Low temperature reduction of free-standing graphene oxide papers with metal iodides for ultrahigh bulk conductivity

Scientific Reports

Volumn 4, Issue , 2014, Pages

  Liu, Chenyang ^a   Hao, Feng ^a   Zhao, Xiaochong ^a,b   Zhao, Qiancheng ^a   Luo, Songping ^a   Lin, Hong ^a  

^a TSINGHUA UNIVERSITY   (China)

^b Science and Technology on Surface Physics and Chemisty Laboratory   (China)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84893828362     PISSN: None     EISSN: 20452322     Source Type: Journal    
DOI: 10.1038/srep03965     Document Type: Article

References (32)

1. Roy-Mayhew, J. D., Bozym, D. J., Punckt, C. & Aksay, I. A. Functionalized graphene as a catalytic counter electrode in dye-sensitized solar cells. ACS Nano 4, 6203-6211 (2010).
2. Hu, Y. H., Wang, H. & Hu, B. Thinnest two-dimensional nanomaterial-graphene for solar energy. Chem. Sus. Chem. 3, 782-796 (2010).
3. Xu, Z. W. et al. Synthesis of hybrid graphene carbon-coated nanocatalysts. J. Mater. Chem. 20, 8230-8232 (2010).
4. Viet, H. P. et al. Chemical functionalization of graphene sheets by solvothermal reduction of a graphene oxide suspension in Nmethyl-2-pyrrolidone. J. Mater. Chem. 21, 3371-3377 (2011).
5. Zhou, X. F., Wang, F., Zhu, Y. M.&Liu, Z. P. Graphenemodified LiFePO4 cathode materials for high power lithium ion batteries. J. Mater. Chem. 21, 3353-3358 (2011).
6. Kavan, L. et al. Optically transparent cathode for dye-sensitized solar cells based on graphene nanoplatelets. ACS Nano 5, 65-172 (2011).
7. Yen, M. Y. et al. Platinum nanoparticles/graphene composite catalyst as a novel composite counter electrode for high performance dye-sensitized solar cells. J. Mater. Chem. 21, 12880-12888 (2011).
8. Zhao, X. et al. Carbon nanosheets as the electrode material in supercapacitors. J. Power Sources. 194, 1208-1212 (2009).
9. Bae, J. et al. Fiber supercapacitors made of nanowire-fiber hybrid structures for wearable/flexible energy storage. Angew. Chem. Int. Edit. 50, 1683-1687 (2011).
10. Li, Z. P. et al. Electrostatic layer-by-layer self-assembly multilayer films based on graphene and manganese dioxide sheets as novel electrode materials for supercapacitors. J. Mater. Chem. 21, 3397-3403 (2011).
11. Liao, L. et al. Top-gated graphene nanoribbon transistors with ultrathin high-K dielectrics. Nano Lett. 10, 1917-1921 (2010).
12. Hu,W. et al.Graphene-based antibacterial paper. ACS Nano 4, 4317-4323 (2010).
13. Xu, Y. & Shi, G. Assembly of chemically modified graphene: methods and applications. J. Mater. Chem. 21, 3311-3323 (2011).
14. Novoselov, K. S. et al. Electric field effect in atomically thin carbon films. Science 306, 666-669 (2004). (Pubitemid 39440910)
15. Bae, S. et al. Roll-to-roll production of 30-inch graphene films for transparent electrodes. Nature Nanotechnology 5, 574-578 (2010).
16. Reina, A. et al. Large area, few-layer graphene films on arbitrary substrates by chemical vapor deposition. Nano Lett. 9, 30-35 (2009).
17. Dong, X. C. et al. Ultra-large single-layer graphene obtained from solution chemical reduction and its electrical properties. Phys. Chem. Chem. Phys. 12, 2164-2169 (2010).
18. Zhou, X. Z. et al. In situ synthesis of metal nanoparticles on single-layer graphene oxide and reduced graphene oxide surfaces. J. Phys. Chem. C. 113, 10842-10846 (2009).
19. Zhou, X. F. & Liu, Z. P. A scalable, solution-phase processing route to graphene oxide and graphene ultralarge sheets. Chem. Commun. 46, 2611-2613 (2010).
20. Peng, H., Meng, L. J., Niu, L. Y. & Lu, Q. H. Simultaneous reduction and surface functionalization of graphene oxide by natural cellulose with the assistance of the ionic liquid. J. Phys. Chem. C. 116, 16924-16929 (2012).
21. Mohanty, N., Nagaraja, A., Armesto, J. & Berry, V. High-throughput, ultrafast synthesis of solution-dispersed graphene via a facile hydride chemistry. Small 6, 226-31 (2010).
22. He, F. A. et al. The attachment of Fe3O4 nanoparticles to graphene oxide by covalent bonding. Carbon 48, 3139-3144 (2010).
23. Li, J., Lin, H., Yang, Z. & Li, J. A Method for the catalytic reduction of graphene oxide at temperatures below 150uC. Carbon 49, 3024-3030 (2011).
24. Pei, S. F. et al. Direct reduction of graphene oxide films into highly conductive and flexible graphene films by hydrohalic acids. Carbon 48, 4466-74 (2010).
25. Zhao, J. P. et al. Efficient preparation of large-area graphene oxide sheets for transparent conductive films. ACS Nano 4, 5245-52 (2010).
26. Zhao, X. et al. Low-cost preparation of a conductive and catalytic graphene film from chemical reduction with AlI3. Carbon 50, 3497-3502 (2012).
27. Cancado, L. G. et al. Quantifying defects in graphene via raman spectroscopy at different excitation energies. Nano lett. 11, 3190-3196 (2011).
28. Dikin, D. A. et al. Preparation and characterization of graphene oxide paper. Nature 448, 457-460 (2007). (Pubitemid 47123522)
29. Bagri, A. et al. Structural evolution during the reduction of chemically derived graphene oxide. Nat. Chem. 2, 581-587 (2010).
30. Schniepp, H. C. et al. Functionalized single graphene sheets derived from splitting graphite oxide. J. Phys. Chem. B 110, 8535-8539 (2006). (Pubitemid 43798555)
31. Flynn, C. M. Jr. Hydrolysis of inorganic iron (III) salts. Chem. Rev. 84, 31-41 (1984).
32. McAllister, M. J. et al. Single Sheet functionalized graphene by oxidation and thermal expansion of Graphite. Chem. Mater. 19, 4396-4404 (2007). (Pubitemid 47441874)