13C and 63,65Cu ENDOR studies of CO dehydrogenase from oligotropha carboxidovorans. Experimental evidence in support of a copper-carbonyl intermediate

Journal of the American Chemical Society

Volumn 135, Issue 47, 2013, Pages 17775-17782

  Shanmugam, Muralidharan ^a   Wilcoxen, Jarett ^b   Habel Rodriguez, Diana ^c   Cutsail Iii, George E ^a   Kirk, Martin L ^c   Hoffman, Brian M ^a   Hille, Russ ^b  

^a NORTHWESTERN UNIVERSITY   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c UNIVERSITY OF NEW MEXICO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COMPUTATIONAL STUDIES; EXPERIMENTAL EVIDENCE; INTERMEDIATE STATE; ISOTROPIC COUPLINGS; QUADRUPOLAR COUPLING; REACTION MECHANISM; UNPAIRED ELECTRONS; XANTHINE OXIDASE;

COPPER; ENZYMES; MOLYBDENUM COMPOUNDS;

COPPER COMPOUNDS;

CARBON 13; CARBON MONOXIDE DEHYDROGENASE; COPPER; MOLYBDENUM; XANTHINE OXIDASE;

ARTICLE; BACTERIUM; ENZYME ANALYSIS; ENZYME MECHANISM; ENZYME STRUCTURE; NONHUMAN; OLIGOTROPHA CARBOXIDOVORANS;

ALDEHYDE OXIDOREDUCTASES; ALPHAPROTEOBACTERIA; CATALYTIC DOMAIN; COPPER; ELECTRON SPIN RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MULTIENZYME COMPLEXES;

EID: 84889244645     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja406136f     Document Type: Article

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