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Volumn 19, Issue 52, 2013, Pages 17702-17706

Utilization of common ligands for the ruthenium-catalyzed amination of alcohols

Author keywords

alcohols; amines; ammonia; homogeneous catalysis; ruthenium

Indexed keywords

BIDENTATE PHOSPHINES; HOMOGENEOUS CATALYSIS; PRIMARY AMINES; RU CATALYSTS; SECONDARY ALCOHOLS; SIMPLE STRUCTURES; STRUCTURAL CHARACTERISTICS; TRIPHENYL PHOSPHINES;

EID: 84891028882     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201302774     Document Type: Article
Times cited : (53)

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    • 3 (catalyst preparation according to the given protocol, catalyst loading: 1.5 mol % of Ni) at 160 °C in o-xylene. In contrast to the reported procedure, the cooling and infilling of the freshly reduced Ni-catalyst were done under dry argon (oxygen content <1 ppm) to exclude strictly the presence of external hydrogen in the reaction system. Under such conditions, we detected no activity of the Ni catalyst and no conversion of 2-octanol into 2-octylamine (reaction time 24 h). According to our observation, the amination of alcohols to primary amines does not really proceed as a "borrowing-hydrogen" reaction over heterogeneous Ni catalysts.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.