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13344254994
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note
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2 (6.0 g, 0.136 mol) was slowly transferred into 150 mL (0.231 mol) of aqueous 40% tetrabutylammomum hydroxide at -78 °C in an evacuated vessel and stirred for 12 h. The solvent was removed under vacuum and the product isolated by triturating the residue with ethyl acetate and recrystallizing from ethyl acetate.
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15
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13344264355
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note
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3 The precipitation/dissolution process was repeated three times to produce a sodium-free Np(V) solution.
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13344293407
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note
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EXAFS fluorescence data (295 K) were recorded at the Stanford Synchrotron Radiation Laboratory (SSRL): unfocused beamline 4-2, Si(220) double-crystal monochromator, 3.0 GeV, 60-100 mA. EXAFS signals for each of the two-body and three-body configurations were calculated on the basis of crystallographic distances and angles Individual signals with significant contributions (see text) were summed to generate the total theoretical EXAFS signal, which was then fitted to the experimental data by varying distances, angles. Debye-Waller factors, and nonstructural parameters.
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13344256689
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note
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0.
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