prototype Sol. Energy 2009, 83, 1599-1610
5. 2/SnO redox reactions: Thermogravimetric analysis Int. J. Hydrogen Energy 2012, 37, 8223-8231
6. Rodat, S.; Abanades, S.; Flamant, G. Co-production of hydrogen and carbon black from solar thermal methane splitting in a tubular reactor prototype Sol. Energy 2011, 85, 645-652
7. Rodat, S.; Abanades, S.; Sans, J.-L.; Flamant, G. A pilot-scale solar reactor for the production of hydrogen and carbon black from methane splitting Int. J. Hydrogen Energy 2010, 35, 7748-7758
8. Rodat, S.; Abanades, S.; Flamant, G. High-temperature solar methane dissociation in a multitubular cavity-type reactor in the temperature range 1823-2073 K Energy Fuels 2009, 23, 2666-2674
9. Rodat, S.; Abanades, S.; Grivei, E.; Patrianakos, G.; Zygogianni, A.; Konstandopoulos, A. G.; Flamant, G. Characterisation of carbon blacks produced by solar thermal dissociation of methane Carbon 2011, 49, 3084-3091
10. Funk, J. E.; Reinstrom, R. M. Energy requirements in production of hydrogen from water Ind. Eng. Chem. Process Des. Dev. 1966, 5, 336-342
11. Abraham, B. M.; Schreiner, F. General principles underlying chemical cycles which thermally decompose water into the elements Ind. Eng. Chem. Fundam. 1974, 13, 305-310
12. Abanades, S.; Charvin, P.; Flamant, G.; Neveu, P. Screening of water-splitting thermochemical cycles potentially attractive for hydrogen production by concentrated solar energy Energy 2006, 31, 2805-2822
13. 2 flow using concentrated thermal radiation Ind. Eng. Chem. Res. 2009, 48, 528-533
14. Hirsch, D.; Epstein, M.; Steinfeld, A. The solar thermal decarbonization of natural gas Int. J. Hydrogen Energy 2001, 26, 1023-1033
15. Wieckert, C.; Frommherz, U.; Kräupl, S.; Guillot, E.; Olalde, G.; Epstein, M.; Santén, S.; Osinga, T.; Steinfeld, A. A 300 kW solar chemical pilot plant for the carbothermic production of zinc J. Sol. Energy Eng. 2007, 129, 190
16. Osinga, T.; Olalde, G.; Steinfeld, A. Solar carbothermal reduction of ZnO: Shrinking packed-bed reactor modeling and experimental validation Ind. Eng. Chem. Res. 2004, 43, 7981-7988
17. 2/Sn carbothermic cycle for splitting water and production of hydrogen J. Sol. Energy Eng. 2010, 132, 031007
18. Padilla, R.; Sohn, H. Y. The reduction of stannic oxide with carbon Metall. Trans. B 1979, 10, 109-115
19. x/Sn for the thermochemical storage of solar energy Energy 2004, 29, 789-799
20. Vishnevetsky, I.; Epstein, M. Tin as a possible candidate for solar thermochemical redox process for hydrogen production J. Sol. Energy Eng. 2009, 131, 021007
21. Roine, A. Outokumpu HSC Chemistry for Windows; Outokumpu Research Oy: Finland, 2002.
22. Gotor, F. J.; Criado, J. M.; Malek, J.; Koga, N. Kinetic analysis of solid-state reactions: The universality of master plots for analyzing isothermal and nonisothermal experiments J. Phys. Chem. A 2000, 104, 10777-10782