Chemical effects of a solvent-limited approach to hcl-doped polyaniline nanopowder synthesis

Journal of Physical Chemistry C

Volumn 118, Issue 2, 2014, Pages 1294-1305

  Tantawy, Hesham Ramzy ^a   Weakley, Andrew T ^a   Aston, D Eric ^a  

^a UNIVERSITY OF IDAHO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE DELOCALIZATION; CROSS-LINKING DENSITY; DELOCALIZED POLARONS; ELECTROMAGNETIC SHIELDING EFFECTIVENESS; NANOPOWDER SYNTHESIS; SOLVENT FREE REACTION; SYNTHESIS CONDITIONS; UV-VIS SPECTROSCOPY;

CHAINS; CHEMICAL ANALYSIS; CROSSLINKING; ELECTROMAGNETIC SHIELDING; ELECTRONIC STRUCTURE; NANOSTRUCTURED MATERIALS; POLARONS; POLYANILINE; ULTRAVIOLET VISIBLE SPECTROSCOPY;

SOLVENTS;

EID: 84892713263     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp410119n     Document Type: Article

References (147)

1. Nalwa, H. S. Handbook of Organic Conductive Molecules and Polymers 3, Conductive Polymers: Spectroscopy and Physical Properties; Wiley: Chichester; New York, 1997; Vol. 3.
2. Wan, M. Conducting Polymers with Micro or Nanometer Structure; Tsinghua University Press; Springer: Beijing; Berlin, 2008.
3. Jadhav, S. V.; Vijaya, P. Microwave Absorption and Permittivity of Polyaniline Thin Films Using Overlay Technique Microelectron. J. 2008, 39, 1472-1475
4. Qiu, H.; Li, H.; Fang, K.; Li, J.; Mao, W.; Luo, S. Micromorphology and Conductivity of the Vacuum-Deposited Polyaniline Films Synt. Met. 2005, 148, 71-74
5. Xia, H.; Wang, Q. Ultrasonic Irradiation: A Novel Approach to Prepare Conductive Polyaniline/Nanocrystalline Titanium Oxide Composites Chem. Mater. 2002, 14, 2158-2165
6. Bhadra, S.; Khastgir, D.; Singha, N. K.; Lee, J. H. Progress in Preparation, Processing and Applications of Polyaniline Prog. Polym. Sci. 2009, 34, 783-810
7. Li, D.; Huang, J.; Kaner, R. B. Polyaniline Nanofibers: A Unique Polymer Nanostructure for Versatile Applications Acc. Chem. Res. 2008, 42, 135-145
8. Saraswat, A.; Sharma, L. K.; Singh, S.; Singh, R. Electrochemical Assisted Synthesis and Characterization of Perchloric Acid-Doped Aniline-Functionalized Copolymers Synth. Met. 2013, 167, 31-36
9. Zhang, Y.; Wang, Z.; Ye, W.; Qian, H.; Lin, Z. Enhancement of Polyaniline's Electrical Conductivity by Coagulation Polymerization Colloid Polym. Sci. 2013, 1-8
10. Abdiryim, T.; Xiao-Gang, Z.; Jamal, R. Comparative Studies of Solid-State Synthesized Polyaniline Doped with Inorganic Acids Mater. Chem. Phys. 2005, 90, 367-372
11. Kulkarni, M. V.; Charhate, N. A.; Bhavsar, K. V.; Tathe, M. A.; Kale, B. B. Development of Polyaniline-Multiwalled Carbon Nanotube (Pani-Mwcnt) Nanocomposite for Optical Ph Sensor Mater. Res. Innovations 2013, 17, 238-243
12. Ju, Q.; Shi, Y.; Kan, J. Performance Study of Magnesium-Polyaniline Rechargeable Battery in 1-Ethyl-3-methylimidazolium Ethyl Sulfate Electrolyte Synth. Met. 2013, 178, 27-33
13. Zhao, Y.; Si, S.; Liao, C. A Single Flow Zinc//Polyaniline Suspension Rechargeable Battery J. Power Sources 2013, 241, 449-453
14. Louis, D.; de Poncharra, J. d. P. Microelectronic Device Provided with an Array of Elements Made from a Conductive Polymer with a Positive Temperature Coefficient; US Patent 8,421,230, 2013.
15. Xiang, C.; Zou, Y.; Qiu, S.; Sun, L.; Xu, F.; Zhou, H. Bienzymatic Glucose Biosensor Based on Direct Electrochemistry of Cytochrome C on Gold Nanoparticles/Polyaniline Nanosperes Composite Talanta 2013, 110, 96-100
16. Mazeiko, V.; Kausaite-Minkstimiene, A.; Ramanaviciene, A.; Balevicius, Z.; Ramanavicius, A. Gold Nanoparticle and Conducting Polymer-Polyaniline-Based Nanocomposites for Glucose Biosensor Design Sens. Actuators, B 2013, 189, 187-193
17. Khan, R.; Radhapyari, K.; Das, M. R.; Kotoky, P. Graphene-Polyaniline Nanocomposite Based Biosensor for Detection of Antimalarial Drug Artesunate in Pharmaceutical Formulation and Biological Fluids Talanta 2013, 111, 47-53
18. Jaymand, M. Recent Progress in Chemical Modification of Polyaniline Prog. Polym. Sci. 2013, 38, 1287-1306
19. Kulkarni, M. V.; Kale, B. B. Studies of Conducting Polyaniline (Pani) Wrapped-Multiwalled Carbon Nanotubes (Mwcnts) Nanocomposite and Its Application for Optical pH Sensing Sens. Actuators, B 2013, 187, 407-412
20. Liu, C. Y.; Chou, J. C.;; Liao, Y. H.;; Yang, C. J.;; Huang, C. J.; Cheng, T. Y.;; Hu, J. E.;; Chou, H. T. The Investigation of the Electrochromic Characteristics for the Pani Thin Film by Cyclic Voltammetry and Potentiostatic Method. Proceedings of the World Congress on Engineering, WCE 2013, London, U.K., July 3-5, 2013.
21. Tantawy, H. R.; Aston, D. E.; Smith, J. R.; Young, J. L. A Comparison of Electromagnetic Shielding with Polyaniline Nanopowders Produced in Solvent-Limited Conditions ACS Appl. Mater. Interfaces 2013, 5, 4648-4658
22. Wang, W.; Gumfekar, S. P.; Jiao, Q.; Zhao, B. Ferrite-Grafted Polyaniline Nanofibers as Electromagnetic Shielding Materials J. Mater. Chem. C 2013, 1, 2851-2859
23. Saini, P.; Choudhary, V. Enhanced Electromagnetic Interference Shielding Effectiveness of Polyaniline Functionalized Carbon Nanotubes Filled Polystyrene Composites J. Nanopart. Res. 2013, 15, 1-7
24. Oyharcabal, M.; Olinga, T.; Foulc, M.-P.; Lacomme, S.; Gontier, E.; Vigneras, V. Influence of the Morphology of Polyaniline on the Microwave Absorption Properties of Epoxy Polyaniline Composites Compos. Sci. Technol. 2013, 74, 107-112
25. Ting, T.-H.; Wu, K.-H. Synthesis and Electromagnetic Wave-Absorbing Properties of Batio3/Polyaniline Structured Composites in 2-40 Ghz J. Polym. Res. 2013, 20, 1-6
26. McManus, P. M.; Cushman, R. J.; Yang, S. C. Influence of Oxidation and Protonation on the Electrical Conductivity of Polyaniline J. Phys. Chem. 1987, 91, 744-747
27. Wang, Y.; Jing, X. Intrinsically Conducting Polymers for Electromagnetic Interference Shielding Polym. Adv. Technol. 2005, 16, 344-351
28. Sharma, A. L.; Kumar, K.; Deep, A. Nanostructured Polyaniline Films on Silicon for Sensitive Sensing of Ammonia Sens. Actuators, A 2013, 198, 107-112
29. Althaus, C.; Knoll, M. Digital Switching Systems Based on Lateral Self-Oxidation of Aluminum Nanofilm Processors Electrochem. Commun. 2013, 29, 75-77
30. Wallace, G. G.; Spinks, G. M.; Kane-Maguire, L. A. P.; Teasdale, P. R. Conductive Electroactive Polymers Intelligent Materials Systems; CRC Press: Boca Raton; London; New York, 2009.
31. Toshima, N.; Hara, S. Direct Synthesis of Conducting Polymers from Simple Monomers Prog. Polym. Sci. 1995, 20, 155-183
32. Han, M. G.; Cho, S. K.; Oh, S. G.; Im, S. S. Preparation and Characterization of Polyaniline Nanoparticles Synthesized from Dbsa Micellar Solution Synt. Met. 2002, 126, 53-60
33. Zhou, C. F.; Du, X. S.; Mai, Y. W.; Liu, Z.; Ringer, S. P. Solid Phase Mechanochemical Synthesis of Polyaniline Branched Nanofibers Synt. Met. 2009, 159, 1302-1307
34. Bekri-Abbes, I.; Srasra, E. Investigation of Structure and Conductivity Properties of Polyaniline Synthesized by Solid-Solid Reaction J. Polym. Res. 2011, 18, 659-665
35. Du, X. S.; Zhou, C. F.; Wang, G. T.; Mai, Y. W. Novel Solid-State and Template-Free Synthesis of Branched Polyaniline Nanofibers Chem. Mater. 2008, 20, 3806-3808
36. Abdiryim, T.; Jamal, R.; Nurulla, I. Doping Effect of Organic Sulphonic Acids on the Solid-State Synthesized Polyaniline J. Appl. Polym. Sci. 2007, 105, 576-584
37. Ding, Y.; Abdiryim, T.; An, S.; Nurulla, I. Effect of B-Cyclodextrin on the Solid-State Synthesized Polyaniline Doped with Hydrochloric Acid J. Appl. Polym. Sci. 2008, 107, 3864-3870
38. Huang, J.; Moore, J. A.; Acquaye, J. H.; Kaner, R. B. Mechanochemical Route to the Conducting Polymer Polyaniline Macromolecules 2004, 38, 317-321
39. Chowdhury, P.; Saha, B. Potassium Dichromate Initiated Polymerization of Aniline Indian J. Chem. Technol. 2005, 12, 671-675
40. Li, Y.; Al-Ghamdi, A. A.; Al-Hartomy, O. A.; El-Tantawy, F.; Yakuphanoglu, F. Semiconducting Properties of Nanofiber Polyaniline Organic Semiconductor Optoelectron. Adv. Mater., Rapid Commun. 2012, 6, 235-238
41. Pohanish, R. P.; Greene, S. A. Wiley Guide to Chemical Incompatibilities, 3rd ed.; Wiley: Hoboken, N.J., 2009.
42. Fu, Y.; Elsenbaumer, R. L. Thermochemistry and Kinetics of Chemical Polymerization of Aniline Determined by Solution Calorimetry Chem. Mater. 1994, 6, 671-677
43. Stejskal, J.; Gilbert, R. G. Polyaniline. Preparation of a Conducting Polymer (Iupac Technical Report) Pure Appl. Chem. 2002, 74, 857
44. Nalwa, H. S. Handbook of Organic Conductive Molecules and Polymers 2, Conductive Polymers: Synthesis and Electrical Properties; Wiley: Chichester; New York, 1997; Vol. 2.
45. Bhadra, S.; Khastgir, D. Determination of Crystal Structure of Polyaniline and Substituted Polyanilines through Powder X-Ray Diffraction Analysis Polym. Test 2008, 27, 851-857
46. Zhang, X.; Zhu, J.; Haldolaarachchige, N.; Ryu, J.; Young, D. P.; Wei, S.; Guo, Z. Synthetic Process Engineered Polyaniline Nanostructures with Tunable Morphology and Physical Properties Polymer 2012, 53, 2109-2120
47. Varma, S. J.; Xavier, F.; Jayalekshmi, S.; Varghese, S. Synthesis and Studies of Exceptionally Crystalline Polyaniline Thin Films Polym. Int. 2012, 61, 743-748
48. Majumdar, D.; Baskey, M.; Saha, S. K. Epitaxial Growth of Crystalline Polyaniline on Reduced Graphene Oxide Macromol. Rapid Commun. 2011, 32, 1277-1283
49. Colomban, P.; Folch, S.; Gruger, A. Vibrational Study of Short-Range Order and Structure of Polyaniline Bases and Salts Macromolecules 1999, 32, 3080-3092
50. Folch, S.; Gruger, A.; Régis, A.; Baddour-Hadjean, R.; Colomban, P. Polymorphism and Disorder in Oligo-and Polyanilines Synth. Met. 1999, 101, 795-796
51. El Khalki, A.; Gruger, A.; Colomban, P. Bulk-Surface Nanostructure and Defects in Polyaniline Films and Fibres Synth. Met. 2003, 139, 215-220
52. Stejskal, J.; Exnerova, M.; Moravkova, Z.; Trchova, M.; Hromadkova, J.; Prokes, J. Oxidative Stability of Polyaniline Polym. Degrad. Stab. 2012, 97, 1026-1033
53. Sedenkova, I.; Trchova, M.; Stejskal, J. Thermal Degradation of Polyaniline Films Prepared in Solutions of Strong and Weak Acids and in Water-Ftir and Raman Spectroscopic Studies Polym. Degrad. Stab. 2008, 93, 2147-2157
54. Moravkova, Z.; Trchova, M.; Tomsik, E.; Stejskal, J.; Cechvala, J. Enhanced Thermal Stability of Multi-Walled Carbon Nanotubes after Coating with Polyaniline Salt Polym. Degrad. Stab. 2012, 97, 1405-1414
55. Rozlívková, Z.; Trchová, M.; SǏedeǏ nková, I.; Spírková, M.; Stejskal, J. Structure and Stability of Thin Polyaniline Films Deposited in Situ on Silicon and Gold During Precipitation and Dispersion Polymerization of Aniline Hydrochloride Thin Solid Films 2011, 519, 5933-5941
56. Ćirić-Marjanović, G.; Trchová, M.; Stejskal, J. The Chemical Oxidative Polymerization of Aniline in Water: Raman Spectroscopy J. Raman Spectrosc. 2008, 39, 1375-1387
57. MažeikieneǏ, R.; TomkuteǏ, V.; Kuodis, Z.; Niaura, G.; Malinauskas, A. Raman Spectroelectrochemical Study of Polyaniline and Sulfonated Polyaniline in Solutions of Different Ph Vib. Spectrosc. 2007, 44, 201
58. Liu, C.; Zhang, J.; Shi, G.; Chen, F. e. Doping Level Change of Polyaniline Film During Its Electrochemical Growth Process J. Appl. Polym. Sci. 2004, 92, 171-177
59. Dennany, L.; Innis, P. C.; McGovern, S. T.; Wallace, G. G.; Forster, R. J. Electronic Interactions within Composites of Polyanilines Formed under Acidic and Alkaline Conditions. Conductivity, Esr, Raman, Uv-Vis and Fluorescence Studies Phys. Chem. Chem. Phys. 2011, 13, 3303-3310
60. Bernard, M. C.; Hugot-Le Goff, A. Quantitative Characterization of Polyaniline Films Using Raman Spectroscopy: Ii. Effects of Self-Doping in Sulfonated Polyaniline Electrochim. Acta 2006, 52, 728-735
61. Bernard, M. C.; Hugot-Le Goff, A. Quantitative Characterization of Polyaniline Films Using Raman Spectroscopy: I: Polaron Lattice and Bipolaron Electrochim. Acta 2006, 52, 595-603
62. Fukuda, T.; Takezoe, H.; Ishikawa, K.; Fukuda, A.; Woo, H. S.; Jeong, S. K.; Oh, E. J.; Suh, J. S. Ir and Raman Studies in Three Polyanilines with Different Oxidation Level Synth. Met. 1995, 69, 175-176
63. Pereira da Silva, J. E.; Temperini, M. L. A.; Córdoba de Torresi, S. I. Secondary Doping of Polyaniline Studied by Resonance Raman Spectroscopy Electrochim. Acta 1999, 44, 1887-1891
64. Jozefowicz, M. E.; Laversanne, R.; Javadi, H. H. S.; Epstein, A. J.; Pouget, J. P.; Tang, X.; MacDiarmid, A. G. Multiple Lattice Phases and Polaron-Lattice-Spinless-Defect Competition in Polyaniline Phys. Rev. B 1989, 39, 12958-12961
65. Pouget, J. P.; Jozefowicz, M. E.; Epstein, A. J.; Tang, X.; MacDiarmid, A. G. X-Ray Structure of Polyaniline Macromolecules 1991, 24, 779-789
66. Laridjani, M.; Pouget, J. P.; Scherr, E. M.; MacDiarmid, A. G.; Jozefowicz, M. E.; Epstein, A. J. Amorphography-the Relationship between Amorphous and Crystalline Order. 1. The Structural Origin of Memory Effects in Polyaniline Macromolecules 1992, 25, 4106-4113
67. Gouadec, G.; Colomban, P. Raman Spectroscopy of Nanomaterials: How Spectra Relate to Disorder, Particle Size and Mechanical Properties Prog. Cryst. Growth Charact. Mater. 2007, 53, 1-56
68. Varela-Alvarez, A.; Sordo, J. A.; Scuseria, G. E. Doping of Polyaniline by Acid-Base Chemistry: Density Functional Calculations with Periodic Boundary Conditions J. Am. Chem. Soc. 2005, 127, 11318-11327
69. Eftekhari, A. Nanostructured Conductive Polymers; Wiley: Chichester, West Sussex, U.K.; Hoboken, N.J., 2010.
70. Trchová, M.; Morávková, Z.; SǏedeǏ nková, I.; Stejskal, J. Spectroscopy of Thin Polyaniline Films Deposited During Chemical Oxidation of Aniline Chem. Pap. 2012, 66, 415-445
71. Do Nascimento, G. M. Spectroscopy of Polyaniline Nanofibers. In Nanofibers; Kumar, A., Ed.; INTECH: Croatia, 2010; p 438.
72. Jain, M.; Annapoorni, S. Raman Study of Polyaniline Nanofibers Prepared by Interfacial Polymerization Synth. Met. 2010, 160, 1727-1732
73. Cochet, M.; Louarn, G.; Quillard, S.; Buisson, J. P.; Lefrant, S. Theoretical and Experimental Vibrational Study of Emeraldine in Salt Form. Part Ii J. Raman Spectrosc. 2000, 31, 1041-1049
74. Do Nascimento, G. M.; Temperini, M. L. Studies on the Resonance Raman Spectra of Polyaniline Obtained with near-Ir Excitation J. Raman Spectrosc. 2008, 39, 772-778
75. Nobrega, M. M.; Silva, C. H. B.; Constantino, V. R. L.; Temperini, M. L. A. Spectroscopic Study on the Structural Differences of Thermally Induced Cross-Linking Segments in Emeraldine Salt and Base Forms of Polyaniline J. Phys. Chem. B 2012, 116, 14191-14200
76. Bernard, M. C.; Hugot-Le Goff, A.; Joiret, S.; Arkoub, H.; Saïdani, B. Influence of the Nature of Substituent on the Charge Mechanisms in Substituted Polyanilines (Spani, Poma) Studied by Raman and Optical Spectroscopies Electrochim. Acta 2005, 50, 1615-1623
77. Socrates, G. Infrared and Raman Characteristic Group Frequencies:Tables and Charts; Wiley: Chichester; New York, 2000.
78. Cochet, M.; Louarn, G.; Quillard, S.; Boyer, M. I.; Buisson, J. P.; Lefrant, S. Theoretical and Experimental Vibrational Study of Polyaniline in Base Forms: Non-Planar Analysis. Part I J. Raman Spectrosc. 2000, 31, 1029-1039
79. Cochet, M.; Quillard, S.; Buisson, J. P.; Lefrant, S.; Louarn, G. Vibrational Study of the Base Form of Polyaniline: Effect of the 3d Character Synt. Met. 1999, 101, 793-794
80. Moravkova, Z.; Trchova, M.; Exnerova, M.; Stejskal, J. The Carbonization of Thin Polyaniline Films Thin Solid Films 2012, 520, 6088-6094
81. Wilhelm, P. " Modern Polymer Spectroscopy; Wiley-VCH: Weinheim, Germany, 2008.
82. Mazeikiene, R.; Statino, A.; Kuodis, Z.; Niaura, G.; Malinauskas, A. In Situ Raman Spectroelectrochemical Study of Self-Doped Polyaniline Degradation Kinetics Electrochem. Commun. 2006, 8, 1082-1086
83. Mazeikiene, R.; Niaura, G.; Malinauskas, A. A Comparative Raman Spectroelectrochemical Study of Selected Polyaniline Derivatives in a Ph-Neutral Solution Synth. Met. 2010, 160, 1060-1064
84. Lambert, J. B. Organic Structural Spectroscopy; Prentice Hall: Boston, 2010.
85. Boyer, M. I.; Quillard, S.; Louarn, G.; Froyer, G.; Lefrant, S. Vibrational Study of the Fecl3-Doped Dimer of Polyaniline; a Good Model Compound of Emeraldine Salt J. Phys. Chem. B 2000, 104, 8952-8961
86. Tagowska, M.; Pałys, B.; Jackowska, K. Polyaniline Nanotubules-Anion Effect on Conformation and Oxidation State of Polyaniline Studied by Raman Spectroscopy Synth. Met. 2004, 142, 223-229
87. Bernard, M. C.; Hugot-Le Goff, A.; Arkoub, H.; Saïdani, B. Characterization of Substituted Polyaniline Films Using Raman Spectroscopy: Iii. Study of a Methoxylated Polymer: Poma Electrochim. Acta 2007, 52, 5030-5038
88. Zhang, J.; Liu, C.; Shi, G. Raman Spectroscopic Study on the Structural Changes of Polyaniline During Heating and Cooling Processes J. Appl. Polym. Sci. 2005, 96, 732
89. do Nascimento, G. M.; Silva, C. H. B.; Temperini, M. L. A. Electronic Structure and Doping Behavior of Pani-Nsa Nanofibers Investigated by Resonance Raman Spectroscopy Macromol. Rapid Commun. 2006, 27, 255-259
90. Pan, L. J.; Pu, L.; Shi, Y.; Sun, T.; Zhang, R.; Zheng, Y. O. Hydrothermal Synthesis of Polyaniline Mesostructures Adv. Funct. Mater. 2006, 16, 1279-1288
91. Mathew, R.; Mattes, B. R.; Espe, M. P. A Solid State Nmr Characterization of Cross-Linked Polyaniline Powder Synth. Met. 2002, 131, 141
92. Stejskal, J.; Sapurina, I.; Trchova, M. Polyaniline Nanostructures and the Role of Aniline Oligomers in Their Formation Prog. Polym. Sci. 2010, 35, 1420-1481
93. Cruz-Silva, R.; Romero-García, J.; Angulo-Sánchez, J. L.; Flores-Loyola, E.; Farías, M. H.; Castillón, F. F.; Díaz, J. A. Comparative Study of Polyaniline Cast Films Prepared from Enzymatically and Chemically Synthesized Polyaniline Polymer 2004, 45, 4711-4717.
94. Bernard, M. C.; Joiret, S.; Hugot-Le Goff, A. Spectroelectrochemical Characterization of Aniline/Metanilic Acid Copolymers Russ. J. Electrochem. 2004, 40, 235-244
95. Louarn, G.; Lapkowski, M.; Quillard, S.; Pron, A.; Buisson, J. P.; Lefrant, S. Vibrational Properties of Polyaniline-Isotope Effects J. Phys. Chem. 1996, 100, 6998-7006
96. Bernard, M. C.; Hugot-Le Goff, A. Raman Spectroscopy for the Study of Polyaniline Synth. Met. 1997, 85, 1145-1146
97. Furukawa, Y. Electronic Absorption and Vibrational Spectroscopies of Conjugated Conducting Polymers J. Phys. Chem. 1996, 100, 15644-15653
98. Heeger, A. J.; Kivelson, S.; Schrieffer, J. R.; Su, W. P. Solitons in Conducting Polymers Rev. Mod. Phys. 1988, 60, 781-850
99. Brédas, J. L.; Chance, R. R.; Silbey, R. Comparative Theoretical Study of the Doping of Conjugated Polymers: Polarons in Polyacetylene and Polyparaphenylene Phys. Rev. B 1982, 26, 5843-5854
100. Chance, R. R.; Silbey, R. Bipolaron Transport in Doped Conjugated Polymers Phys. Rev. B 1984, 29, 4491-4495
101. Shimano, J. Y.; MacDiarmid, A. G. Phase Segregation in Polyaniline: A Dynamic Block Copolymer Synth. Met. 2001, 119, 365-366
102. Shimano, J. Y.; MacDiarmid, A. G. Polyaniline, a Dynamic Block Copolymer: Key to Attaining Its Intrinsic Conductivity? Synth. Met. 2001, 123, 251-262
103. Quillard, S.; Boyer, M. I.; Cochet, M.; Buisson, J. P.; Louarn, G.; Lefrant, S. Spectroelectrochemical Measurements of the Conducting Form of Polyaniline and Related Oligomers Synth. Met. 1999, 101, 768-771
104. Kumar, A.; Banerjee, S.; Deka, M. Electron Microscopy for Understanding Swift Heavy Ion Irradiation Effects on Electroactive Polymers; FORMATEX: Spain, 2010; Vol. 3.
105. Kim, J. Y.; Lee, J. H.; Kwon, S. J. The Manufacture and Properties of Polyaniline Nano-Films Prepared through Vapor-Phase Polymerization Synth. Met. 2007, 157, 336-342
106. Engert, C.; Umapathy, S.; Kiefer, W.; Hamaguchi, H. o. Dynamic Structure of Charge Carrier in Polyaniline by near-Infrared Excited Resonance Raman Spectroscopy Chem. Phys. Lett. 1994, 218, 87-92
107. Lapkowski, M.; Berrada, K.; Quillard, S.; Louarn, G. Electrochemical Oxidation of Polyaniline in Nonaqueous Electrolytes: ″In Situ″ Raman Spectroscopic Studies Macromolecules 1995, 28, 1233
108. Gospodinova, N.; Dorey, S.; Ivanova, A.; Zhekova, H.; Tadjer, A. Evidence for Generation of Delocalized Polarons in Conducting Polyaniline: A Raman Scattering Spectroscopy Approach Int. J. Polym. Anal. Charact. 2007, 12, 251-271
109. Tan, C. K.; Blackwood, D. J. Interactions between Polyaniline and Methanol Vapour Sens. Actuators, B 2000, 71, 184-191
110. Nalwa, H. S. Handbook of Advanced Electronic and Photonic Materials and Devices; Academic Press: San Diego, 2001; Vol. 8.
111. da Silva, J. E. P.; de Torresi, S. I. C.; de Faria, D. L. A.; Temperini, M. L. A. Raman Characterization of Polyaniline Induced Conformational Changes Synth. Met. 1999, 101, 834-835
112. Boutaleb, N.; Benyoucef, A.; Salavagione, H. J.; Belbachir, M.; Morallón, E. Electrochemical Behaviour of Conducting Polymers Obtained into Clay-Catalyst Layers. An in Situ Raman Spectroscopy Study Eur. Polym. J. 2006, 42, 733-739
113. Nastase, C.; Mihaiescu, D.; Nastase, F.; Moldovan, A.; Stamatin, I. Effect of P-Toluene Sulphonic Acid Doping on the Properties of Plasma Polymerized Aniline Thin Films Synth. Met. 2004, 147, 133-138
114. Nastase, C.; Nastase, F.; Dumitru, A.; Ionescu, M.; Stamatin, I. Thin Film Composites of Nanocarbons-Polyaniline Obtained by Plasma Polymerization Technique Compos., Part A 2005, 36, 481-485
115. Bernard, M. C.; Cordoba de Torresi, S.; Hugot-Le Goff, A. In Situ Raman Study of Sulfonate-Doped Polyaniline Electrochim. Acta 1999, 44, 1989-1997
116. Rajendra Prasad, K.; Munichandraiah, N. Electrochemically Deposited Crystalline Thin Film of Polyaniline on Nickel for Redox Reactions at Positive Potentials Synth. Met. 2002, 130, 17-26
117. Lee, S. Y.; Lim, H.; Choi, G. R.; Kim, J. D.; Suh, E.-K.; Lee, S.-K. Metal-to-Insulating Transition of Single Polyaniline (Pani) Nanowire: A Dedoping Effect J. Phys. Chem. C 2010, 114, 11936-11939
118. Niaura, G.; Mažeikien, R.; Malinauskas, A. Structural Changes in Conducting Form of Polyaniline Upon Ring Sulfonation as Deduced by near Infrared Resonance Raman Spectroscopy Synth. Met. 2004, 145, 105-112
119. Gustavsson, J. M.; Innis, P. C.; He, J.; Wallace, G. G.; Tallman, D. E. Processable Polyaniline-Hcsa/Poly(Vinyl Acetate-Co-Butyl Acrylate) Corrosion Protection Coatings for Aluminium Alloy 2024-T3: A Svet and Raman Study Electrochim. Acta 2009, 54, 1483-1490
120. Furukawa, Y.; Ueda, F.; Hyodo, Y.; Harada, I.; Nakajima, T.; Kawagoe, T. Vibrational Spectra and Structure of Polyaniline Macromolecules 1988, 21, 1297-1305
121. Yang, C.; Chen, C.; Zeng, Y. Fourier Transform Infrared Spectra of Transition Metal Ion-Containing Polyanilines Synthesized in Different Reaction Conditions Spectrochim. Acta, Part A 2007, 66, 37-41
122. Gruger, A.; Novak, A.; Regis, A.; Colomban, P. Infrared and Raman Study of Polyaniline. Part Ii: Influence of Ortho Substituents on Hydrogen Bonding and Uv/Vis-near-Ir Electron Charge Transfer J. Mol. Struct. 1994, 328, 153
123. Kurmaev, E. Z.; Katsnelson, M. I.; Moewes, A.; Magnuson, M.; Guo, J. H.; Butorin, S. M.; Nordgren, J.; Ederer, D. L.; Iwami, M. Spectroscopic Observation of Polaron-Lattice Band Structure in the Conducting Polymer Polyaniline J. Phys.: Condens. Matter 2001, 13, 3907
124. Sinha, S.; Bhadra, S.; Khastgir, D. Effect of Dopant Type on the Properties of Polyaniline J. Appl. Polym. Sci. 2009, 112, 3135-3140
125. Zhou, Q.; Wang, J.; Ma, Y.; Cong, C.; Wang, F. The Relationship of Conductivity to the Morphology and Crystallinity of Polyaniline Controlled by Water Content Via Reverse Microemulsion Colloid Polym. Sci. 2007, 285, 405-411
126. Epstein, A. J.; MacDiarmid, A. G. Electronic Phenomena in Polyanilines; Defense Technical Information Center: Virginia, 1992.
127. Izumi, C. M. S.; Rodrigues, D. C.; Temperini, M. L. A. The Role of Solvent on the Doping of Polyaniline with Fe(Iii) Ions Synth. Met. 2010, 160, 2552-2558
128. Kim, S. C.; Whitten, J.; Kumar, J.; Bruno, F.; Samuelson, L. Self-Doped Carboxylated Polyaniline: Effect of Hydrogen Bonding on the Doping of Polymers Macromol. Res. 2009, 17, 631-637
129. Han, M. G.; Im, S. S. X-Ray Photoelectron Spectroscopy Study of Electrically Conducting Polyaniline/Polyimide Blends Polymer 2000, 41, 3253-3262
130. Garai, A.; Chatterjee, S.; Nandi, A. K. Viscoelastic and Conductivity Properties of Thermoreversible Polyaniline-Dnnsa Gel in M-Cresol Synth. Met. 2010, 160, 1733-1739
131. Inzelt, G. Conducting Polymers a New Era in Electrochemistry; Springer: Berlin; New York, 2012.
132. Chao, L.; Ho, K. S.; Shen, S. Y.; Pu, H. Y.; Hsieh, T. H.; Kuo, C. W.; Tseng, B. H. Short Polyaniline Nanorod Prepared in the Presence of Para-Phenylenediamine J. Appl. Polym. Sci. 2013, 127, 1853-1862
133. Anilkumar, P.; Jayakannan, M. Single-Molecular-System-Based Selective Micellar Templates for Polyaniline Nanomaterials: Control of Shape, Size, Solid State Ordering, and Expanded Chain to Coillike Conformation Macromolecules 2007, 40, 7311-7319
134. Aphesteguy, J.; Jacobo, S. Synthesis of a Soluble Polyaniline-Ferrite Composite: Magnetic and Electric Properties J. Mater. Sci. 2007, 42, 7062-7068
135. Majidi, M. R.; Kane-Maguire, L. A. P.; Wallace, G. G. Electrochemical Synthesis of Optically Active Polyanilines Aust. J. Chem. 1998, 51, 23-30
136. Karatchevtseva, I.; Zhang, Z.; Hanna, J.; Luca, V. Electrosynthesis of Macroporous Polyaniline-V2o5 Nanocomposites and Their Unusual Magnetic Properties Chem. Mater. 2006, 18, 4908-4916
137. Mire, C. A.; Kane-Maguire, L. A.; Wallace, G. G.; in het Panhuis, M. Influence of Added Hydrogen Bonding Agents on the Chiroptical Properties of Chiral Polyaniline Synth. Met. 2009, 159, 715-717
138. Kane-Maguire, L. A. P.; MacDiarmid, A. G.; Norris, I. D.; Wallace, G. G.; Zheng, W. Facile Preparation of Optically Active Polyanilines Via the in Situ Chemical Oxidative Polymerisation of Aniline Synth. Met. 1999, 106, 171-176
139. MacDiarmid, A. G.; Epstein, A. J. Secondary Doping in Polyaniline Synth. Met. 1995, 69, 85-92
140. Min, Y.; Xia, Y.; MacDiarmid, A. G.; Epstein, A. J. Vapor Phase "Secondary Doping" of Polyaniline Synth. Met. 1995, 69, 159-160
141. Xia, Y.; Wiesinger, J. M.; MacDiarmid, A. G.; Epstein, A. J. Camphorsulfonic Acid Fully Doped Polyaniline Emeraldine Salt: Conformations in Different Solvents Studied by an Ultraviolet/Visible/near-Infrared Spectroscopic Method Chem. Mater. 1995, 7, 443-445
142. Sedenkova, I.; Konyushenko, E. N.; Stejskal, J.; Trchova, M.; Prokes, J. Solid-State Oxidation of Aniline Hydrochloride with Various Oxidants Synth. Met. 2011, 161, 1353-1360
143. Rumbau, V.; Pomposo, J. A.; Alduncin, J. A.; Grande, H.; Mecerreyes, D.; Ochoteco, E. A New Bifunctional Template for the Enzymatic Synthesis of Conducting Polyaniline Enzyme Microb. Technol. 2007, 40, 1412-1421
144. Gök, A.; Sari, B.; Talu, M. Synthesis and Characterization of Conducting Substituted Polyanilines Synth. Met. 2004, 142, 41-48
145. Liu, H.; Hu, X. B.; Wang, J. Y.; Boughton, R. I. Structure, Conductivity, and Thermopower of Crystalline Polyaniline Synthesized by the Ultrasonic Irradiation Polymerization Method Macromolecules 2002, 35, 9414
146. Wise, D. L. Electrical and Optical Polymer Systems: Fundamentals: Methods, and Applications; CRC Press: Boca Raton, 1998.
147. Surwade, S. P.; Agnihotra, S. R.; Dua, V.; Zhang, X.; Manohar, S. K.; Kolla, H. S. Chromism and Molecular Weight of Polyaniline Derivatives Synth. Met. 2009, 159, 2153-2156