Impacts of seasonal and regional variability in biogenic VOC emissions on surface ozone in the Pearl river delta region, China

Atmospheric Chemistry and Physics

Volumn 13, Issue 23, 2013, Pages 11803-11817

  Situ, S ^a   Guenther, A ^b,e   Wang, X ^a,d   Jiang, X ^b   Turnipseed, A ^b   Wu, Z ^a   Bai, J ^c  

^a SUN YAT SEN UNIVERSITY   (China)

^b NATIONAL CENTER FOR ATMOSPHERIC RESEARCH   (United States)

^c INSTITUTE OF ATMOSPHERIC PHYSICS   (China)

^d GUANGZHOU INSTITUTE OF GEOCHEMISTRY   (China)

^e PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC CHEMISTRY; BIOGENIC EMISSION; OZONE; REGIONAL PATTERN; SEASONAL VARIATION; VOLATILE ORGANIC COMPOUND;

CHINA; GUANGDONG; ZHUJIANG DELTA;

EID: 84889818025     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-13-11803-2013     Document Type: Article

References (78)

1. Adams, R. P.: Identification of essential oil components by gas chromatography/mass spectrometry quadrupole, Allured Publ. Corp.: Carol Stream, 2001.
2. Aneja, V., Yoder, G. T., and Arya, S. P.: Ozone in the urban southeastern United States, Environ. Pollut., 75, 39-44, 1992.
3. Atkinson, R. and Arey, J.: Atmospheric degradation of Volatile Organic Compounds, Chem. Rev., 103, 4605-4638, 2003.
4. Bai, J. H. andWang, X. M.: A Study of Nonmethane Hydrocarbons at Subtropical Forest Part I: Seasonal Variation (Flask Sampling), China Climatic and Environmental Research, 6, 286-293, 2001a (in Chinese).
5. Bai, J. H. andWang, X. M.: A Study of Nonmethane Hydrocarbons at Subtropical Forest Part II: Diurnal variation, China Climatic and Environmental Research, 6, 456-466, 2001b (in Chinese).
6. Bai, J. H., Wang, M. X, Graham, J., Prinn, R. G., and Huang, Z. L.: Primary Study on the Concentrations of Nonmethane Hydrocarbon emitted from the Forest, Chinese Journal of Atmospheric Sciences, 12, 247-251, 1998 (in Chinese).
7. Baker, B., Guenther, A., and Greenberg, J.: Canopy level fluxes of 2-methyl-3buten-2-ol, acetone, and methanol by a portable relaxed eddy accumulation system, Environ. Sci. Technol., 35, 1707-1708, 2001.
8. Bao, H., Shrestha, K. L., Kondo, A., Kaga, A., and Inoue, Y.: Modeling the influence of biogenic volatile organic compound emissions on ozone concentration during summer season in the Kinki region of Japan, Atmos. Environ., 44, 421-431, 2009.
9. Barkley, M. P., Palmer, P. I., Smedt, I. D., Karl, T., Guenther, A., and Roozendael, M. V.: Regulated large-scale annual shutdown of Amazonian isoprene emissions, Geophys. Res. Lett., 36, L04803, doi:10.1029/2008GL036843, 2009.
10. Bowling, D. R., Turnipseed, A. A., Delany, A. C., Baldocchi, D. D., Greenberg, J. P., and Monson, R. K.: The use of relaxed eddy accumulation to measure biosphere-atmosphere exchange of isoprene and other biological trace gased, Oecologia, 116, 306-315, 1998. (Pubitemid 28422450)
11. Bowling, D. R., Delany, A. C., Turnipseed, A. A., Baldocchi, D. D., and Monson, R. K.: Modification of the relaxed eddy accumulation technique to maximize measured scalar mixing ratio differences in updrafts and downdrafts, J. Geophys. Res., 104, 9121-9133, 1999. (Pubitemid 29370727)
12. Businger, J. A. and Oncley, S. P.: Flux Measurement with Conditional Sampling, Notes and Correspondence, 7, 349-352, 1990.
13. Carlton, A. G., Wiedinmyer, C., and Kroll, J. H.: A review of Secondary Organic Aerosol (SOA) formation from isoprene, Atmos. Chem. Phys., 9, 4987-5005, doi:10.5194/acp-9-4987-2009, 2009.
14. Carslaw, N., Bell, N., Lewis, A. C., McQuaid, J. B., and Pilling, M. J.: A detailed case study of isoprene chemistry during the EASE96 Mace Head campaign, Atmos. Environ., 34, 2827-2836, 2000. (Pubitemid 30256029)
15. Chameides, W. L., Fehsenfeld, F., Rodgers, M. O., Cardelino, C., Martinez, J., Parrish, D., Lonneman, W., Lawson, D. R., Rasmussen, R. A., Zimmerman, P., and Greenberg, J.: Ozone precursor relationships in the abmbient atmosphere, J. Geophys. Res., 97, 6037-6055, 1992.
16. Chen, F. and Dudhia, J.: Coupling an advanced land surfacehydrology model with the Penn State-NCAR MM5 modeling system. Part I: Model implementation and sensitivity, Mon. Weather Rev. 129, 569-585, 2001. (Pubitemid 32511917)
17. Cheng, H. R., Guo, H., Wang, X. M., Saunders, S. M., Lam, S. H. M., Jiang, F., Wang, T. J., Ding, A. J., Lee, S. C., and Ho, K. F.: On the relationship between ozone and its precursors in the Pearl River Delta: application of an observation-based model (OBM), Environ. Sci. Pollut. R., 17, 547-560, doi:10.1007/s11356-009-0247-9, 2010.
18. Chou, M. D., Suarez, M. J., Ho, C. H., Yan, M. H. H., and Lee, K. T.: Parameterizations for cloud overlapping and shortwave singlescattering properties for use in general circulation and cloud ensemble models, J. Climate, 11, 202-214, 1998.
19. Collins,W. J., Derwent, R. G., Johnson, C. E., and Stevenson, D. S.: The oxidation of organic compounds in the troposphere and their global warming potentials, Clim. Change, 52, 453-479, 2002. (Pubitemid 34220232)
20. Curci, G., Beekmann, M., Vautard, R., Smiatek, G., Steinbrecher, R., Theloke, J., and Friedrich, R.: Modelling study of the impact of isoprene and terpene biogenic emissions on European ozone levels, Atmos. Environ., 43, 1444-1455, 2009.
21. Deng, A. J., Stauffer, D. R., Dudhia, J., Otte, T., and Hunter, G. K.: Update analysis nudging FDDA in WRF-ARW, The 8th WRF Users'sWorkshop, 11-15 June, Boulder, CO, available at: http://www.mmm.ucar.edu/wrf/users/workshops/ WS2007/abstracts/4-8Deng.pdf (29 November 2013), 2007.
22. Fan, S. J., Wang, B. M., Tesche, M., Engelmann, R., Althausen, A., Liu, J., Zhu, W., Fan, Q., Li, M. H., Ta, N., Song, L. L., and Leong, K.: Meteorological conditions and structures of atmospheric boundary layer in October 2004 over Pearl River Delta area, Atmos. Environ., 42, 6174-6186, 2008.
23. Fast, J. D., Gustafson Jr., Easter, W. I., Zaveri, R. C., Barnard, J. C., Chapman, E. G., Grell, G. A., and Packham, S. E.: Evolution of ozone, particulates and aerosol direct radiative forcing in the vicinity of Houston using a fully coupled meteorology-chemistry-aerosol model, J. Geophys. Res., 111, D21305, doi:10.1029/2005JD006721, 2006. (Pubitemid 46978606)
24. Fu, Y. and Liao, H.: Simulation of the interannual variations of biogenic emissions of volatile organic compounds in China: Impacts on tropospheric ozone and secondary organic aerosol, Atmos. Environ., 59, 170-185, 2012.
25. Geng, F., Tie, X., Guenther, A., Li, G., Cao, J., and Harley, P.: Effect of isoprene emissions from major forests on ozone formation in the city of Shanghai, China, Atmos. Chem. Phys., 11, 10449-10459, doi:10.5194/acp-11-10449- 2011, 2011.
26. Granier, C., Petron, G., Muller, J. F., and Brasseur, G.: The impact of natural and anthropogenic hydrocarbons on the tropospheric budget of carbon monoxide, Atmos. Environ, 34, 5255-5270, 2000.
27. Grell, G. A., Peckham, S. E., Schmitz, R., McKeen, S. A., Frost, G., Skamarock, W. C., and Eder, B.: Fully coupled "online" chemistry within the WRF model, Atmos. Environ., 39, 6957-6975, 2005. (Pubitemid 41539465)
28. Grote, R., Keenan, T., Lavoir, A.-V., and Staudt, M.: Process-based simulation of seasonality and drought stress in monoterpene emission models, Biogeosciences, 7, 257-274, doi:10.5194/bg-7-257-2010, 2010.
29. Guenther, A., Hewitt, C. N., Erickson, D., Fall, R., Geron, C., Graedel, T., Harley, P., Klinger, L., Lerdau, M., McKay, W. A., Pierce, T., Scholes B., Steinbrecher, R., Tallamraju, R., Taylor, J. and Aimmerman, P.: A global model of natural volatile organic compound emissions, J. Geophys. Res., 100, 8873-8892, 1995. (Pubitemid 26439580)
30. Guenther, A., Baugh, W., Davis, K., Hampton, G., Harley, P., Klinger, L., Vierling, L., and Zimmerman P.: Isoprene fluxes measured by enclosure, relaxed eddy accumulation, surface layer gradient, mixed layer gradient, and mixed layer mass balance techniques, J. Geophys. Res., 101, 18555-18567, 1996a.
31. Guenther, A., Zimmerman, P., Klinger, L., Greenberg, J., Ennis, C., Davis, K., and Pollock,W.: Estimates of regional natural volatile organic compound fluxes from enclosure and ambient measurements, J. Geophys. Res., 101, 1345-1359, 1996b. (Pubitemid 26475329)
32. Guenther, A., Baugh, B., Brasseur, G., Greenberg, J., Harley, P., Klinger, L., Serca, D., and Vierling, L.: Isoprene emission estimates and uncertainties for the central african espresso study domain, J. Geophys. Res., 104, 30625-30639, 1999.
33. Guenther, A., Karl, T., Harley, P., Wiedinmyer, C., Palmer, P. I., and Geron, C.: Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature), Atmos. Chem. Phys., 6, 3181-3210, doi:10.5194/acp-6-3181-2006, 2006. (Pubitemid 44197400)
34. Guenther, A. B., Jiang, X., Heald, C. L., Sakulyanontvittaya, T., Duhl, T., Emmons, L. K., andWang, X.: The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions, Geosci. Model Dev., 5, 1471-1492, doi:10.5194/gmd-5-1471-2012, 2012.
35. Janjic, Z. L.: Nonsingular Implementation of the Mellor-Yamada Level 2.5 Scheme in the NCEP Meso model, NCEP Office Note, 437, 61, 2002.
36. Kain, J. S. and Fritsch, J. M.: A one-dimensional entraining/detraining plume model and its application in convective parameterization, J. Atmos. Sci., 47, 2784-2802, 1990.
37. Kain, J. S. and Fritsch, J. M.: Convective parameterization for mesoscale model: The Kain-Fritsch scheme. The Representation of Cumulus Convection in Numerical Model, Meteor. Mon., 24, 165-170, 1993.
38. Klinger, L. F., Li, Q. J., Guenther, A., Greenberg, J., Baker, B., and Bai, J. H.: Assessment of volatile organic compound emissions from ecosystems of China, J. Geophys. Res. 107, ACH 16-19, 2002.
39. Lamb, B., Guenther, A., Gay, D., and Westberg, H.: A national inventory of biogenic hydrocarbon emissions. Atmos. Environ., 21, 1695-1705, 1987. (Pubitemid 17656818)
40. Laothawornkitkul, J., Taylor, J. E., Paul, N. D., and Hewitt, C. N.: Biogenic volatile organic compounds in the Earth system, New Phytol., 183, 27-51, 2009.
41. Li, G. H., Zhang, R. Y., Fan, J. W., and Tie, X. X.: Impacts of biogenic emissions on photochemical ozone production in Houston, Texas, J. Geophys. Res., 112, D10309, doi:10.1029/2006JD007924, 2007. (Pubitemid 47193660)
42. Li, Y.: Numerical Studies on Ozone Source Apportionment and Formation Regime and their Implications on Control Strategies, Ph.D. thesis, Hong Kong University of Science and Technology, Hongkong, 2011.
43. Lin, Y. L., Farley, R. D., and Orvilie, H. D.: Bulk parameterization of the snow field in a cloud model, J. Clim. Appl. Meteorol., 22, 1065-1092, 1983.
44. Liu, H., Wang, X. M., Zhang, J. P., He, K. B., Wu, Y., and Xu, J. P.: Emission controls and changes in air quality in Guangzhou during the Asian Games, Atmos. Environ., 76, 81-93, 2013.
45. Lu, K. D., Rohrer, F., Holland, F., Fuchs, H., Bohn, B., Brauers, T., Chang, C. C., Häseler, R., Hu, M., Kita, K., Kondo, Y., Li, X., Lou, S. R., Nehr, S., Shao, M., Zeng, L. M., Wahner, A., Zhang, Y. H., and Hofzumahaus, A.: Observation and modelling of OH and HO2 concentrations in the Pearl River Delta 2006: a missing OH source in a VOC rich atmosphere, Atmos. Chem. Phys., 12, 1541-1569, doi:10.5194/acp-12-1541-2012, 2012.
46. Marley, N. A., Gaffney, J. S., Tackett, M., Sturchio, N. C., Heraty, L., Martinez, N., Hardy, K. D., Marchany-Rivera, A., Guilderson, T., MacMillan, A., and Steelman, K.: The impact of biogenic carbon sources on aerosol absorption in Mexico City, Atmos. Chem. Phys., 9, 1537-1549, doi:10.5194/acp-9-1537-2009, 2009.
47. Martilli, A., Clappier, A., and Rotach, M. W.: An urban surface exchange parameterization for mesoscale models, Bound.-Lay. Meteorol., 104, 261-304, 2002. (Pubitemid 34825190)
48. Mass, C. and Ovens, D.: WRF model physics: Problems, solutions and a new paradigm for progress. Preprints, WRF Users' Workshop, Boulder, CO, NCAR, 2010.
49. Mass, C. and Ovens, D.: Fixing WRF's high speed wind bias: a new subgrid scale drag parameterization and the role of detailed verification, Preprints, 24th Conf. on Weather and Forecasting/20th Conf. on Numerical Weather Prediction, Seattle, WA, Amer. Meteor. Soc., 9B.6, available at: https://ams.confex. com/ams/91Annual/webprogram/Paper180011.html, 2011.
50. Mlawer, E. J., Taubman, S. J., Brown, P. D., Iacono, M. J., and Clough, S. A.: Radiative transfer for inhomogeneous atmosphere: RRTM, a validated correlated-K model for longwave, J. Geophys. Res., 102, 16663-16682, 1997.
51. Pegoraro, E., Rey, A., Greenberg, J., Harley, P., Grace, J., Malhi, Y., and Guenther, A: Effect of drought on isoprene emission rates from leaves of Quercus virginiana Mill, Atmos. Environ., 38, 6149-6156, 2004. (Pubitemid 39445791)
52. Petron, G., Harley, P., Greenberg, J., and Guenther, A.: Seasonal temperature variations influence isoprene emission, Geophys. Res. Lett., 28, 1707-1710, 2001. (Pubitemid 32575900)
53. Pierce, T., Geron, C., Bender, L., Dennis, R., Tonnesen, G., and Guenther, A.: Influence of increased isoprene emissions on regional ozone modeling, J. Geophys. Res.-Atmos., 103, 25611-25629, 1998. (Pubitemid 128700108)
54. Poisson, N., Kanakidou, M., and Crutzen, P. J.: Impact of nonmethane hydrocarbons on tropospheric chemistry and the oxidizing power of the global troposphere: 3-dimensional modeling results, J. Atmos. Chem., 36, 157-230, 2000. (Pubitemid 30216155)
55. Roux, G., Liu, Y., Monache, L. D., Sheu, R.-S., and Warner, T. T.: Verification of high resolution WRF-RTFDDA surface forecasts over mountains and plains. Preprints, WRF Users' Workshop, Boulder, CO, NCAR, 2009.
56. Sakulyanontvittaya, T., Duhl, T.,Wiedinmyer, C., Helmig, D., Matsunaga, S., Potosnak, M., Milford, J., and Guenther, A.: Monoterpene and sesquiterpene emission estimates for the United States, Environ. Sci. Technol., 42, 1623-1629, 2008. (Pubitemid 351416172)
57. Sanderson, M. G., Jones, C. D., Collins, W. J., Johnson, C. E., and Derwent, R. G.: Effect of climate change on isoprene emissions and surface ozone levels, Geophys. Res. Lett., 30, 1936, doi:10.1029/2003GL017642, 2003.
58. Simpson, D., Winiwarter, W., Börjesson, G., Cinderby, S., Ferreiro, A., Guenther, A., Hewitt, C. N., Janson, R., Khalil, M. A. K., Owen, S., Pierce, T. E., Puxbaum, H., Shearer, M., Skiba, U., Steinbrecher, R., Tarrason, L., and Öquist, M. G.: Inventorying emissions from nature in Europe, J. Geophys. Res., 104, 8113-8152, 1999. (Pubitemid 29417097)
59. Skamarock, W. C., Klemp, J. B., Dudhia, J., Gill, D. O., Barker, D. M., Duda, M. G., Huang, X. Y., Wang, W., and Powers, J. G.: A Description of the Advanced Research WRF Version 3, Technical Report, National Center for Atmospheric Research, TN-475,+STR, 2008.
60. Solmon, F., Sarrat, C., Serca, D., Tulet, P., and Rosset, R.: Isoprene and monoterpenes biogenic emissions in France: modeling and impact during a regional pollution episode, Atmos. Environ., 38, 3853-3865, 2004. (Pubitemid 38797945)
61. Stewart, H. E., Hewitt, C. N., Bunce, R. G. H., Steinbrecher, R., Smiatek, G., and Schoenemeyer, T.: A highly spatially and temporally resolved inventory for biogenic isoprene and monoterpene emissions-model description and application to Great Britain, J. Geophys. Res., 108, 4644, doi:10.1029/ 2002JD002694, 2003.
62. Tang, J. H., Chan, L. Y., Chan, C. Y., Li, Y. S., Chang, C. C., Liu, S. C., Wu, D., and Li, Y. D.: Characteristics and diurnal variations of NMHCs at urban, suburban, and rural sites in the Pearl River Delta and a remote site in South China, Atmos. Environ., 41, 8620-8632, 2007. (Pubitemid 350151959)
63. Thunis, P. and Cuvelier, C.: impact of biogenic emissions on ozone formation in the Mediterranean area-a BEMA modeling study, Atmos. Environ., 34, 467-481, 2000. (Pubitemid 32210633)
64. Tsui, J., Guenther, A., Yip, W. K., and Chen, F.: A biogenic volatile organic compound emission inventory for Hong Kong, Atmos. Environ, 43, 6442-6448, doi:doi:10.1016/j.atmosenv.2008.01.027, 2009.
65. Wang, X., Zhang, Y., Hu, Y., Zhou,W., Lu, K., Zhong, L., Zeng, L., Shao, M., Hu, M., and Russell, A. G.: Process analysis and sensitivity study of regional ozone formation over the Pearl River Delta, China, during the PRIDE-PRD2004 campaign using the Community Multiscale Air Quality modeling system, Atmos. Chem. Phys., 10, 4423-4437, doi:10.5194/acp-10-4423-2010, 2010.
66. Wang, X. M., Carmichael, G., Chen, D. L., Tang, Y. H., and Wang, T. J.: Impacts on different emission sources on air quality during March 2001 in the Pearl River Delta (PRD) region, Atmos. Environ., 39, 5227-5241, 2005.
67. Wang, X. M., Lin, W. S., Yang, L. M., Deng, R. R, and Lin, H.: A numerical study of influences of urban land-use change on ozone distribution over the Pearl River Delta Region, China, Tellus B, 59, 633-641, 2007. (Pubitemid 47193303)
68. Wang, X. M., Chen, F.,Wu, Z. Y., Zhang, M. G., Tewari, M., Guenther, A., and Wiedinmyer, C.: Impacts of Weather Conditions Modified by Urban Expansion on Surface Ozone: Comparison between the Pearl River Delta and Yangtze River Delta Regions, Adv. Atmos. Sci., 26, 962-972, 2009.
69. Wang, X. M., Situ, S. P., Guenther, A., Chen, F., Wu, Z. Y., Xia, B. C., and Wang, T. J.: Spatiotemporal variability of biogenic terpenoid emissions in Pearl River Delta, China, with highresolution land-cover and meteorological data, Tellus B, 63, 241-254, 2011.
70. Wei, X. L., Li, Y. S., Lam, K. S., Wang, A. Y., and Wang, T. J.: Impact of biogenic VOC emissions on a tropical cyclone-related ozone episode in the Pearl River Delta region, China, Atmos. Environ., 41, 7851-7861, 2007.
71. Winters, A. J., Adams, M. A., Bleby, T. M., Rennenberg, H., Steigner, D., Steinbrecher, R., and Kreuzwieser, J.: Emissions of isoprene, monoterpene and short-chained carbonyl compounds from Eucalyptus spp. in southern Australia, Atmos. Environ., 43, 3035-3043, 2009.
72. Zaveri, R. Z. and Peters, L. K.: A new lumped structure photochemical mechanism for long-scale applications, J. Geophys. Res., 104, 30387-30414, 1999.
73. Zhang, Y. H., Su, H., Zhong, L. J., Cheng, Y. F., Zeng, L. M.,Wang, X. S., Xiang, Y. R., Wang, J. L., Gao, D. F., Shao, M., and Liu, S. C.: Regional ozone pollution and observation-based approach for analyzing ozone-precursor relationship during the PRIDEPRD2004 campaign, Atmos. Environ., 42, 6203-6218, 2008.
74. Zhang, Y. L.,Wang, X. M., Barletta, B., Simpson, I. J., Blake, D. R., Fu, X. X., Zhang, Z., He, Q. F., Liu, T. Y., Zhao, X. Y., and Ding, X.: Source attributions of hazardous aromatic hydrocarbons in urban, suburban and rural areas in the Pearl River Delta (PRD) region, J. Hazard. Mater., 250-251, 403-411, 2013.
75. Zheng, J. Y., Zhang, L. J., Che, W. W., Zheng, Z. Y., and Yin, S. S.: A highly resolved temporal and spatial air pollutant emission inventory for the Pearl River Delta region, China and its uncertainty assessment, Atmos. Environ., 43, 5112-5122, 2009.
76. Zheng, J. Y., Zheng, Z. Y., Yu, Y. F., and Zhong, L. J.: Temporal, spatial characteristics and uncertainty of biogenic VOC emissions in the Pearl River Delta area, Atmos. Environ., 44, 1960-1969, 2010a.
77. Zheng, J. Y., Zhong, L. J., Wang, T., Louie, P. K. K., and Li, Z. C.: Ground-level ozone in the Pearl River Delta region: Analysis of data from a recently established regional air quality monitoring network, Atmos. Environ., 44, 814-823, 2010b.
78. Zhou, G. Y., Guan, L. L., Wei, X. H., Zhang, D. Q., Zhang, Q. M., Yan, J. H.,Wen, D. Z., Liu, J. X., Liu, S. G., Huang, Z. L., Kong, G. H., Mo, J. M., and Yu, Q. F.: Litterfall production along successional and altitudinal gradients of subtropical monsoon evergreen broadleaved forests in Guangdong, China, Plant Ecol., 188, 77-89, 2007.