Spectroscopic identification of binary and ternary surface complexes of Np(V) on gibbsite

Environmental Science and Technology

Volumn 47, Issue 24, 2013, Pages 14418-14425

  Gückel, Katharina ^a   Rossberg, Andre ^a   Müller, Katharina ^a   Brendler, Vinzenz ^a   Bernhard, Gert ^a   Foerstendorf, Harald ^a  

^a INSTITUTE OF ION BEAM PHYSICS AND MATERIALS RESEARCH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC CONDITIONS; ATTENUATED TOTAL REFLECTIONS; BIDENTATE COORDINATION; EXTENDED XRAY ABSORPTION FINE STRUCTURE (EXAFS) SPECTROSCOPIES; FOURIER TRANSFORM INFRA REDS; INNER SPHERE COMPLEXES; SPECTROSCOPIC IDENTIFICATION; TERNARY SURFACE COMPLEXES;

EXTENDED X RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY; GROUNDWATER;

COORDINATION REACTIONS;

ALUMINUM OXIDE; CARBONIC ACID; GROUND WATER; ION; NEPTUNIUM; NEPTUNIUM DIOXIDE; OXIDE; UNCLASSIFIED DRUG;

COMPLEXATION; GROUNDWATER RESOURCE; NEPTUNIUM; SORPTION; SPECIATION (CHEMISTRY); SPECIES DIVERSITY; WATER CHEMISTRY;

ARTICLE; EXTENDED X RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY; INFRARED SPECTROSCOPY; SPECTROSCOPY;

ALUMINUM HYDROXIDE; ATMOSPHERE; CARBONATES; MINERALS; NEPTUNIUM; SOLUTIONS; SPECTROSCOPY, FOURIER TRANSFORM INFRARED; SURFACE PROPERTIES; VIBRATION; WATER; X-RAY ABSORPTION SPECTROSCOPY;

EID: 84890586914     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es4034183     Document Type: Article

References (41)

1. Choppin, G. R. Actinide speciation in the environment J. Radioanal. Nucl. Chem. 2007, 273 (3) 695-703
2. Bidoglio, G.; Tanet, G.; Chatt, A. Studies on neptunium(v) carbonate complexes under geologic repository conditions Radiochim. Acta 1985, 38 (1) 21-26
3. Neck, V.; Runde, W.; Kim, J. I. m.; Kanellakopulos, B. Solid-liquid equilibrium reactions of neptunium(V) in carbonate solution at different ionic-strength Radiochim. Acta 1994, 65 (1) 29-37
4. 2, and ZnO: an in situ ATR FT-IR spectroscopic study Environ. Sci. Technol. 2009, 43 (20) 7665-7670
5. Tachi, Y.; Nakazawa, T.; Ochs, M.; Yotsuji, K.; Suyama, T.; Seida, Y.; Yamada, N.; Yui, M. Diffusion and sorption of neptunium(V) in compacted montmorillonite: effects of carbonate and salinity Radiochim. Acta 2010, 98 (9-11) 711-718
6. Fröhlich, D. R.; Amayri, S.; Drebert, J.; Reich, T. Sorption of neptunium(V) on Opalinus Clay under aerobic/anaerobic conditions Radiochim. Acta 2011, 99 (2) 71-77
7. Ikeda-Ohno, A.; Tsushima, S.; Takao, K.; Rossberg, A.; Funke, H.; Scheinost, A. C.; Bernhard, G.; Yaita, T.; Hennig, C. Neptunium carbonato complexes in aqueous solution: an electrochemical, spectroscopic, and quantum chemical study Inorg. Chem. 2009, 48 (24) 11779-11787
8. 4 at 25 C Inorg. Chem. 1983, 22 (14) 2093-2095
9. Neck, V.; Runde, W.; Kim, J. I. Solid-liquid equilibria of neptunium(V) in carbonate solutions of different ionic strengths. 2. Stability of the solid-phases J. Alloys Compd. 1995, 225 (1-2) 295-302
10. Runde, W.; Neu, M. P.; Clark, D. L. Neptunium(V) hydrolysis and carbonate complexation: experimental and predicted neptunyl solubility in concentrated NaCl using the Pitzer approach Geochim. Cosmochim. Acta 1996, 60 (12) 2065-2073
11. Clark, D. L.; Hobart, D. E.; Neu, M. P. Actinide carbonate complexes and their importance in actinide environmental chemistry Chem. Rev. 1995, 95 (1) 25-48
12. Wu, T.; Amayri, S.; Reich, T. Neptunium(V) sorption onto gibbsite Radiochim. Acta 2009, 97 (2) 99-103
13. Del Nero, M.; Ben Said, K.; Madé, B.; Clement, A.; Bontems, G. Effect of pH and carbonate concentration in solution on the sorption of neptunium(V) by hydrargilite: Application of the non-electrostatic model Radiochim. Acta 1998, 81 (3) 133-141
14. Del Nero, M.; Madé, B.; Bontems, G.; Clement, A. Adsorption of neptunium(V) on hydrargilite Radiochim. Acta 1997, 76 (4) 219-228
15. Li, W. J.; Tao, Z. Y. Comparative study on Np(V) sorption on oxides of aluminum and silicon: effects of humic substance and carbonate in solution J. Colloid Interface Sci. 2003, 267 (1) 25-31
16. Tochiyama, O.; Yamazaki, H.; Mikami, T. Sorption of neptunium(V) on various aluminum oxides and hydrous aluminum oxides Radiochim. Acta 1996, 73 (4) 191-198
17. Lefèvre, G.; Noinville, S.; Fédoroff, M. Study of uranyl sorption onto hematite by in situ attenuated total reflection-infrared spectroscopy J. Colloid Interface Sci. 2006, 296 (2) 608-613
18. 2-water interface: An in situ vibrational spectroscopic study Geochim. Cosmochim. Acta 2012, 76 (1) 191-205
19. Gückel, K.; Rossberg, A.; Brendler, V.; Foerstendorf, H. Binary and ternary surface complexes of U(VI) on the gibbsite/water interface studied by vibrational and EXAFS spectroscopy Chem. Geol. 2012, 326, 27-35
20. 2 at the ferrihydrite-water interface probed by time-resolved vibrational spectroscopy J. Colloid Interface Sci. 2012, 377 (1) 299-306
21. Jordan, N.; Foerstendorf, H.; Weiß, S.; Heim, K.; Schild, D.; Brendler, V. Sorption of selenium(VI) onto anatase: macroscopic and microscopic characterization Geochim. Cosmochim. Acta 2011, 75 (6) 1519-1530
22. Jordan, N.; Ritter, A.; Foerstendorf, H.; Scheinost, A. C.; Weiß, S.; Heim, K.; Grenzer, J.; Mücklich, A.; Reuther, H. Adsorption mechanism of selenium(VI) onto maghemite Geochim. Cosmochim. Acta 2013, 103, 63-75
23. Glasoe, P. K.; Long, F. A. Use of glass electrodes to measure acidities in deuterium oxide J. Phys. Chem. 1960, 64 (1) 188-190
24. Adekola, F.; Fédoroff, M.; Geckeis, H.; Kupcik, T.; Lefèvre, G.; Lützenkirchen, J.; Plaschke, M.; Preocanin, T.; Rabung, T.; Schild, D. Characterization of acid-base properties of two gibbsite samples in the context of literature results J. Colloid Interface Sci. 2011, 354 (1) 306-317
25. George, G. N.; Pickering, I. J. EXAFSPAK: A Suite of Computer Programs for Analysis of X-ray Absorption Spectra; Stanford Synchrotron Radiation Laboratory: Stanford, CA, U.S.A., 1995.
26. Ankudinov, A. L.; Ravel, B.; Rehr, J. J.; Conradson, S. D. Real-space multiple-scattering calculation and interpretation of X-ray-absorption near-edge structure Phys. Rev. B 1998, 58 (12) 7565-7576
27. Wolery, T. EQ3/6: A software package for geochemical modelling of aqueous systems: Package overview and installation guide. In Technical Report UCRL-MA-10662 PT I ed., 1992; Lawrence Livermore National Laboratory.
28. Guillaumont, R.; Fanghänel, T.; Fuger, J.; Grenthe, I.; Neck, V.; Palmer, D. A.; Rand, M. H., Update on the Chemical Thermodynamics of Uranium, Neptunium, Plutonium, Americium and Technetium, 1 st ed.; Elsevier: Amsterdam, 2003; p 970.
29. Müller, K.; Brendler, V.; Foerstendorf, H. Aqueous uranium(VI) hydrolysis species characterized by attenuated total reflection Fourier-transform infrared spectroscopy Inorg. Chem. 2008, 47 (21) 10127-10134
30. Müller, K.; Foerstendorf, H.; Tsushima, S.; Brendler, V.; Bernhard, G. Direct spectroscopic characterization of aqueous actinyl(VI) species: a comparative study of Np and U J. Phys. Chem. A 2009, 113 (24) 6626-6632
31. Tsushima, S. On the "yl" bond weakening in uranyl(VI) coordination complexes Dalton Trans. 2011, 40 (25) 6732-6737
32. Su, C. M.; Suarez, D. L. In situ infrared speciation of absorbed carbonate on aluminum and iron oxide Clays Clay Mineral. 1997, 45 (6) 814-825
33. Busca, G.; Lorenzelli, V. Infrared spectroscopic identification of species arising from reactive adsorption of carbon oxides on metal-oxide surfaces Mater. Chem. 1982, 7 (1) 89-126
34. Bargar, J. R.; Kubicki, J. D.; Reitmeyer, R.; Davis, J. A. ATR-FTIR spectroscopic characterization of coexisting carbonate surface complexes on hematite Geochim. Cosmochim. Acta 2005, 69 (6) 1527-1542
35. Hausner, D. B.; Bhandari, N.; Pierre-Louis, A. M.; Kubicki, J. D.; Strongin, D. R. Ferrihydrite reactivity toward carbon dioxide J. Colloid Interface Sci. 2009, 337 (2) 492-500
36. Clark, D. L.; Conradson, S. D.; Ekberg, S. A.; Hess, N. J.; Neu, M. P.; Palmer, P. D.; Runde, W.; Tait, C. D. EXAFS studies of pentavalent neptunium carbonate complexes. Structural elucidation of the principal constituents of neptunium in groundwater environments J. Am. Chem. Soc. 1996, 118 (8) 2089-2090
37. Clark, D. L.; Conradson, S. D.; Ekberg, S. A.; Hess, N. J.; Janecky, D. R.; Neu, M. P.; Palmer, P. D.; Tait, C. D. A multi-method approach to actinide speciation applied to pentavalent neptunium carbonate complexation New J. Chem. 1996, 20 (2) 211-220
38. Combes, J. M.; Chisholm-Brause, C. J.; Brown, G. E.; Parks, G. A.; Conradson, S. D.; Eller, P. G.; Triay, I. R.; Hobart, D. E.; Meijer, A. EXAFS spectroscopic study of neptunium(v) sorption at the α-FeOOH water interface Environ. Sci. Technol. 1992, 26 (2) 376-382
39. Arai, Y.; Moran, P. B.; Honeyman, B. D.; Davis, J. A. In situ spectroscopic evidence for neptunium(V)-carbonate inner-sphere and outer-sphere ternary surface complexes on hematite surfaces Environ. Sci. Technol. 2007, 41 (11) 3940-3944
40. Rossberg, A.; Ulrich, K. U.; Weiß, S.; Tsushima, S.; Hiemstra, T.; Scheinost, A. C. Identification of uranyl surface complexes on ferrihydrite: advanced EXAFS data analysis and CD-MUSIC modeling Environ. Sci. Technol. 2009, 43 (5) 1400-1406
41. May, H. M.; Helmke, P. A.; Jackson, M. L. Gibbsite solubility and thermodynamic properties of hydroxy-aluminum ions in aqueous-solution at 25 C Geochim. Cosmochim. Acta 1979, 43 (6) 861-868