Supramolecular Construction of Chelating Bidentate Ligand Libraries through Hydrogen Bonding: Concept and Applications in Homogeneous Metal Complex Catalysis

Supramolecular Catalysis

Volumn , Issue , 2008, Pages 29-55

  Breit, Bernhard ^a  

^a UNIVERSITY OF FREIBURG   (Germany)

Author keywords

Heterodimeric self assembling ligands; Homogeneous metal complex catalysis; Hydrogen bonding; Supramolecular catalysis

Indexed keywords

EID: 84889325858     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9783527621781.ch2     Document Type: Chapter

References (40)

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34. A first confirmation for this assumption was obtained from the reaction of 6-DPPAP (1 equiv), 3-DPICon (1 equiv), and cis-[PtCl2(cod)] (1 equiv; cod 1/4 cyclooctadiene) in toluene in the presence of water to give cis-[PtCl2(6-DPPAP) (3-DPICon)-(H2O)] quantitatively.
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39. (2007) Self-assembly of bidentate ligands for combinatorial homogeneous catalysis: Methanol-stable platforms analogous to the adenine-thymine base pair. Angew. Chem., Int. Ed., 46, 3037-3039.
40. Under identical conditions (Table 2.9), a turnover frequency of 1312 h-1 and a linear: branched regio selectivity of 76: 24 in the rhodium-catalyzed hydroformylation of 1-octene were measured for triphenylphosphine.