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The known macrocyclic oligothiophene 4-mers also show two different crystalline state structures owing to either favorable molecular packing or stabilization with π-π stacking. Although the oligothiophene 4-mer with butyl substituents showed a twisted crystal structure in response to favorable molecular packing,(28) X-ray analysis of a similar oligothiophene 4-mer without a substituent revealed a stacked planar structure stabilized by π-π stacking interaction despite very short S···S distances (3.014(2) and 3.025 Å)
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